TY - JOUR A1 - Schmidt, Stefan A1 - Göbel, Christoph A1 - Nebel, Janine A1 - Wiesmann, Thomas A1 - Hamel, Christian A1 - Reinsdorf, Arne A1 - Wolf, Dorit A1 - Gehrmann, Stefan A1 - Tenhumberg, Nils A1 - Muhler, Martin A1 - Kaluza, Stefan T1 - Recent Developments in the Conversion of Synthesis Gas to Short-Chain Alcohols over Cu-Co-Based Catalysts JF - Chemie Ingenieur Technik Y1 - 2018 U6 - https://doi.org/10.1002/cite.201800023 SN - 1522-2640 VL - 90 IS - 10 SP - 1465 EP - 1475 PB - Wiley ER - TY - JOUR A1 - Schulzke, Tim A1 - Conrad, Stefan A1 - Kaluza, Stefan A1 - van Loo, Tom T1 - Upgrading of fast pyrolysis condensates via esterification with higher alcohols JF - Biomass and Bioenergy Y1 - 2017 U6 - https://doi.org/10.1016/j.biombioe.2017.05.010 SN - 0961-9534 N1 - Postprint ist veröffentlicht unter: http://publica.fraunhofer.de/dokumente/N-446003.html VL - 103 SP - 11 EP - 20 PB - Elsevier ER - TY - JOUR A1 - Junge Puring, Kai A1 - Piontek, Stefan A1 - Smialkowski, Mathias A1 - Burfeind, Jens A1 - Kaluza, Stefan A1 - Doetsch, Christian A1 - Apfel, Ulf-Peter T1 - Simple Methods for the Preparation of Non-noble Metal Bulk-electrodes for Electrocatalytic Applications JF - Journal of visualized experiments : JoVE N2 - The rock material pentlandite with the composition Fe4.5Ni4.5S8 was synthesized via high temperature synthesis from the elements. The structure and composition of the material was characterized via powder X-ray diffraction (PXRD), Mössbauer spectroscopy (MB), scanning electron microscopy (SEM), differential scanning calorimetry (DSC) and energy dispersive X-ray spectroscopy (EDX). Two preparation methods of pentlandite bulk electrodes are presented. In the first approach a piece of synthetic pentlandite rock is directly contacted via a wire ferrule. The second approach utilizes pentlandite pellets, pressed from finely ground powder, which is immobilized in a Teflon casing. Both electrodes, whilst being prepared by an additive-free method, reveal high durability during electrocatalytic conversions in comparison to common drop-coating methods. We herein showcase the striking performance of such electrodes to accomplish the hydrogen evolution reaction (HER) and present a standardized method to evaluate the electrocatalytic performance by electrochemical and gas chromatographic methods. Furthermore, we report stability tests via potentiostatic methods at an overpotential of 0.6 V to explore the material limitations of the electrodes during electrolysis under industrial relevant conditions. Y1 - 2017 UR - http://www.ncbi.nlm.nih.gov/pubmed/28671654 U6 - https://doi.org/10.3791/56087 SN - 1940-087X IS - 124 PB - JoVE ER - TY - JOUR A1 - Girod, Kai A1 - Breitkreuz, Klaas A1 - Henning, Torsten A1 - Lohmann, Heiko A1 - Kaluza, Stefan A1 - Schluter, Stefan T1 - Steel Mills as Syngas Source for Methanol Synthesis: Simulation and Practical Performance Investigations JF - Chemical Engineering Transactions N2 - In the present contribution, the utilization of steel-mill gases for an industrial methanol synthesis process is described. The focus of this work is on the influence of syngas compositions derived from steel-mill gases on an industrial Cu/ZnO/Al2O3 catalyst. Elevated CO2 and H2O concentrations seem to have an irreversible impact on the activity of the catalyst. In order to obtain realistic gas composition for the catalyst tests, a process simulation of the methanol synthesis was conducted. The calculated gas compositions at the reactor inlet were applied in a practical test in order to evaluate the catalyst stability under steel mill gas conditions. No noticeable deactivation was observed. KW - DOAJ Y1 - 2019 SN - 978-88-95608-71-6 U6 - https://doi.org/10.3303/CET1974080 SN - 2283-9216 VL - 74 SP - 475 EP - 480 PB - AIDIC ER - TY - JOUR A1 - Girod, Kai A1 - Lohmann, Heiko A1 - Schlüter, Stefan A1 - Kaluza, Stefan T1 - Methanol Synthesis with Steel-Mill Gases: Simulation and Practical Testing of Selected Gas Utilization Scenarios JF - Processes Y1 - 2020 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:hbz:due62-opus-26928 VL - 8 IS - 12 PB - MDPI ER - TY - JOUR A1 - Nebel, Janine A1 - Schmidt, Stefan A1 - Pan, Qiushi A1 - Lotz, Katrin A1 - Kaluza, Stefan A1 - Muhler, Martin T1 - On the role of cobalt carbidization in higher alcohol synthesis over hydrotalcite-based Co-Cu catalysts JF - Chinese Journal of Catalysis Y1 - 2019 U6 - https://doi.org/10.1016/S1872-2067(19)63344-9 SN - 1872-2067 N1 - The research project is funded by the Federal Ministry of Education and Research (Bundesministerium für Bildung und Forschung, BMBF, Verbundvorhaben Carbon2Chem®, FKZ: 03EK3041). VL - 40 IS - 11 SP - 1731 EP - 1740 PB - Elsevier ER - TY - JOUR A1 - Schittkowski, Julian A1 - Ruland, Holger A1 - Laudenschleger, Daniel A1 - Girod, Kai A1 - Kähler, Kevin A1 - Kaluza, Stefan A1 - Muhler, Martin A1 - Schlögl, Robert T1 - Methanol Synthesis from Steel Mill Exhaust Gases: Challenges for the Industrial Cu/ZnO/Al 2 O 3 Catalyst JF - Chemie Ingenieur Technik Y1 - 2018 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:hbz:due62-opus-34526 SN - 1522-2640 N1 - We gratefully appreciate the support received from the Federal Ministry of Education and Research (Bundesministerium für Bildung und Forschung, BMBF, Verbundvorhaben Carbon2Chem®). VL - 90 IS - 10 SP - 1419 EP - 1429 PB - Wiley ER - TY - BOOK A1 - Marzi, Thomas A1 - Deerberg, Görge A1 - Dötsch, Christian A1 - Grevé, Anna A1 - Hiebel, Markus A1 - Stefan Kaluza, A1 - Knappertsbusch, Volker A1 - Maga, Daniel A1 - Müller, Torsten A1 - Pflaum, Hartmut A1 - Pohlig, Astrid A1 - Renner, Manfred A1 - Seifert, Ulrich A1 - Stießel, Sebastian A1 - Unger, Christoph A1 - Wack, Thorsten A1 - Weidner, Eckhard T1 - Kohlendioxid, Biomasse und Regenerativer Strom - Ressourcen einer neuen Kohlenstoffwirtschaft? Y1 - 2017 SN - 978-3-87468-358-6 U6 - https://doi.org/10.24406/UMSICHT-N-473349 VL - Umsicht-Diskurs IS - 1 PB - Fraunhofer-Institut für Umwelt-, Sicherheit- und Energietechnik CY - Oberhausen ER - TY - JOUR A1 - Weide, Philipp A1 - Schulz, Katharina A1 - Kaluza, Stefan A1 - Rohe, Markus A1 - Beranek, Radim A1 - Muhler, Martin T1 - Controlling the Photocorrosion of Zinc Sulfide Nanoparticles in Water by Doping with Chloride and Cobalt Ions JF - Langmuir Y1 - 2016 UR - http://www.ncbi.nlm.nih.gov/pubmed/27934521 U6 - https://doi.org/10.1021/acs.langmuir.6b03385 SN - 1520-5827 VL - 32 IS - 48 SP - 12641 EP - 12649 PB - ACS Publ. ER - TY - JOUR A1 - Wiesmann, Thomas A1 - Hamel, Christian A1 - Kaluza, Stefan T1 - Techniques to Remove Traces of Oxygen by Catalytic Conversion from Gas Mixtures JF - Chemie Ingenieur Technik Y1 - 2018 U6 - https://doi.org/10.1002/cite.201800022 SN - 1522-2640 VL - 90 IS - 10 SP - 1446 EP - 1452 PB - Wiley ER - TY - JOUR A1 - Titus, Juliane A1 - Kaluza, Stefan A1 - Marschall, Roland T1 - German Catalysis on an International Scale in Weimar JF - ChemCatChem Y1 - 2014 U6 - https://doi.org/10.1002/cctc.201402266 SN - 1867-3899 VL - 6 IS - 6 SP - 1523 EP - 1525 PB - Wiley ER - TY - JOUR A1 - Kaluza, Stefan A1 - Behrens, Malte A1 - Schiefenhövel, Nora A1 - Kniep, Benjamin A1 - Fischer, Richard A1 - Schlögl, Robert A1 - Muhler, Martin T1 - A Novel Synthesis Route for Cu/ZnO/Al2O3 Catalysts used in Methanol Synthesis: Combining Continuous Consecutive Precipitation with Continuous Aging of the Precipitate JF - ChemCatChem Y1 - 2011 U6 - https://doi.org/10.1002/cctc.201000329 SN - 1867-3899 VL - 3 IS - 1 SP - 189 EP - 199 PB - Wiley ER - TY - JOUR A1 - Kaluza, Stefan A1 - Muhler, Martin T1 - On the Role of Aging, Washing, and Drying in the Synthesis of Polycrystalline Zinc Oxide by Precipitation: Combining Fast Continuous Mixing, Spray Drying and Freeze Drying to Unravel the Solid-State Transformations of the Precipitate JF - Catalysis Letters Y1 - 2009 UR - 1572-879X U6 - https://doi.org/10.1007/s10562-008-9818-5 N1 - The authors gratefully acknowledge fruitful discussions with Malte Behrens and Robert Schlögl, and the financial support by the BMBF (Bundesministerium für Bildung und Forschung) within the scope of the project 01RI05028 “Entwicklung von Methanolsynthesekatalysatoren als Basis für nachhaltige Ressourcennutzung” VL - 129 IS - 3-4 SP - 287 EP - 292 PB - Springer ER - TY - CHAP A1 - Kaluza, Stefan A1 - Muhler, Martin ED - Gaigneaux, E. M. ED - Devillers, M. ED - Hermans, S. ED - Jacobs, P. A. ED - Martens, J. A. ED - Ruiz, P. T1 - A novel continuous approach for the synthesis and characterization of pure and mixed metal oxide systems applied in heterogeneous catalysis T2 - Scientific Bases for the Preparation of Heterogeneous Catalysts Y1 - 2010 SN - 978-0-444-53601-3 U6 - https://doi.org/10.1016/S0167-2991(10)75027-8 VL - Studies in Surface Science and Catalysis, 175 SP - 217 EP - 220 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Mei, Bastian A1 - Sánchez, Miguel D. A1 - Reinecke, Thomas A1 - Kaluza, Stefan A1 - Xia, Wei A1 - Muhler, Martin T1 - The synthesis of Nb-doped TiO2 nanoparticles by spray drying: an efficient and scalable method JF - Journal of Materials Chemistry Y1 - 2011 U6 - https://doi.org/10.1039/c1jm11431j SN - 1364-5501 VL - 21 IS - 32 SP - 11781 EP - 11790 PB - Royal Society of Chemistry (RSC) ER - TY - JOUR A1 - Kaluza, Stefan A1 - Schröter, Marie Katrin A1 - Naumann d'Alnoncourt, Raoul A1 - Reinecke, Thomas A1 - Muhler, Martin T1 - High Surface Area ZnO Nanoparticles via a Novel Continuous Precipitation Route JF - Advanced Functional Materials Y1 - 2008 U6 - https://doi.org/10.1002/adfm.200800457 SN - 1616-3028 N1 - The authors gratefully acknowledge fruitful discussions with Malte Behrens and Robert Schlögl, and financial support by the BMBF (Bundesministerium für Bildung und Forschung, project 01RI05028 “Entwicklung von Methanolsynthesekatalysatoren als Basis für nachhaltige Ressourcennutzung”). Supporting Information is available online from Wiley InterScience or from the author. VL - 18 IS - 22 SP - 3670 EP - 3677 ER - TY - JOUR A1 - Peter, Maximilian A1 - Fichtl, Matthias B. A1 - Ruland, Holger A1 - Kaluza, Stefan A1 - Muhler, Martin A1 - Hinrichsen, Olaf T1 - Detailed kinetic modeling of methanol synthesis over a ternary copper catalyst JF - Chemical Engineering Journal Y1 - 2012 U6 - https://doi.org/10.1016/j.cej.2012.06.066 SN - 0009-2509 VL - 203 SP - 480 EP - 491 PB - Elsevier ER - TY - JOUR A1 - Kaluza, Stefan A1 - Muhler, Martin T1 - On the precipitation mechanism and the role of the post-precipitation steps during the synthesis of binary ZnO–Al2O3 composites with high specific surface area JF - Journal of Materials Chemistry KW - FBMV Y1 - 2009 U6 - https://doi.org/10.1039/b902004g SN - 1364-5501 VL - 19 IS - 23 SP - 3914 EP - 3922 PB - Royal Society of Chemistry (RSC) ER - TY - JOUR A1 - Girod, Kai A1 - Lohmann, Heiko A1 - Kaluza, Stefan T1 - Methanol Synthesis with Steel Mill Gases: Performance Investigations in an On‐Site Technical Center JF - Chemie Ingenieur Technik KW - DEAL Y1 - 2021 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:hbz:due62-opus-34409 SN - 1522-2640 N1 - he investigations within the scope of the project Carbon2Chem® are funded by the German Federal Ministry of Education and Research (BMBF; support code: 03EK3039F). We also thank our project partners in the Carbon2Chem subproject L2 (methanol synthesis) for the trustful cooperation. Open access funding enabled and organized by Projekt DEAL. VL - 93 IS - 5 SP - 850 EP - 855 PB - Wiley ER - TY - JOUR A1 - Girod, Kai A1 - Breitkreuz, Klaas A1 - Gerstner, Andrea A1 - Marzi, Thomas A1 - Schulzke, Tim A1 - Kaluza, Stefan T1 - Close‐to‐Practice Investigations of Heterogeneously Catalyzed Syngas Conversions in Slurry and Fixed‐Bed Reactor Systems JF - Chemie Ingenieur Technik Y1 - 2018 U6 - https://doi.org/10.1002/cite.201700143 SN - 1522-2640 VL - 90 IS - 5 SP - 690 EP - 695 PB - Wiley ER -