TY - JOUR A1 - Girod, Kai A1 - Breitkreuz, Klaas A1 - Gerstner, Andrea A1 - Marzi, Thomas A1 - Schulzke, Tim A1 - Kaluza, Stefan T1 - Close‐to‐Practice Investigations of Heterogeneously Catalyzed Syngas Conversions in Slurry and Fixed‐Bed Reactor Systems JF - Chemie Ingenieur Technik Y1 - 2018 U6 - https://doi.org/10.1002/cite.201700143 SN - 1522-2640 VL - 90 IS - 5 SP - 690 EP - 695 PB - Wiley ER - TY - JOUR A1 - Girod, Kai A1 - Lohmann, Heiko A1 - Kaluza, Stefan T1 - Methanol Synthesis with Steel Mill Gases: Performance Investigations in an On‐Site Technical Center JF - Chemie Ingenieur Technik KW - DEAL Y1 - 2021 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:hbz:due62-opus-34409 SN - 1522-2640 N1 - he investigations within the scope of the project Carbon2Chem® are funded by the German Federal Ministry of Education and Research (BMBF; support code: 03EK3039F). We also thank our project partners in the Carbon2Chem subproject L2 (methanol synthesis) for the trustful cooperation. Open access funding enabled and organized by Projekt DEAL. VL - 93 IS - 5 SP - 850 EP - 855 PB - Wiley ER - TY - CHAP A1 - Hamel, Christian A1 - Kaluza, Stefan A1 - Unger, Christoph ED - Ernst, Stefan T1 - Catalytic tar reforming of biomass-derived synthesis gas: Influence of the catalyst, gas composition and sulfur poisoning T2 - Preprints of the DGMK-Conference "Synthesis Gas Chemistry",October 7 - 9, 2015, Dresden Y1 - 2015 SN - 978-3-941721-56-2 VL - DGMK Tagungsbericht, 2015,2 SP - 139 EP - 146 PB - DGMK CY - Hamburg ER - TY - JOUR A1 - Heeskens, Denise A1 - Aghaei, Pedram A1 - Kaluza, Stefan A1 - Strunk, Jennifer A1 - Muhler, Martin T1 - Selective oxidation of ethanol in the liquid phase over Au/TiO 2 JF - physica status solidi (b) Y1 - 2013 U6 - https://doi.org/10.1002/pssb.201248440 SN - 1521-3951 VL - 250 IS - 6 SP - 1107 EP - 1118 PB - Wiley ER - TY - JOUR A1 - Junge Puring, Kai A1 - Piontek, Stefan A1 - Smialkowski, Mathias A1 - Burfeind, Jens A1 - Kaluza, Stefan A1 - Doetsch, Christian A1 - Apfel, Ulf-Peter T1 - Simple Methods for the Preparation of Non-noble Metal Bulk-electrodes for Electrocatalytic Applications JF - Journal of visualized experiments : JoVE N2 - The rock material pentlandite with the composition Fe4.5Ni4.5S8 was synthesized via high temperature synthesis from the elements. The structure and composition of the material was characterized via powder X-ray diffraction (PXRD), Mössbauer spectroscopy (MB), scanning electron microscopy (SEM), differential scanning calorimetry (DSC) and energy dispersive X-ray spectroscopy (EDX). Two preparation methods of pentlandite bulk electrodes are presented. In the first approach a piece of synthetic pentlandite rock is directly contacted via a wire ferrule. The second approach utilizes pentlandite pellets, pressed from finely ground powder, which is immobilized in a Teflon casing. Both electrodes, whilst being prepared by an additive-free method, reveal high durability during electrocatalytic conversions in comparison to common drop-coating methods. We herein showcase the striking performance of such electrodes to accomplish the hydrogen evolution reaction (HER) and present a standardized method to evaluate the electrocatalytic performance by electrochemical and gas chromatographic methods. Furthermore, we report stability tests via potentiostatic methods at an overpotential of 0.6 V to explore the material limitations of the electrodes during electrolysis under industrial relevant conditions. Y1 - 2017 UR - http://www.ncbi.nlm.nih.gov/pubmed/28671654 U6 - https://doi.org/10.3791/56087 SN - 1940-087X IS - 124 PB - JoVE ER - TY - JOUR A1 - Kaluza, Stefan A1 - Behrens, Malte A1 - Schiefenhövel, Nora A1 - Kniep, Benjamin A1 - Fischer, Richard A1 - Schlögl, Robert A1 - Muhler, Martin T1 - A Novel Synthesis Route for Cu/ZnO/Al2O3 Catalysts used in Methanol Synthesis: Combining Continuous Consecutive Precipitation with Continuous Aging of the Precipitate JF - ChemCatChem Y1 - 2011 U6 - https://doi.org/10.1002/cctc.201000329 SN - 1867-3899 VL - 3 IS - 1 SP - 189 EP - 199 PB - Wiley ER - TY - JOUR A1 - Kaluza, Stefan A1 - Muhler, Martin T1 - On the precipitation mechanism and the role of the post-precipitation steps during the synthesis of binary ZnO–Al2O3 composites with high specific surface area JF - Journal of Materials Chemistry KW - FBMV Y1 - 2009 U6 - https://doi.org/10.1039/b902004g SN - 1364-5501 VL - 19 IS - 23 SP - 3914 EP - 3922 PB - Royal Society of Chemistry (RSC) ER - TY - JOUR A1 - Kaluza, Stefan A1 - Muhler, Martin T1 - On the Role of Aging, Washing, and Drying in the Synthesis of Polycrystalline Zinc Oxide by Precipitation: Combining Fast Continuous Mixing, Spray Drying and Freeze Drying to Unravel the Solid-State Transformations of the Precipitate JF - Catalysis Letters Y1 - 2009 UR - 1572-879X U6 - https://doi.org/10.1007/s10562-008-9818-5 N1 - The authors gratefully acknowledge fruitful discussions with Malte Behrens and Robert Schlögl, and the financial support by the BMBF (Bundesministerium für Bildung und Forschung) within the scope of the project 01RI05028 “Entwicklung von Methanolsynthesekatalysatoren als Basis für nachhaltige Ressourcennutzung” VL - 129 IS - 3-4 SP - 287 EP - 292 PB - Springer ER - TY - JOUR A1 - Failing, Luisa A1 - Kaluza, Stefan A1 - Strucks, Peter T1 - Catalytic CO2 methanation: Providing optimal test conditions for kinetic investigations JF - Chemie Ingenieur Technik N2 - In the context of using renewable energies and recycling climate-changing gases, methanation of CO2 provides one possibility. However, volatile availability of renewable energies for hydrogen production and fluctuating CO2streams from different sources lead to enhanced demand in investigating the influence of dynamic process operation on the catalyst performance, including detailed kinetic characterization. Reliable kinetic measurements require isothermal temperature control and absence of macrokinetic diffusion limitations. Both were investigated in this work while the determination of steady-state kinetic parameters is part of ongoing studies. Furthermore, a detailed analysis with respect to the long-term-stability of the nickel-based catalyst was performed KW - CO2 methanation KW - Kinetics KW - Long-term stability KW - Ni catalyst KW - Power-to-Gas Y1 - 2023 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:hbz:due62-opus-40026 SN - 1522-2640 VL - 95 IS - 5 SP - 749 EP - 753 PB - Wiley ER - TY - CHAP A1 - Wacht, Anika A1 - Kaluza, Stefan A1 - Fleiger, Philipp ED - Leipzig, Konrad von ED - Sacks, Natasha ED - Mc Clelland, Michelle T1 - Carbon Capture and Utilization in Cement Industry—Aspects of the Production of E-Fuels by Upcycling Carbon Dioxide T2 - Smart, Sustainable Manufacturing in an Ever-Changing World: Proceedings of International Conference on Competitive Manufacturing (COMA ’22) KW - Carbon dioxide capture and utilization KW - Synthetischer Kraftstoff KW - Upcycling KW - Kreislaufwirtschaft KW - Zementindustrie KW - Kohlendioxid Y1 - 2023 SN - 9783031156014 U6 - https://doi.org/10.1007/978-3-031-15602-1_44 SN - 2194-0525 SP - 603 EP - 612 PB - Springer Nature CY - Cham ER - TY - JOUR A1 - Schulzke, Tim A1 - Conrad, Stefan A1 - Kaluza, Stefan A1 - van Loo, Tom T1 - Upgrading of fast pyrolysis condensates via esterification with higher alcohols JF - Biomass and Bioenergy Y1 - 2017 U6 - https://doi.org/10.1016/j.biombioe.2017.05.010 SN - 0961-9534 N1 - Postprint ist veröffentlicht unter: http://publica.fraunhofer.de/dokumente/N-446003.html VL - 103 SP - 11 EP - 20 PB - Elsevier ER - TY - RPRT A1 - Failing, Luisa A1 - Kaluza, Stefan A1 - Strucks, Peter T1 - Power2Gas - Katalytische Methanisierung von CO₂ als Baustein einer erfolgreichen Energie- und Rohstoffwende N2 - Die katalytische Methanisierung von Kohlendioxid (CO2) mit Hilfe von elektrolytisch erzeugtem Wasserstoff (H2) aus erneuerbaren Energiequellen kann einen wichtigen Beitrag zur Reduktion von CO2-Emissionen leisten. Aufgrund einer immer stärker fluktuierenden Energie- und Rohstoffbereitstellung spielt die Möglichkeit einer flexiblen, dynamischen Betriebsweise eine zunehmend große Rolle für zukünftige Technologien. Dies bedingt auch im Fall der katalytischen Methanisierung umfangreiche Untersuchungen, um zu ermitteln, inwieweit eine dynamische Fahrweise Auswirkungen auf Prozess und Katalysator besitzt. An diesem Punkt setzte das HiFF-Projekt Power2Gas an. So wurden verschiedene nickelbasierte Katalysatorsysteme synthetisiert, wobei sich der via Imprägnierung hergestellte Ni/Al2O3-Katalysator sowohl aufgrund seiner guten Leistung als auch der praktikablen und reproduzierbaren Herstellung als geeignetes Benchmark-System für weitere Untersuchungen - vor allem im kinetischen Bereich - erwies. Während umfassender Parametervariationen wurden kinetische Datensätze im stationären Zustand bestimmt, die zur Modellierung der katalysierten CO2-Methanisierung verwendet werden können. Darüber hinaus wurden in ausgewählten Versuchsreihen die isotherme Temperaturkontrolle und eine ausreichende Langzeitstabilität sichergestellt sowie makrokinetische Diffusionsbeschränkungen ausgeschlossen. Die Ergebnisse wurden in einer peer-review-Publikation veröffentlicht und auf zwei Konferenzen präsentiert. Sie waren zudem die Basis für eine erfolgreiche Masterarbeit und flossen in die Antragstellung im Rahmen des DFG-Programms „Großgeräteaktion für Hochschulen für Angewandte Wissenschaften“ ein. N2 - The catalytic methanation of carbon dioxide (CO2) using electrolytically produced hydrogen (H2) from renewable energy sources represents a potential option for reducing CO2 emissions. Due to an increasingly fluctuating availability of energy and raw materials, the need for flexible, dynamic operation is becoming ever more crucial for future technologies. In the case of catalytic methanation, this also requires further investigations to determine the impact of dynamic operation on the process and catalysts. This is where the HiFF Power2Gas project comes in. Various nickel-based catalyst systems were synthesized. The Ni/Al2O3 catalyst produced via impregnation was identified as a suitable benchmark system for further investigations - particularly in the kinetic range - due to its good performance as well as its simple and reproducible synthesis. By thorough parameter variation, kinetic data sets were determined in steady state, which can be used to model catalyzed CO2 methanation. In addition, isothermal temperature control and long-term stability were ensured in a series of selected experiments, while macro-kinetic diffusion limitations could be ruled out. The results were published in a peer-reviewed publication and presented at two conferences. They were also fundamental for a successful master's thesis and were used in an application for the DFG program "Großgeräteaktion für Hochschulen für Angewandte Wissenschaften". T3 - Berichte zu HSD-intern geförderten Forschungsprojekten - 4 KW - Dekarbonisierung KW - Dynamische Betriebsweise KW - Nickel-Katalysator KW - Deaktivierung KW - Power-to-X KW - CO₂ Methanisierung Y1 - 2024 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:hbz:due62-opus-45143 SN - 2625-3690 CY - Düsseldorf ER - TY - BOOK A1 - Marzi, Thomas A1 - Deerberg, Görge A1 - Dötsch, Christian A1 - Grevé, Anna A1 - Hiebel, Markus A1 - Kaluza, Stefan A1 - Knappertsbusch, Volker A1 - Maga, Daniel A1 - Müller, Torsten A1 - Pflaum, Hartmut A1 - Pohlig, Astrid A1 - Renner, Manfred A1 - Seifert, Ulrich A1 - Stießel, Sebastian A1 - Unger, Christoph A1 - Wack, Thorsten A1 - Weidner, Eckhard T1 - Kohlendioxid, Biomasse und Regenerativer Strom - Ressourcen einer neuen Kohlenstoffwirtschaft? Y1 - 2017 SN - 978-3-87468-358-6 U6 - https://doi.org/10.24406/UMSICHT-N-473349 VL - Umsicht-Diskurs IS - 1 PB - Fraunhofer-Institut für Umwelt-, Sicherheit- und Energietechnik CY - Oberhausen ER -