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- Femtosekundenlaser (7)
- Bragg-Reflektor (6)
- Laserbearbeitung (4)
- Ultrakurzzeitlaser (4)
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- Gassensor (2)
- Kohlendioxidlaser (2)
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- cyclic olefin copolymers (2)
Year of publication
- 2020 (19) (remove)
Document Type
- Article (12)
- Conference Proceeding (6)
- Other (1)
This contribution reviews recent advancements, current research and possible applications of polymer planar Bragg grating (PPBG) sensors with a focus on the utilization of cyclic olefin copolymer (COC) substrates. COC-PPBGs can be handled and fabricated efficiently by employing a single writing step procedure which features simultaneous generation of waveguide and Bragg grating structure within an injection molded substrate. The resulting photonic structures exhibit an attenuation as low as 1.2 dB cm-1 and a reflectivity up to 99 %. The potential of COC-PPBGs for high-temperature applications is proven by demonstrating temperature measurements up to 160 °C. Moreover, it is possible to employ single PPBGs for multidimensional stress and strain sensing or even three-dimensional shape reconstruction. Due to their excellent properties, it is feasible to integrate COC-PPBGs into commercial-grade carbon fiber reinforced polymer workpieces for structural health monitoring. Furthermore, utilization of appropriate coatings enables functionalization of PPBGs for refractive index sensing and thus biochemical applications. Beside the fabrication and characterization of COC-based PPBGs, this contribution exemplifies and reviews such applications.
We report on a femtosecond laser based fabrication technique that enables simultaneous single-step generation of optical waveguides and Bragg gratings inside bulk cyclic olefin copolymers. Due to the nonlinear absorption of focused and spatially modulated laser radiation with a wavelength of 514 nm and a pulse duration of 450 fs, a modification concluding a refractive index shift increase inside the substrate can be achieved. A sophisticated characterization of the generated waveguides by means of an elaborate cut-back method reveals a maximum attenuation of 3.2 dB/cm. Additionally, a Mach-Zehnder interferometer is used to examine the waveguide’s refractive index profile. The integrated Bragg grating structures exhibit reflectivities up to 95 % and a spectral full width at half maximum of 288 pm, at a Bragg wavelength of 1582 nm, whereas the grating period can be deliberately chosen by adapting the fabrication parameters. Thus, due to its increased flexibility and the resulting dispensability of cost-intensive phase masks, this method constitutes an especially promising fabrication process for polymer Bragg gratings inside of bulk materials.
We report on femtosecond laser direct writing of electrically conductive copper structures on transparent cyclic olefin copolymer based planar optical chips. The process is based on a laser-induced reduction of CuO nanoparticles dissolved in a water-soluble resin. Thus generated conductive copper structures are characterized with respect to their chemical composition and electrical resistivity. In addition, the application of ultrashort laser pulses enables a hybrid micromachining approach comprising ablation of polymer substrates and the fabrication of copper patterns in a single laser processing setup. A possible electro-optical application of this approach is demonstrated by employing the copper structures as an electro-thermal microheater in combination with a polymer planar optical Bragg grating sensor. This, in turn, highlights the potential of generating copious micro-opto-electro-mechanical polymer structures for numerous sensing applications ranging from Lab-on-Chip to environmental applications using the presented hybrid micromachining approach.
We report on the fabrication of rotationally symmetrical geometries with ultrashort laser pulses impinging the constant rotating workpiece tangentially. This particular micro machin-ing of geometry is referred to as laser turning, upon which the laser beam is, in general, orient-ed perpendicularly to the rotational axis and tangentially to the work piece. The target geome-try is realized by moving the constantly rotating specimen according to the specified geometry along the focused laser spot. In contrast to mechanical turning, laser turning induces a mini-mized amount of lateral forces through friction that might deteriorate the geometry. In this study, laser turning is examined for stellite as a function of pulse energy and pulse length in the range between 240 fs and 10 ps. Shorter pulse lengths and higher pulse energies increase the achievable ablation rate, while in the pulse length regime of below 1 ps lower roughness is achieved. With a maximum ablation rate of 1.27 mm³/min and a minimum roughness of 0.17 µm, laser turning combines both, fast processing and high surface quality.
Hypersensitive H2 sensor based on polymer planar Bragg gratings coated with Pt-loaded WO3-SiO2
(2020)
This letter demonstrates a novel hydrogen sensor based on a polymer planar Bragg grating coated with Pt-loaded WO3-SiO2. The reflected Bragg signal shows a distinct peak splitting correlated to substrate anisotropies originating from the injection molding process. Especially at low H2 concentrations, both sensing peaks
exhibit an outstanding response to the heat generated by the exothermic reaction between hydrogen molecules and coating. Thereby, a hydrogen volume ratio of 50 ppm
leads to a Bragg wavelength shift of -37 pm, which yields an outstandingly low detection limit of only 5 ppm H2 in air. Thus, functionalized polymer planar Bragg gratings are eminently suitable for H2 leak detection applications.