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Towards to Battery Digital Passport: Reviewing Regulations and Standards for Second-Life Batteries
(2024)
Greenhouse gas emissions from transportation harm the environment. In response to these environmental concerns, numerous countries encourage the adoption of electric vehicles (EVs) as a more environmentally friendly option than traditional gasoline-powered vehicles. Advances in battery technology have made batteries an alternative solution for energy storage in stationary applications and for electric mobility. Reduced lithium-ion batteries (LIBs) production costs due to economies of scale, electrode material and cell design developments, and manufacturing process improvements have driven this success. This trend is expected to increase the number of LIBs on the market that may be discarded in the environment at the end of their useful life if more sustainable alternatives are not technologically mature. This coming environmental concern can be mitigated by collecting wasted EV batteries, reconfiguring them, and reusing them for applications with less stringent weight, performance, and size requirements. This method would extend battery life and reduce environmental effects. The present work investigates the main regulatory structures of the second-life battery industry that require rules, technical standards, and laws. To achieve this objective, a systematic review was carried out following a strict protocol that includes identifying relevant studies, extracting data and information, evaluating, and summarizing information. This paper explains the primary rules and technical standards governing the second-life battery business. The findings highlight the need for universities, research institutions, and government agencies to evaluate the second-life battery industry objectively. This would enable the creation of new technological regulations and laws for this burgeoning industry.
Cooperative Intelligent Transportation Systems have achieved a mature technology stage and are in an early phase of mass deployment in Europe. Relying on Vehicle-to-X communication, these systems were primarily developed to improve traffic safety, efficiency, and driving comfort. However, they also offer great opportunities for other use cases. One of them is forensic accident analysis, where the received data provide details about the status of other traffic participants, give insights into the accident scenario, and therefore help in understanding accident causes. A high accuracy of the sent information is essential: For safety use cases, such as traffic jam warning, a poor accuracy of the data may result in wrong driver information, undermine the usability of the system and even create new safety risks. For accident analysis, a low accuracy may prevent the correct reconstruction of an accident. This paper presents an experimental study of the first generation of Cooperative Intelligent Transportation Systems in Europe. The results indicate a high accuracy for most of the data fields in the Vehicle-to-X messages, namely speed, acceleration, heading and yaw rate information, which meet the accuracy requirements for safety use cases and accident analysis. In contrast, the position data, which are also carried in the messages, have larger errors. Specifically, we observed that the lateral position still has an acceptable accuracy. The error of the longitudinal position is larger and may compromise safety use cases with high accuracy requirements. Even with limited accuracy, the data provide a high value for the accident analysis. Since we also found that the accuracy of the data increases for newer vehicle models, we presume that Vehicle-to-X data have the potential for exact accident reconstruction.
Influence of Blind Spot Assistance Systems in Heavy Commercial Vehicles on Accident Reconstruction
(2024)
Accidents between right-turning commercial vehicles and crossing vulnerable road users (VRUs) in urban environments often lead to serious or fatal injuries and therefore play a significant role in forensic accident analysis. To reduce the risk of accidents, blind spot assistance systems have been installed in commercial vehicles for several years, among other things, to detect VRUs and warn the driver in time. However, since such systems cannot reliably prevent all turning accidents, an investigation by experts must clarify how the accident occurred and to what extent the blind spot assistance system influenced the course of the accident. The occurrence of the acoustic warning message can be defined as an objective reaction prompt for the driver, so that the blind spot assistance system can significantly influence the avoidability assessment. In order to be able to integrate the system into forensic accident analysis, a precise knowledge of how the system works and its limitations is required. For this purpose, tests with different systems and accident constellations were conducted and evaluated. It was found that the type of sensor used for the assistance systems has a great influence on the system’s performance. The lateral distance between the right side of the commercial vehicle and the VRU, as well as obstacles between them, along with the speed difference can have great influence on the reliability of the assistance system. Depending on the concrete time of the system’s warning signal, the accident can be avoided or not by the driver when reacting to this signal.
Battery safety is a prominent concern for the deployment of electric vehicles (EVs). The battery powering an EV contains highly energetic active materials and flammable organic electrolytes. Usually, an EV battery catches fire due to its thermal runaway, either immediately at the time of the accident or can take a while to gain enough heat to ignite the battery chemicals. There are numerous battery abuse testing standards and regulations available globally. Therefore, battery manufacturers are always in dilemma to choose the safest one. Henceforth, to find the optimal outcome of these two major issues, six standards (SAE J2464:2009, GB/T 31485-2015:2015, FreedomCAR:2006, ISO 12405-3:2014, IEC 62660-2:2010, and SAND2017-6295:2017) and two regulations (UN/ECE-R100.02:2013 and GTR 20:2018), that are followed by more than fifty countries in the world, are investigated in terms of their abuse battery testing conditions (crush test). This research proves that there is a need for (a) augmenting these standards and regulations as they do not consider real-life vehicle crash scenarios, and (b) one harmonised framework should be developed, which can be adopted worldwide. These outcomes will solve the battery manufacturers dilemma and will also increase the safety of EV consumers.
With the upcoming new legislative rules in the EU on Event Data Recorder beginning 2022 the question is whether the discussed data base is sufficient for the needs of clarifying accidents involving automated vehicles. Based on the reconstruction of real accidents including vehicles with ADAS combined with specially designed crash tests a broader data base than US EDR regulation (NHTSA 49 CFR Part 563.7) is proposed. The working group AHEAD, to which the authors contribute, has already elaborated a data model that fits the needs of automated driving. The structure of this data model is shown. Moreover, the special benefits of storing internal video or photo feeds form the vehicle camera systems combined with object data is illustrated. When using a sophisticate 3D measurement method of the accident scene the videos or photos can also serve as a control instance for the stored vehicle data. The AHEAD Data Model enhanced with the storage of the video and photo feeds should be considered in the planned roadmap of the Informal Working Group (IWG) on EDR/ DSSAD (Data Storage System for Automated Driving) reporting to UNECE WP29. Also, a data access over the air using technology already applied in China for electric vehicles called Real Time Monitoring would allow a quantum leap in forensic accident reconstruction.
Available energy and available capacity are key factors for dimensioning batteries. Discharge duration of a battery and its dependency on discharge current amplitude are well described by Peukert’s law from low to medium current ranges. Other equations describe this dependency up to very high current rates, including the currents occurring during a short circuit. It is not current and capacity, but energy and power which are the key parameters for dimensioning battery systems. Thus, the available power of battery cells, vs. the discharge duration was investigated from low to high constant power discharge loads. Based on the results of these experiments, a correlation of the maximum discharge duration for low to medium discharge power pulses, similar to the Peukert’s equation was found. Additionally, a new equation is proposed, describing the power range from low to very high discharge power rates.
The result of this work simplifies the design of battery systems, its electromechanical components, as well as improves the prediction of available boost power cost-effective way e.g. for hybrid electric vehicles.
In this analysis, Cooperative Intelligent Transportation System relevant scenarios are created to investigate the need to differentiate Vehicle-to-X transmission technologies on behalf of accident analysis. For each scenario, the distances between the vehicles are calculated 5 s before the crash. Studies on the difference between Dedicated Short-Range Communication (IEEE 802.11p) and Cellular Vehicle-to-X communication (LTE-V2C PC5 Mode 4) are then used to assess whether both technologies have a reliable connection over the relevant distance. If this is the case, the transmission technology is of secondary importance for future investigations on Vehicle-to-X communication in combination with accident analysis. The results show that studies on freeways and rural roads can be carried out independently of the transmission technology and other boundary conditions (speed, traffic density, non-line of sight/line of sight). The situation is different for studies in urban areas, where both technologies may not have a sufficiently reliable connection range depending on the traffic density.
The derivation of real accident scenarios from accident databases represents an important task within vehicle safety research. Simulations are increasingly used for this purpose. Depending on the research interest, a wide range of accident databases exists worldwide, which differ mainly in the number of recorded data per accident and availability. This work aims to identify critical vehicle-to-vehicle accidents based on freely available accident databases to derive concrete scenarios for a subsequent simulation. For this purpose, the method of the pre-crash matrix is applied using the example of the freely available Crash Investigation Sampling System database of the National Highway Traffic Safety Administration. An analysis of existing databases worldwide shows that this is the most detailed, freely available database. The derivation of scenarios succeeds here by a new method, whereby a center of gravity calculation is carried out based on the damages of the vehicles according to Collision Deformation Classification nomenclature. In addition, the determination of other necessary parameters, as well as the limits of the database, is shown in order to derive a scenario that can be simulated. As a result, the constellations of the five most frequent vehicle-to-vehicle accident scenarios according to the Crash Investigation Sampling System database are presented. In particular, other institutions should follow National Highway Traffic Safety Administration’s example and make data freely available for accident research.
Contribution: Prior studies comparing the effectiveness of different laboratory learning modes do not allow one to draw a universally valid conclusion, as other influences are mixed with the learning modes. In order to contribute to the existing body of work and to add another piece to the puzzle, this article demonstrates an improved methodology to evaluate the effectiveness of computer-simulated laboratories in comparison to hands-on exercises using a battery basics practical course as a case study.
Background: Computer-simulated experiments are becoming increasingly popular for conducting laboratory exercises in higher education and vocational training institutions. To ensure the consistent quality of laboratory learning, an accurate comparison between the results of simulated experiments and practical hands-on experiments is required.
Intended Outcomes: In this article, the achievement of the following learning objectives were compared between the two laboratory modes: 1) comprehension of the most important parameters of battery cells and 2) knowledge on how these parameters can be determined using adequate experimental procedures.
Application Design: To avoid interference of factors other than laboratory mode on the learning, laboratory instructions and experimental interfaces ensured identical execution of the experiments in the compared modes. Using a counterbalanced methodology, the two laboratory modes alternated by the session, while the experimental procedures remained constant regardless of the respective modes.
Findings: Tests taken by the participants after conducting the laboratory experiments revealed that hands-on laboratories resulted in statistically significantly better student performance than simulated laboratories. This difference was even more pronounced for the participants that finished a vocational education and training program before the university studies.
In the near future, electric powered vehicles will represent a major part of the road traffic. Accordingly, there will be a natural increase of accidents involving electric vehicles. There are not many cases of such accidents yet and therefore the experience and correct handling are still partially open points for the involved parties, such as the rescue services for example. The aim of this work is to provide a complete overview of the accident handling sequence in Germany, starting with the damaged vehicle on site and moving on to the risks and challenges for the stakeholders, such as transport and recycling companies. Arising from the developed overview, a handling recommendation for yet undiscussed points is given. Especially, different extinguishing and deactivation methods are compared and discussed. Due to a lack of a common live-feed from battery data on site, other criteria have to be taken into account to assess the state of the battery. The wrecked vehicle—including the high voltage system—needs to be in a definite safe state at the handover to a towing service. Depending on the case, different options for securing the vehicle will be considered in this work.
It is a fact that electric vehicles (EVs) are beneficial for climate protection. However, the current challenge is to decide on whether to reuse an EV battery or to recycle it after its first use. This paper theoretically investigates these areas i.e., recycle and reuse. It was found that there are several commercially used recycling processes and also some are under research to regain maximum possible materials and quantity. The concept of reusing (second life) of the battery is promising because, at the end of the first life, batteries from EVs can be used in several applications such as storing energy generated from renewable sources to support the government grid. However, the cost and life-cycle analysis (LCA) demonstrated that there are several aspects involved in battery reuse applications. Henceforth, one LCA generalised method cannot provide an optimal approach for all cases. It is important to have a detailed study on each of the battery reusing applications. Until then, it is safe to say that reusing the battery is a good option as it would give some time to recycling companies to develop cost and energy-efficient methods.
Lithium-ion traction battery systems of hybrid and electric vehicles must have a high level of durability and reliability like all other components and systems of a vehicle. Battery systems get heated while in the application. To ensure the desired life span and performance, most systems are equipped with a cooling system. The changing environmental condition in daily use may cause water condensation in the housing of the battery system. In this study, three system designs were investigated, to compare different solutions to deal with pressure differences and condensation: (1) a sealed battery system, (2) an open system and (3) a battery system equipped with a pressure compensation element (PCE). These three designs were tested under two conditions: (a) in normal operation and (b) in a maximum humidity scenario. The amount of the condensation in the housing was determined through a change in relative humidity of air inside the housing. Through PCE and available spacing of the housing, moisture entered into the housing during the cooling process. While applying the test scenarios, the gradient-based drift of the moisture into the housing contributed maximum towards the condensation. Condensation occurred on the internal surface for all the three design variants.
The degradation of lithium-ion cells is an important aspect, not only for quality management, but also for the customer of the application like, e.g., scooters or electric vehicles. During the lifetime of the system, the overall health on the battery plays a key role in its depreciation. Therefore, it is necessary to monitor the health of the battery during operation, i.e., cycle life, but also during stationary conditions, i.e., calendar aging. In this work, the degradation due to calendar aging is analyzed for six different cell chemistries in terms of capacity degradation and impedance increase and their performance are being compared. In a new proposed metric, the relative deviations between various cells with the exact identical aging history are being analyzed for their degradation effects and their differences, which stands out in comparison to similar research. The capacity loss was found to be most drastic at 60 °C and at higher storage voltages, even for titanate-oxide cells. LiNiMnCoO2 (NMC), LiNiCoAlO2 (NCA) and Li2TiO3 (LTO) cells at 60 °C showed the most drastic capacity decrease. NMC and NCA cells at 60 °C and highest storage voltage did not show any open circuit voltage, as their current interrupt mechanism triggered. The effect of aging shows no uniform impact on the changes in the capacity variance when comparing different aging conditions, with respect to the evaluated standard deviation for all cells. The focus of this work was on the calendar aging effect and may be supplemented in a second study for cyclic aging.
Nowadays, batteries for electric vehicles are expected to have a high energy density, allow fast charging and maintain long cycle life, while providing affordable traction, and complying with stringent safety and environmental standards. Extensive research on novel materials at cell level is hence needed for the continuous improvement of the batteries coupled towards achieving these requirements. This article firstly delves into future developments in electric vehicles from a technology perspective, and the perspective of changing end-user demands. After these end-user needs are defined, their translation into future battery requirements is described. A detailed review of expected material developments follows, to address these dynamic and changing needs. Developments on anodes, cathodes, electrolyte and cell level will be discussed. Finally, a special section will discuss the safety aspects with these increasing end-user demands and how to overcome these issues.
Due to growing numbers of sold HEV (hybrid electric vehicles), PHEV (plug-in hybrid electric vehicles), and BEV (battery electric vehicles), new market opportunities to reuse or recycle old lithium ion batteries arise. Thus, a forecast of available batteries caused by accidents or from end-of-life vehicles was carried out using a mathematical model. Input data were obtained from an estimate of newly registered hybrid and electric vehicles in Germany from 2010 until 2030, from the accident rate of cars in Germany, and from the average cars’ lifetime. The results indicate that (a) the total amount of available second use batteries in 2030 will be between 130,000 units/year and 500,000 units/year, (b) the highest amount of batteries will be obtained from end-of-life vehicles not from accident vehicles, although most batteries from accident vehicles will be suitable for 2nd use, and (c) the quantity of hybrid, plug-in hybrid, and electric car batteries available for reuse will continue to rise after 2030.
Nowadays, lithium ion batteries have found their place in a various field of portable applications. With the upcoming of electrically propelled vehicles, it is mandatory to guarantee a safe and predictable behavior during the whole lifetime and not only after manufacturing during performance tests. To gain a general overview of the abuse behavior, research on the topic of abusive tests on calendar-aged cells is being investigated, split up depending on the electrode composition and lined up against each other. It can be shown, that almost all abuse experiments have been performed with external heating tests in the past, still leaving research gaps that need to be filled.
Electrically propelled cars will play a major role on the streets, not only in the far, but also in the near future. In this work, an overview on the possible risks arising from electric vehicles is given that involves electrical, chemical and thermal hazards. Additionally, an analysis on different scenarios involving damaged electric vehicles, the involved parties, as well as their risk assessment in terms of hazard rating is presented. Furthermore, two scenarios are explained and addressed with more detail. With the derived risks of the battery and with possible crash scenarios presented, the still existing uncertainties for handling damaged electric vehicles are addressed, followed by a discussion on ways to overcome this problem.
CONTEXT Many universities and vocational training institutions conduct laboratories as simulated experiments. This is due to the costs and supervision needs to conduct hands-on labs safely. Numerous studies have presented mixed opinions on whether hands-on laboratory work is more conducive to learning than a simulated laboratory. Most of the studies put students from experimental and control groups in significantly different conditions. Therefore, it is hard to reach any definite conclusion regarding the influence of the learning mode onto the learning achievements.
PURPOSE This study compares learning outcomes of student laboratory work in an energy storages course conducted in two different modes: first as a practical hands-on exercise and second using computer-based simulations.
APPROACH In order to provide reliable insights, this study implements optimized research methodology to avoid any other effect (e.g. learning synchronicity/distance learning/instructions) on the learning outcome rather than the effect of the learning mode itself. The student laboratory experiments were created in a manner that they could be conducted in both modes in the same way and using a single set of instructions. To ensure a comparable group environment for the individual student, the students were arranged into two similar groups based on the student's practical experience. In this crossover study, the groups were taught the same topics by means of interchanging learning modes.
RESULTS To evaluate the influence of each mode on student learning, short written tests regarding the previous experiment were conducted at the beginning of the subsequent laboratory session. 102 students have taken part in the study in two years. Overall learning results of hands-on experiments were slightly better than those of simulated laboratories (Cohen's d=0.25), the difference in performance was statistically significant (p<0.02). Through solicited feedback on each laboratory session, in hands-on mode more students expressed they have acquired new insights/comprehensions (76% vs. 66%, Cohen's d=0.23, small effect, p<0.07).
CONCLUSIONS Following the strategy not to optimize the lessons individually to the learning mode, other influences on the learning outcome, which were usually mixed, were excluded. The students' subjective opinions show advantages of the hands-on mode. Based on the objective data, a weak, but significant outcome to better knowledge acquisition with hands-on laboratory experiments was achieved. This observation is against the trend of the literature in the last years towards better or equal learning with nontraditional labs. Some of the excluded factors might have a stronger influence on student learning than estimated previously. To get a clear view, the authors recommend isolated research.
In 1897 Wilhelm Peukert tested lead-acid batteries with constant current and observed that a single equation can describe the relationship between the discharge capacity of the battery and a constant discharge current. In this article the dependence of the discharge capacity of lithium-ion battery cells, electrochemical double-layer capacitors and lithium capacitors are investigated from low to very high discharge rates. From low to intermediate discharge rates, these energy storage devices show ideal Peukert behavior, but a deviation was observed at high discharge rates. The cells provide less charge than predicted by Peukert’s Law. To describe this deviation, a new equation has been derived by expanding Peukert’s law to very discharge rates. It is capable to describe the discharge behavior of lithium-ion battery cells, electrochemical double-layer capacitors and lithium capacitors from low to high discharge rates in an unequivocal way.
The relevance of scientific investigations, whether simulative or empirical, is strongly related to the environment used and the scenarios associated with it. Within the field of cooperative intelligent transport systems, use-cases are defined to describe the benefits of applications. This has already been conducted in the available safety-relevant Day 1 applications longitudinal and intersection collision risk warning through the respective technical specifications. However, the relevance of traffic scenarios is always a function of accident severity and frequency of a retrospective consideration of accident databases. In this study, vehicle-to-vehicle scenarios with high frequency and/or severe personal injuries are therefore determined with the help of the CISS database and linked to the use-cases of the safety-relevant Day 1 applications. The relevance of the scenarios thus results on the one hand from the classical parameters of retrospective accident analysis and on the other hand from the coverage by the named vehicle-to-x applications. As a result, accident scenarios with oncoming vehicles are the most relevant scenarios for investigations with cooperative intelligent transport systems. In addition, high coverage of the most critical scenarios within the use-cases of longitudinal and intersection collision risk warning is already apparent.
Cooperative Intelligent Transport Systems have been deployed in mass-produced vehicles in Europe (Golf 8, ID.3, etc.) since 2019, promising major improvements in vehicle safety, efficiency, and comfort. Equipped with Vehicle-to-X communication, the vehicles directly send information about their driving status to the environment. The data are already used for many Vehicle-to-X communication use-cases specified by the Car-2-Car Communication Consortium to achieve the above-mentioned improvements. This study focuses on using Vehicle-2-X communication and its messages for accident analysis. For this purpose, we investigated the advantage in temporal resolution of the continuously sent Cooperative Awareness Message compared to the Event-Data-Recorder for accident reconstruction in the pre-crash. A high resolution of the temporal accident scene is essential for the doubtless clarification of accidents. Therefore, we analyzed the generation frequencies and the trigger conditions of the Cooperative Awareness Message of vehicles available on the European market while driving in real traffic and during different parking maneuvers. Also, the pseudonym change was analyzed. We found that the average generation frequency of the Cooperative Awareness Message is higher than the 2.00 Hz recording frequency of the event data recorder for all scenarios investigated. Especially on rural roads and highways, the temporal resolution is advantageous. Since many serious accidents occur on rural roads, the use of Cooperative Awareness Messages could significantly benefit the reconstruction of the accident scene. Thus, we recommend increasing efforts to use the Cooperative Awareness Message as digital data for accident analysis and encourage more scientists to deal with this topic.
Partially automated driving functions (SAE Level 2) can control a vehicle’s longitudinal and lateral movements. However, taking over the driving task involves automation risks that the driver must manage. In severe accidents, the driver’s ability to avoid a collision must be assessed, considering their expected reaction behavior. The primary goal of this study is to generate essential data on driver reaction behavior in case of malfunctions in partially automated driving functions for use in legal affairs. A simulator study with two scenarios involving 32 subjects was conducted for this purpose. The first scenario investigated driver reactions to system limitations during cornering. The results show that none of the subjects could avoid leaving their lane and moving into the oncoming lane and, therefore, could not control the situation safely. Due to partial automation, we could also identify a new part of the reaction time, the hands-on time, which leads to increased steering reaction times of 1.18 to 1.74 s. The second scenario examined driver responses to phantom braking caused by AEBS. We found that 25 of the 32 subjects could not override the phantom braking by pressing the accelerator pedal, although 16 subjects were informed about the system analog to the actual vehicle manuals. Overall, the study suggests that the current legal perspective on vehicle control and the expected driver reaction behavior for accident avoidance should be reconsidered.
Partially automated driving functions (SAE Level 2) can control a vehicle's longitudinal and lateral movements. However, taking over the driving task involves automation risks that the driver must manage. In severe accidents, the driver's ability to avoid a collision must be assessed, considering their expected reaction behavior. The primary goal of this study is to generate essential data on driver reaction behavior in case of malfunctions in partially automated driving functions for use in legal affairs. A simulator study with two scenarios involving 32 subjects was conducted for this purpose. The first scenario investigated driver reactions to system limitations during cornering. The second scenario examined driver responses to phantom braking caused by the AEBS. As a result, the first scenario shows that none of the subjects could control the situation safely. Due to partial automation, we could also identify a new part of the reaction time, the hands-on time, which leads to increased steering reaction times of 1.18 to 1.74 seconds. In the second scenario, we found that 25 of the 32 subjects could not override the phantom braking by pressing the accelerator pedal, although 16 subjects were informed about the system analog to the actual vehicle manuals. Overall, the study suggests that the current legal perspective on vehicle control and the expected driver reaction behavior for accident avoidance should be reconsidered.
Possibilities for a Quick Onsite Safety-State Assessment of Stand-Alone Lithium-Ion Batteries
(2022)
Electric vehicles’ high-voltage lithium-ion batteries are complex systems and can be sources of several hazards for interacting people. Sophisticated battery management systems (BMS) therefore constantly monitor their characteristics and varying states, to keep the battery within desired operational conditions and to mitigate safety risks as well as excessive degradation. However, there can be several situations where the battery is not in normal operation (e.g., a stand-alone battery) and a fully functional BMS monitoring function is not available. When necessary to interact with the system, its safety state must be deduced to ensure the safety of interactors. This can be a challenging task depending on a situation’s characteristics (time pressure, technical knowledge of involved people). Thus, this article discusses how the safety state of electric vehicle batteries can be evaluated quickly even by untrained people. To develop a solution, different scenarios, which require a battery’s state assessment, and the options for collecting relevant information are motivated and discussed, respectively. Finally, a mobile interface that can evaluate and display the safety state by using BMS-internal data is described and demonstrated.
Calculating Available Charge and Energy of Lithium-Ion Cells Based on OCV and Internal Resistance
(2022)
The design and operation of performant and safe electric vehicles depend on precise knowledge of the behavior of their electrochemical energy storage systems. The performance of the battery management systems often relies on the discrete-time battery models, which can correctly emulate the battery characteristics. Among the available methods, electric circuit-based equations have shown to be especially useful in describing the electrical characteristics of batteries. To overcome the existing drawbacks, such as discrete-time simulations for parameter estimation and the usage of look-up tables, a set of equations has been developed in this study that solely relies on the open-circuit voltage and the internal resistance of a battery. The parameters can be obtained from typical cell datasheets or can be easily extracted via standard measurements. The proposed equations allow for the direct analytical determination of available discharge capacity and the available energy content depending on the discharge current, as well as the Peukert exponent. The fidelity of the proposed system was validated experimentally using 18650 NMC and LFP lithium-ion cells, and the results are in close agreement with the datasheet.
Laboratory learning
(2019)
The deployment of battery-powered electric vehicles in the market has created a naturally increasing need for the safe deactivation and recycling of batteries. Various deactivating methods for lithium-ion cells include electrical discharging or deactivation with liquids. Such methods are also useful for cases where the cell tabs are not accessible. In the literature analyses, different deactivation media are used, but none include the use of calcium chloride (CaCl2) salt. As compared to other media, the major advantage of this salt is that it can capture the highly reactive and hazardous molecules of Hydrofluoric acid. To analyse the actual performance of this salt in terms of practicability and safety, this experimental research aims to compare it against regular Tap Water and Demineralized Water. This will be accomplished by performing nail penetration tests on deactivated cells and comparing their residual energy against each other. Moreover, these three different media and respective cells are analysed after deactivation, i.e., based on conductivity measurements, cell mass, flame photometry, fluoride content, computer tomography and pH value. It was found that the cells deactivated in the CaCl2 solution did not show any signs of Fluoride ions, whereas cells deactivated in TW showed the emergence of Fluoride ions in the 10th week of the insertion. However, with the addition of CaCl2 in TW, the deactivation process > 48 h for TW declines to 0.5–2 h, which could be an optimal solution for real-world situations where deactivating cells at a high pace is essential.