@article{StrucksWatermannWeberetal.2021, author = {Strucks, Peter and Watermann, Clara and Weber, Konradin and Kaluza, Stefan}, title = {Systematic Investigations of Vibrational and Fluid-Mechanical Stability of Coated Monolithic Catalysts}, series = {Chemie Ingenieur Technik}, volume = {93}, journal = {Chemie Ingenieur Technik}, number = {5}, publisher = {Wiley}, issn = {1522-2640}, doi = {10.1002/cite.202000233}, url = {http://nbn-resolving.de/urn:nbn:de:hbz:due62-opus-28930}, pages = {1 -- 6}, year = {2021}, abstract = {Heterogeneous catalysts usually consist of porous, inorganic materials. Especially in the mobile application, e.g., in exhaust gas catalysis as a part of the gas line of an engine, there are loads due to vibrations and high gas velocities. It can be assumed that physical stress will lead to a loss of the catalytically active coating. The present contribution describes experimental setups and methods for a systematic and reproducible investigation of the main influences to the mass loss due to vibrational and fluid-mechanical stress caused by particle-free gas flows.}, language = {en} } @article{FallingKaluzaStrucks2021, author = {Falling, Luisa and Kaluza, Stefan and Strucks, Peter}, title = {A Short Review on Ni-Catalyzed Methanation of CO²: Reaction Mechanism, Catalyst Deactivation, Dynamic Operation}, series = {Chemie Ingenieur Technik}, volume = {93}, journal = {Chemie Ingenieur Technik}, publisher = {Wiley}, issn = {1522-2640}, doi = {10.1002/cite.202100049}, url = {http://nbn-resolving.de/urn:nbn:de:hbz:due62-opus-32134}, pages = {1526 -- 1536}, year = {2021}, abstract = {Today, the use of renewable energies and recycling of climate-changing gases are increasingly important. In this context,coupling of methanation with small, decentralized CO2sources such as biogas plants provides one possibility. However,fluctuating availability of renewables for hydrogen production in combination with small storage volumes result in anenhanced demand for dynamic process operation. This leads to new research challenges with respect to the required cata-lysts and the overall process design. To draw reliable conclusions about the catalytic performance under dynamic processoperation, the mechanism of the methanation reaction as well as typical deactivation procedures of the catalyst appliedunder steady-state conditions have to be reviewed thoroughly.}, language = {en} } @article{FailingKaluzaStrucks2023, author = {Failing, Luisa and Kaluza, Stefan and Strucks, Peter}, title = {Catalytic CO2 methanation: Providing optimal test conditions for kinetic investigations}, series = {Chemie Ingenieur Technik}, volume = {95}, journal = {Chemie Ingenieur Technik}, number = {5}, publisher = {Wiley}, issn = {1522-2640}, doi = {10.1002/cite.202200201}, url = {http://nbn-resolving.de/urn:nbn:de:hbz:due62-opus-40026}, pages = {749 -- 753}, year = {2023}, abstract = {In the context of using renewable energies and recycling climate-changing gases, methanation of CO2 provides one possibility. However, volatile availability of renewable energies for hydrogen production and fluctuating CO2streams from different sources lead to enhanced demand in investigating the influence of dynamic process operation on the catalyst performance, including detailed kinetic characterization. Reliable kinetic measurements require isothermal temperature control and absence of macrokinetic diffusion limitations. Both were investigated in this work while the determination of steady-state kinetic parameters is part of ongoing studies. Furthermore, a detailed analysis with respect to the long-term-stability of the nickel-based catalyst was performed}, language = {en} } @techreport{FailingKaluzaStrucks2024, author = {Failing, Luisa and Kaluza, Stefan and Strucks, Peter}, title = {Power2Gas - Katalytische Methanisierung von CO₂ als Baustein einer erfolgreichen Energie- und Rohstoffwende}, address = {D{\"u}sseldorf}, organization = {Hochschule D{\"u}sseldorf}, issn = {2625-3690}, doi = {10.20385/opus4-4514}, url = {http://nbn-resolving.de/urn:nbn:de:hbz:due62-opus-45143}, pages = {27}, year = {2024}, abstract = {Die katalytische Methanisierung von Kohlendioxid (CO2) mit Hilfe von elektrolytisch erzeugtem Wasserstoff (H2) aus erneuerbaren Energiequellen kann einen wichtigen Beitrag zur Reduktion von CO2-Emissionen leisten. Aufgrund einer immer st{\"a}rker fluktuierenden Energie- und Rohstoffbereitstellung spielt die M{\"o}glichkeit einer flexiblen, dynamischen Betriebsweise eine zunehmend große Rolle f{\"u}r zuk{\"u}nftige Technologien. Dies bedingt auch im Fall der katalytischen Methanisierung umfangreiche Untersuchungen, um zu ermitteln, inwieweit eine dynamische Fahrweise Auswirkungen auf Prozess und Katalysator besitzt. An diesem Punkt setzte das HiFF-Projekt Power2Gas an. So wurden verschiedene nickelbasierte Katalysatorsysteme synthetisiert, wobei sich der via Impr{\"a}gnierung hergestellte Ni/Al2O3-Katalysator sowohl aufgrund seiner guten Leistung als auch der praktikablen und reproduzierbaren Herstellung als geeignetes Benchmark-System f{\"u}r weitere Untersuchungen - vor allem im kinetischen Bereich - erwies. W{\"a}hrend umfassender Parametervariationen wurden kinetische Datens{\"a}tze im station{\"a}ren Zustand bestimmt, die zur Modellierung der katalysierten CO2-Methanisierung verwendet werden k{\"o}nnen. Dar{\"u}ber hinaus wurden in ausgew{\"a}hlten Versuchsreihen die isotherme Temperaturkontrolle und eine ausreichende Langzeitstabilit{\"a}t sichergestellt sowie makrokinetische Diffusionsbeschr{\"a}nkungen ausgeschlossen. Die Ergebnisse wurden in einer peer-review-Publikation ver{\"o}ffentlicht und auf zwei Konferenzen pr{\"a}sentiert. Sie waren zudem die Basis f{\"u}r eine erfolgreiche Masterarbeit und flossen in die Antragstellung im Rahmen des DFG-Programms „Großger{\"a}teaktion f{\"u}r Hochschulen f{\"u}r Angewandte Wissenschaften" ein.}, language = {de} }