@article{SchmidtGoebelNebeletal.2018, author = {Schmidt, Stefan and G{\"o}bel, Christoph and Nebel, Janine and Wiesmann, Thomas and Hamel, Christian and Reinsdorf, Arne and Wolf, Dorit and Gehrmann, Stefan and Tenhumberg, Nils and Muhler, Martin and Kaluza, Stefan}, title = {Recent Developments in the Conversion of Synthesis Gas to Short-Chain Alcohols over Cu-Co-Based Catalysts}, series = {Chemie Ingenieur Technik}, volume = {90}, journal = {Chemie Ingenieur Technik}, number = {10}, publisher = {Wiley}, issn = {1522-2640}, doi = {10.1002/cite.201800023}, pages = {1465 -- 1475}, year = {2018}, language = {en} } @article{SchulzkeConradKaluzaetal.2017, author = {Schulzke, Tim and Conrad, Stefan and Kaluza, Stefan and van Loo, Tom}, title = {Upgrading of fast pyrolysis condensates via esterification with higher alcohols}, series = {Biomass and Bioenergy}, volume = {103}, journal = {Biomass and Bioenergy}, publisher = {Elsevier}, issn = {0961-9534}, doi = {10.1016/j.biombioe.2017.05.010}, pages = {11 -- 20}, year = {2017}, language = {en} } @article{JungePuringPiontekSmialkowskietal.2017, author = {Junge Puring, Kai and Piontek, Stefan and Smialkowski, Mathias and Burfeind, Jens and Kaluza, Stefan and Doetsch, Christian and Apfel, Ulf-Peter}, title = {Simple Methods for the Preparation of Non-noble Metal Bulk-electrodes for Electrocatalytic Applications}, series = {Journal of visualized experiments : JoVE}, journal = {Journal of visualized experiments : JoVE}, number = {124}, publisher = {JoVE}, issn = {1940-087X}, doi = {10.3791/56087}, year = {2017}, abstract = {The rock material pentlandite with the composition Fe4.5Ni4.5S8 was synthesized via high temperature synthesis from the elements. The structure and composition of the material was characterized via powder X-ray diffraction (PXRD), M{\"o}ssbauer spectroscopy (MB), scanning electron microscopy (SEM), differential scanning calorimetry (DSC) and energy dispersive X-ray spectroscopy (EDX). Two preparation methods of pentlandite bulk electrodes are presented. In the first approach a piece of synthetic pentlandite rock is directly contacted via a wire ferrule. The second approach utilizes pentlandite pellets, pressed from finely ground powder, which is immobilized in a Teflon casing. Both electrodes, whilst being prepared by an additive-free method, reveal high durability during electrocatalytic conversions in comparison to common drop-coating methods. We herein showcase the striking performance of such electrodes to accomplish the hydrogen evolution reaction (HER) and present a standardized method to evaluate the electrocatalytic performance by electrochemical and gas chromatographic methods. Furthermore, we report stability tests via potentiostatic methods at an overpotential of 0.6 V to explore the material limitations of the electrodes during electrolysis under industrial relevant conditions.}, language = {en} } @article{GirodBreitkreuzHenningetal.2019, author = {Girod, Kai and Breitkreuz, Klaas and Henning, Torsten and Lohmann, Heiko and Kaluza, Stefan and Schluter, Stefan}, title = {Steel Mills as Syngas Source for Methanol Synthesis: Simulation and Practical Performance Investigations}, series = {Chemical Engineering Transactions}, volume = {74}, journal = {Chemical Engineering Transactions}, publisher = {AIDIC}, isbn = {978-88-95608-71-6}, issn = {2283-9216}, doi = {10.3303/CET1974080}, pages = {475 -- 480}, year = {2019}, abstract = {In the present contribution, the utilization of steel-mill gases for an industrial methanol synthesis process is described. The focus of this work is on the influence of syngas compositions derived from steel-mill gases on an industrial Cu/ZnO/Al2O3 catalyst. Elevated CO2 and H2O concentrations seem to have an irreversible impact on the activity of the catalyst. In order to obtain realistic gas composition for the catalyst tests, a process simulation of the methanol synthesis was conducted. The calculated gas compositions at the reactor inlet were applied in a practical test in order to evaluate the catalyst stability under steel mill gas conditions. No noticeable deactivation was observed.}, language = {en} } @article{GirodLohmannSchlueteretal.2020, author = {Girod, Kai and Lohmann, Heiko and Schl{\"u}ter, Stefan and Kaluza, Stefan}, title = {Methanol Synthesis with Steel-Mill Gases: Simulation and Practical Testing of Selected Gas Utilization Scenarios}, series = {Processes}, volume = {8}, journal = {Processes}, number = {12}, publisher = {MDPI}, doi = {10.3390/pr8121673}, url = {http://nbn-resolving.de/urn:nbn:de:hbz:due62-opus-26928}, year = {2020}, language = {en} } @article{NebelSchmidtPanetal.2019, author = {Nebel, Janine and Schmidt, Stefan and Pan, Qiushi and Lotz, Katrin and Kaluza, Stefan and Muhler, Martin}, title = {On the role of cobalt carbidization in higher alcohol synthesis over hydrotalcite-based Co-Cu catalysts}, series = {Chinese Journal of Catalysis}, volume = {40}, journal = {Chinese Journal of Catalysis}, number = {11}, publisher = {Elsevier}, issn = {1872-2067}, doi = {10.1016/S1872-2067(19)63344-9}, pages = {1731 -- 1740}, year = {2019}, language = {en} } @article{SchittkowskiRulandLaudenschlegeretal.2018, author = {Schittkowski, Julian and Ruland, Holger and Laudenschleger, Daniel and Girod, Kai and K{\"a}hler, Kevin and Kaluza, Stefan and Muhler, Martin and Schl{\"o}gl, Robert}, title = {Methanol Synthesis from Steel Mill Exhaust Gases: Challenges for the Industrial Cu/ZnO/Al 2 O 3 Catalyst}, series = {Chemie Ingenieur Technik}, volume = {90}, journal = {Chemie Ingenieur Technik}, number = {10}, publisher = {Wiley}, issn = {1522-2640}, doi = {10.1002/cite.201800017}, url = {http://nbn-resolving.de/urn:nbn:de:hbz:due62-opus-34526}, pages = {1419 -- 1429}, year = {2018}, language = {en} } @book{MarziDeerbergDoetschetal.2017, author = {Marzi, Thomas and Deerberg, G{\"o}rge and D{\"o}tsch, Christian and Grev{\´e}, Anna and Hiebel, Markus and Stefan Kaluza, and Knappertsbusch, Volker and Maga, Daniel and M{\"u}ller, Torsten and Pflaum, Hartmut and Pohlig, Astrid and Renner, Manfred and Seifert, Ulrich and Stießel, Sebastian and Unger, Christoph and Wack, Thorsten and Weidner, Eckhard}, title = {Kohlendioxid, Biomasse und Regenerativer Strom - Ressourcen einer neuen Kohlenstoffwirtschaft?}, volume = {Umsicht-Diskurs}, number = {1}, publisher = {Fraunhofer-Institut f{\"u}r Umwelt-, Sicherheit- und Energietechnik}, address = {Oberhausen}, organization = {Fraunhofer-Institut f{\"u}r Umwelt-, Sicherheit- und Energietechnik}, isbn = {978-3-87468-358-6}, doi = {10.24406/UMSICHT-N-473349}, year = {2017}, language = {de} } @article{WeideSchulzKaluzaetal.2016, author = {Weide, Philipp and Schulz, Katharina and Kaluza, Stefan and Rohe, Markus and Beranek, Radim and Muhler, Martin}, title = {Controlling the Photocorrosion of Zinc Sulfide Nanoparticles in Water by Doping with Chloride and Cobalt Ions}, series = {Langmuir}, volume = {32}, journal = {Langmuir}, number = {48}, publisher = {ACS Publ.}, issn = {1520-5827}, doi = {10.1021/acs.langmuir.6b03385}, pages = {12641 -- 12649}, year = {2016}, language = {en} } @article{WiesmannHamelKaluza2018, author = {Wiesmann, Thomas and Hamel, Christian and Kaluza, Stefan}, title = {Techniques to Remove Traces of Oxygen by Catalytic Conversion from Gas Mixtures}, series = {Chemie Ingenieur Technik}, volume = {90}, journal = {Chemie Ingenieur Technik}, number = {10}, publisher = {Wiley}, issn = {1522-2640}, doi = {10.1002/cite.201800022}, pages = {1446 -- 1452}, year = {2018}, language = {en} }