@article{AntonRulandKaluzaetal.2015, author = {Anton, Johan and Ruland, Holger and Kaluza, Stefan and Muhler, Martin}, title = {Fast and Reproducible Testing of Cu-Co-Based Catalysts Applied in the Conversion of Synthesis Gas to Ethanol and Higher Alcohols}, series = {Catalysis Letters}, volume = {145}, journal = {Catalysis Letters}, number = {7}, publisher = {Springer}, doi = {10.1007/s10562-015-1543-2}, pages = {1374 -- 1381}, year = {2015}, language = {en} } @article{BordoloiSanchezNoeietal.2014, author = {Bordoloi, Ankur and Sanchez, Miguel and Noei, Heshmat and Kaluza, Stefan and Großmann, Dennis and Wang, Yuemin and Gr{\"u}nert, Wolfgang and Muhler, Martin}, title = {Catalytic Behaviour of Mesoporous Cobalt-Aluminum Oxides for CO Oxidation}, series = {Journal of Catalysts}, journal = {Journal of Catalysts}, publisher = {Hindawi}, issn = {2314-5110}, doi = {10.1155/2014/807545}, url = {http://nbn-resolving.de/urn:nbn:de:hbz:due62-opus-34344}, pages = {1 -- 9}, year = {2014}, language = {en} } @article{BozKaluzaBoroğluetal.2012, author = {Boz, İsmail and Kaluza, Stefan and Boroğlu, Mehtap Şafak and Muhler, Martin}, title = {Synthesis of high surface area ZnO powder by continuous precipitation}, series = {Materials Research Bulletin}, volume = {47}, journal = {Materials Research Bulletin}, number = {5}, publisher = {Elsevier}, issn = {1873-4227}, doi = {10.1016/j.materresbull.2012.02.005}, pages = {1185 -- 1190}, year = {2012}, language = {en} } @article{HeeskensAghaeiKaluzaetal.2013, author = {Heeskens, Denise and Aghaei, Pedram and Kaluza, Stefan and Strunk, Jennifer and Muhler, Martin}, title = {Selective oxidation of ethanol in the liquid phase over Au/TiO 2}, series = {physica status solidi (b)}, volume = {250}, journal = {physica status solidi (b)}, number = {6}, publisher = {Wiley}, issn = {1521-3951}, doi = {10.1002/pssb.201248440}, pages = {1107 -- 1118}, year = {2013}, language = {en} } @article{KaluzaBehrensSchiefenhoeveletal.2011, author = {Kaluza, Stefan and Behrens, Malte and Schiefenh{\"o}vel, Nora and Kniep, Benjamin and Fischer, Richard and Schl{\"o}gl, Robert and Muhler, Martin}, title = {A Novel Synthesis Route for Cu/ZnO/Al2O3 Catalysts used in Methanol Synthesis: Combining Continuous Consecutive Precipitation with Continuous Aging of the Precipitate}, series = {ChemCatChem}, volume = {3}, journal = {ChemCatChem}, number = {1}, publisher = {Wiley}, issn = {1867-3899}, doi = {10.1002/cctc.201000329}, pages = {189 -- 199}, year = {2011}, language = {en} } @article{KaluzaMuhler2009, author = {Kaluza, Stefan and Muhler, Martin}, title = {On the precipitation mechanism and the role of the post-precipitation steps during the synthesis of binary ZnO-Al2O3 composites with high specific surface area}, series = {Journal of Materials Chemistry}, volume = {19}, journal = {Journal of Materials Chemistry}, number = {23}, publisher = {Royal Society of Chemistry (RSC)}, issn = {1364-5501}, doi = {10.1039/b902004g}, pages = {3914 -- 3922}, year = {2009}, language = {en} } @article{KaluzaMuhler2009, author = {Kaluza, Stefan and Muhler, Martin}, title = {On the Role of Aging, Washing, and Drying in the Synthesis of Polycrystalline Zinc Oxide by Precipitation: Combining Fast Continuous Mixing, Spray Drying and Freeze Drying to Unravel the Solid-State Transformations of the Precipitate}, series = {Catalysis Letters}, volume = {129}, journal = {Catalysis Letters}, number = {3-4}, publisher = {Springer}, doi = {10.1007/s10562-008-9818-5}, pages = {287 -- 292}, year = {2009}, language = {en} } @article{WinterDiehlTelaaretal.2024, author = {Winter, Franziska Luise and Diehl, Patrick and Telaar, Pascal and Watermann, Clara Maria and Kaluza, Stefan and Muhler, Martin and Apfel, Ulf-Peter and Zeidler-Fandrich, Barbara}, title = {Influence of the catalyst precursor for cobalt on activated carbon applied in ammonia decomposition}, series = {Catalysis Today}, volume = {429}, journal = {Catalysis Today}, publisher = {Elsevier}, issn = {0920-5861}, doi = {10.1016/j.cattod.2023.114502}, url = {http://nbn-resolving.de/urn:nbn:de:hbz:due62-opus-46600}, pages = {9}, year = {2024}, abstract = {Ammonia is a key compound for storing and transporting green hydrogen. However, the efficient release of stored hydrogen through thermocatalytic ammonia decomposition is achievable only at temperatures around 600 °C, particularly with non-noble metal-based catalysts, which prove to be both ecologically and economically more feasible. In this study, electrically conductive activated carbon was selected as the catalyst support, chosen specifically for its suitability in achieving more energy-efficient direct reactor heating through the ohmic resistance of the catalysts. Cobalt salts were wet impregnated on activated carbon investigating the influence of different precursors (cobalt nitrate and cobalt acetate) and pyrolysis temperatures (400 °C and 600 °C) under N2 flow on the cobalt particle size and the incorporation of cobalt into the carbon matrix. TEM imaging and CO-chemisorption revealed well dispersed cobalt particles with sizes below 10 nm for the catalysts synthesized from the cobalt nitrate precursor. On the other hand, cobalt acetate led to about nine times larger Co agglomerates, which were partially detached from the carbon matrix. Moreover, this substantial difference in the Co particle size results in a significantly higher ammonia conversion for cobalt nitrate-based catalysts, achieving 94 \% of ammonia conversion at 600 °C. Furthermore, the long-term stability test of the cobalt nitrate-based catalyst resulted in a slight deactivation of only 2 \% ammonia conversion at 500 °C.}, subject = {Katalyse}, language = {en} }