TY - INPR A1 - Rufino Júnior, Carlos Antônio A1 - Riva Sanseverino, Eleonora A1 - Gallo, Pierluigi A1 - Amaral, Murilo Machado A1 - Koch, Daniel A1 - Kotak, Yash A1 - Diel, Sergej A1 - Walter, Gero A1 - Schweiger, Hans-Georg A1 - Zanin, Hudson T1 - A Comprehensive Review of EV Lithium-Ion Battery Degradation N2 - Lithium-ion batteries with improved energy densities have made understanding the Solid Electrolyte Interphase (SEI) generation mechanisms that cause mechanical, thermal, and chemical failures more complicated. SEI processes reduce battery capacity and power. Thus, a review of this area's understanding is important. It is essential to know how batteries degrade in EVs to estimate battery lifespan as it goes, predict, and minimize losses, and determine the ideal time for a replacement. Lithium-ion batteries used in EVs mainly suffer two types of degradation: calendar degradation and cycling degradation. Despite the existence of several existing works in the literature, several aspects of battery degradation remain unclear or have not been analyzed in detail. This work presents a systematic review of existing works in the literature. The results of the present investigation provide insight into the complex relationships among various factors affecting battery degradation mechanisms. Specifically, this systematic review examined the effects of time, side reactions, temperature fluctuations, high charge/discharge rates, depth of discharge, mechanical stress, thermal stress, and the voltage relationship on battery performance and longevity. The results revealed that these factors interact in complex ways to influence the degradation mechanisms of batteries. For example, high charge currents and deep discharges were found to accelerate degradation, while low temperatures and moderate discharge depths were shown to be beneficial for battery longevity. Additionally, the results showed that the relationship between cell voltage and State-of-Charge (SOC) plays a critical role in determining the rate of degradation. Overall, these findings have important implications for the design and operation of battery systems, as they highlight the need to carefully manage a range of factors to maximize battery performance and longevity. The result is an analysis of the main articles published in this field in recent years. This work aims to present new knowledge about fault detection, diagnosis, and management of lithium-ion batteries based on battery degradation concepts. The new knowledge is presented and discussed in a structured and comprehensive way. UR - https://doi.org/10.20944/preprints202306.0228.v2 Y1 - 2023 UR - https://doi.org/10.20944/preprints202306.0228.v2 UR - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:573-58428 PB - Preprints CY - Basel ER - TY - JOUR A1 - Hußenether, Thomas A1 - Rufino Júnior, Carlos Antônio A1 - Selaibe Pires, Tomás A1 - Mishra, Tarani A1 - Nahar, Jinesh A1 - Vaghani, Akash A1 - Polzer, Richard A1 - Diel, Sergej A1 - Schweiger, Hans-Georg T1 - Analysis of the Measurement Uncertainties in the Characterization Tests of Lithium-Ion Cells JF - Energies N2 - The transition to renewable energy systems and electric mobility depends on the effectiveness, reliability, and durability of lithium-ion battery technology. Accurate modeling and control of battery systems are essential to ensure safety, efficiency, and cost-effectiveness in electric vehicles and grid storage. In engineering and materials science, battery models depend on physical parameters such as capacity, energy, state of charge (SOC), internal resistance, power, and self-discharge rate. These parameters are affected by measurement uncertainty. Despite the widespread use of lithium-ion cells, few studies quantify how measurement uncertainty propagates to derived battery parameters and affects predictive modeling. This study quantifies how uncertainty in voltage, current, and temperature measurements reduces the accuracy of derived parameters used for simulation and control. This work presents a comprehensive uncertainty analysis of 18650 format lithium-ion cells with nickel cobalt aluminum oxide (NCA), nickel manganese cobalt oxide (NMC), and lithium iron phosphate (LFP) cathodes. It applies the law of error propagation to quantify uncertainty in key battery parameters. The main result shows that small variations in voltage, current, and temperature measurements can produce measurable deviations in internal resistance and SOC. These findings challenge the common assumption that such uncertainties are negligible in practice. The results also highlight a risk for battery management systems that rely on these parameters for control and diagnostics. The results show that propagated uncertainty depends on chemistry because of differences in voltage profiles, kinetic limitations, and temperature sensitivity. This observation informs cell selection and testing for specific applications. Improved quantification and control of measurement uncertainty can improve model calibration and reduce lifetime and cost risks in battery systems. These results support more robust diagnostic strategies and more defensible warranty thresholds. This study shows that battery testing and modeling should report and propagate measurement uncertainty explicitly. This is important for data-driven and physics-informed models used in industry and research. UR - https://doi.org/10.3390/en19030825 Y1 - 2026 UR - https://doi.org/10.3390/en19030825 UR - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:573-66630 SN - 1996-1073 VL - 19 IS - 3 PB - MDPI CY - Basel ER - TY - JOUR A1 - Rufino Júnior, Carlos Antônio A1 - Riva Sanseverino, Eleonora A1 - Gallo, Pierluigi A1 - Amaral, Murilo Machado A1 - Koch, Daniel A1 - Kotak, Yash A1 - Diel, Sergej A1 - Walter, Gero A1 - Schweiger, Hans-Georg A1 - Zanin, Hudson T1 - Unraveling the Degradation Mechanisms of Lithium-Ion Batteries JF - Energies N2 - Lithium-Ion Batteries (LIBs) usually present several degradation processes, which include their complex Solid-Electrolyte Interphase (SEI) formation process, which can result in mechanical, thermal, and chemical failures. The SEI layer is a protective layer that forms on the anode surface. The SEI layer allows the movement of lithium ions while blocking electrons, which is necessary to prevent short circuits in the battery and ensure safe operation. However, the SEI formation mechanisms reduce battery capacity and power as they consume electrolyte species, resulting in irreversible material loss. Furthermore, it is important to understand the degradation reactions of the LIBs used in Electric Vehicles (EVs), aiming to establish the battery lifespan, predict and minimise material losses, and establish an adequate time for replacement. Moreover, LIBs applied in EVs suffer from two main categories of degradation, which are, specifically, calendar degradation and cycling degradation. There are several studies about battery degradation available in the literature, including different degradation phenomena, but the degradation mechanisms of large-format LIBs have rarely been investigated. Therefore, this review aims to present a systematic review of the existing literature about LIB degradation, providing insight into the complex parameters that affect battery degradation mechanisms. Furthermore, this review has investigated the influence of time, C-rate, depth of discharge, working voltage window, thermal and mechanical stresses, and side reactions in the degradation of LIBs. UR - https://doi.org/10.3390/en17143372 Y1 - 2024 UR - https://doi.org/10.3390/en17143372 UR - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:573-49089 SN - 1996-1073 VL - 17 IS - 14 PB - MDPI CY - Basel ER - TY - JOUR A1 - Walter, Gero A1 - Diel, Sergej A1 - Rufino Júnior, Carlos Antônio A1 - Schweiger, Hans-Georg A1 - Valente de Bessa, Iury A1 - Mallmann, Maíra A1 - Kirsten Vidal de Oliveira, Aline A1 - Odilio Dos Santos, Daniel A1 - Rüther, Ricardo T1 - Operating Behavior of a Photovoltaic-driven Electrolysis System JF - Revista Brasileira de Energia Solar UR - https://doi.org/10.59627/rbens.2024v15i1.456 Y1 - 2024 UR - https://doi.org/10.59627/rbens.2024v15i1.456 SN - 2526-2831 VL - 15 IS - 1 SP - 82 EP - 92 PB - ABENS CY - São Paulo ER -