@article{WisselFreudenmannCichockaetal.2024, author = {Wissel, Julian and Freudenmann, Dominic and Cichocka, Magdalena Ola and P{\"o}hl, Almut and Stephan-Hofmann, Iris and R{\"o}cke, Nicole and P{\´e}rez, Nicol{\´a}s and D{\"o}hring, Thorsten and Stadtm{\"u}ller, Johannes and Stollenwerk, Manfred}, title = {Microstructure of highly effective platinum-iridium alloys as catalysts for hydrogen peroxide decomposition}, series = {Research on Chemical Intermediates}, volume = {50}, journal = {Research on Chemical Intermediates}, number = {11}, publisher = {Springer Science and Business Media LLC}, issn = {0922-6168}, doi = {10.1007/s11164-024-05412-4}, pages = {5385 -- 5397}, year = {2024}, subject = {Iridium}, language = {en} } @article{AmorimSperaNicoaraetal.2024, author = {Amorim, Isilda and Spera, Natalia C.M. and Nicoara, Nicoleta and Ramasamy, Devaraj and Alves, Diana F. and Stollenwerk, Manfred and Stadtm{\"u}ller, Johannes and D{\"o}hring, Thorsten and Sadewasser, Sascha and Kolen'ko, Yury V. and Sousa, Juliana P.S.}, title = {Overall alkaline water electrolysis over active, stable, low loading iridium catalysts sputtered on nickel foam}, series = {International Journal of Hydrogen Energy}, volume = {92}, journal = {International Journal of Hydrogen Energy}, publisher = {Elsevier BV}, issn = {0360-3199}, doi = {10.1016/j.ijhydene.2024.10.306}, pages = {852 -- 864}, year = {2024}, subject = {Iridium}, language = {en} } @article{SchmittFeldeDoehringetal.2022, author = {Schmitt, Paul and Felde, Nadja and D{\"o}hring, Thorsten and Stollenwerk, Manfred and Uschmann, Ingo and Hanemann, Kevin and Siegler, Marie and Klemm, Georg and Gratzke, Nancy and T{\"u}nnermann, Andreas and Schwinde, Stefan and Schr{\"o}der, Sven and Szeghalmi, Adriana}, title = {Optical, structural, and functional properties of highly reflective and stable iridium mirrorcoatings for infrared applications: supplement}, series = {Optical Materials Express}, volume = {2022}, journal = {Optical Materials Express}, number = {12/2}, doi = {10.6084/m9.figshare.17121509}, pages = {545 -- 559}, year = {2022}, abstract = {Metallic coatings are essential for numerous optical systems due to their high and broadband refl ectivity in the infrared spectral range. In contrast to well-established (protected)silver and gold mirror coatings, iridium is environmentally durable, referring to ISO 9211-3 and thermally stable up to 600 °C even without protective layers, as demonstrated. Additionally,the optical and related structural properties of atomic layer deposited (ALD) and magnetron sputtered (MS) Ir coatings were investigated using spectrophotometry, FTIR, ellipsometry, WLI, AFM, XRR, XRD, SEM, and electrical resistivity measurements. The properties of Ir ALD and Ir MS coatings diff er due to their topography and microstructure.}, subject = {Iridium}, language = {en} } @article{SchmittFeldeDoehringetal.2022, author = {Schmitt, Paul and Felde, Nadja and D{\"o}hring, Thorsten and Stollenwerk, Manfred and Uschmann, Ingo and Hanemann, Kevin and Siegler, Marie and Klemm, Georg and Gratzke, Nancy and T{\"u}nnermann, Andreas and Schwinde, Stefan and Schr{\"o}der, Sven and Szeghalmi, Adriana}, title = {Optical, structural, and functional properties of highly reflective and stable iridium mirror coatings for infrared applications}, series = {Optical Materials Express}, volume = {2022}, journal = {Optical Materials Express}, number = {12 / 2}, doi = {10.1364/OME.447306}, pages = {545 -- 559}, year = {2022}, abstract = {Metallic coatings are essential for numerous optical systems due to their high and broadband refl ectivity in the infrared spectral range. In contrast to well-established (protected)silver and gold mirror coatings, iridium is environmentally durable, referring to ISO 9211-3 and thermally stable up to 600 °C even without protective layers, as demonstrated. Additionally,the optical and related structural properties of atomic layer deposited (ALD) and magnetron sputtered (MS) Ir coatings were investigated using spectrophotometry, FTIR, ellipsometry, WLI,AFM, XRR, XRD, SEM, and electrical resistivity measurements. The properties of Ir ALD and Ir MS coatings diff er due to their topography and microstructure.}, subject = {Iridium}, language = {en} } @article{Doehring2021, author = {D{\"o}hring, Thorsten}, title = {Forscher entwickeln umweltfreundliche Satellitenantriebe}, series = {Wirtschaft am Bayerischen Untermain}, volume = {2021}, journal = {Wirtschaft am Bayerischen Untermain}, number = {M{\"a}rz}, editor = {IHK Aschaffenburg,}, pages = {12 -- 13}, year = {2021}, abstract = {In der aktuellen F{\"o}rderrunde des vom Bayerischen Staatsministeriums f{\"u}r Wissenschaft und Kunst aufgesetzten „Programms zur F{\"o}rderung der angewandten Forschung und Entwicklung an Hochschulen f{\"u}r angewandte Wissenschaften - Fachhochschulen" war die Technische Hochschule Aschaffenburg sehr erfolgreich. F{\"u}r das Technologieprojekt ACCASI („Aschaffenburg Competence Center for Astronomical and Space Instrumentation") erh{\"a}lt sie {\"u}ber eine Laufzeit von drei Jahren insgesamt 250.000 Euro.}, subject = {Satellitentechnik}, language = {de} } @article{StollenwerkDoehringFreudenmannetal.2021, author = {Stollenwerk, Manfred and D{\"o}hring, Thorsten and Freudenmann, Dominic and Sch{\"a}fer, Tobias and Stadtm{\"u}ller, Johannes and R{\"o}cke, Nicole}, title = {Sputtered highly effective iridium catalysts: a new approach for green satellite propulsion}, series = {Journal of Materials Science}, volume = {2021}, journal = {Journal of Materials Science}, number = {2021}, doi = {https://doi.org/10.1007/s10853-021-05897-z}, pages = {1 -- 11}, year = {2021}, abstract = {This work demonstrated the large potential of sputtered iridium metal for catalytic reactions shown by the example of decomposition of hydrogen peroxide (H2O2) for space propulsion systems. For this purpose, iridium was coated onto Al2O3 pellets by a sputter process under varied process parameters. Depending on previously selected parameters, the obtained metal-loaded pellets offer closed- and/or open-shell structures. Catalytic productivity of these first-generation iridium-sputtered catalysts was estimated in laboratory experiments and compared to platinum-loaded pellets. Under optimized sputter-process conditions, the reactivity is significantly improved compared to the platinum-impregnated pellets. The better catalytic productivity can be explained by the increased active surface area of the iridium layers on the pellets. The surface morphology and the microstructure of the iridium coating can be actively controlled by the sputter pressure. The results are in accordance with the sputtering process pressure tendency described by the Thornton Structure-Zone Model.}, subject = {Iridium}, language = {en} } @article{ProbstBegouDoehringetal.2018, author = {Probst, Anne-Catherine and Begou, Thomas and D{\"o}hring, Thorsten and Zeising, Sebastian and Stollenwerk, Manfred and Stadtm{\"u}ller, Johannes and Emmerich, Florian and Lumeau, Julien}, title = {Coating stress analysis and compensation for iridium-based x-ray mirrors}, series = {Applied Optics}, volume = {2018}, journal = {Applied Optics}, number = {57 (29)}, editor = {Publishing OSA,}, pages = {8775 -- 8779}, year = {2018}, abstract = {Iridium-based coatings for mirrors of x-ray telescopes are studied. In particular, stress-induced deformation is characterized and shown to be compressive and equal to -1786  MPa. Two methods for stress compensation are then studied. One relies on the deposition of silica on the back surface of the substrate and a second one relies on the deposition of a chromium sublayer. Advantages and drawbacks of each of these techniques are presented.}, subject = {R{\"o}ntgenteleskop}, language = {en} } @article{ProbstStollenwerkEmmerichetal.2017, author = {Probst, Anne-Catherine and Stollenwerk, Manfred and Emmerich, Florian and B{\"u}ttner, Andre and Zeising, Sebastian and Stadtm{\"u}ller, Johannes and Riethm{\"u}ller, Franziska and Stehlikova, Veronika and Mingwu, Wen and Proserpio, Laura and Damm, Christine and Rellinghaus, Bernd and D{\"o}hring, Thorsten}, title = {Influence of sputtering pressure on the nanostructure and the X-ray reflectivity of iridium coatings}, series = {Surface and Coatings Technology}, volume = {2017}, journal = {Surface and Coatings Technology}, number = {343}, issn = {0257-8972}, pages = {101 -- 107}, year = {2017}, abstract = {Reflective mirror coatings made of iridium are used in X-ray telescopes of the Chandra X-ray Observatory (CXO) launched in 1999 by the National Aeronautics and Space Administration (NASA) to investigate astronomical sources at photon energies below 10. keV. These coatings were produced in a DC magnetron sputtering process and have so far proven their suitability for space-based applications. We are considering in the present paper the processing of thin iridium films for lightweight telescopes using the radio frequency magnetron sputtering technique with an oblique angle deposition. The coating development presented here is focused on the influence of total sputtering pressure on film properties as well as on its impact on the mirror's performance. Characterisation methods such as X-ray diffractometry, X-ray reflectometry, atomic force microscopy and transmission electron microscopy have been used. Correlations between morphology, density, surface micro-roughness, crystal structure of the iridium layer and the expected reflectivity of the X-ray mirror are described and discussed.}, subject = {Iridium}, language = {en} } @article{BuettnerProbstEmmerichetal.2018, author = {B{\"u}ttner, Andre and Probst, Anne-Catherine and Emmerich, Florian and Damm, Christine and Rellinghaus, Bernd and D{\"o}hring, Thorsten and Stollenwerk, Manfred}, title = {Influence of Sputtering Pressure on the Microstructure and Layer Properties of Iridium Thin Films}, series = {Thin Solid Films}, volume = {2018}, journal = {Thin Solid Films}, number = {662}, issn = {0040-6090}, pages = {41 -- 46}, year = {2018}, abstract = {Iridium layers with low stress, high density, and low surface roughness find widespread use in different high-technology applications. This paper presents a study of the influence of the sputtering pressure on the properties of iridium thin films and of its effect on the substrate surface microstructure. We analysed the dependence of the microstructure, crystalline structure, electrical resistivity, and deposition rate on the sputtering pressure and surface defects of the substrate. For the latter, plasma etching of the substrate was performed for different processing times and its effect on the surface roughness of substrates and, subsequently, on the grown iridium films, was examined. The sputtering pressure and the substrate plasma etching time both had a strong influence on the microstructure and surface roughness. These microstructural changes are in good agreement with the tendency described in the Thornton Structure-Zone Model for different sputtering pressures and the microstructure phase map of Alvarez. The electrical resistivity, deposition rate, and crystalline structure were highly dependent on the sputtering pressure.}, subject = {Iridium}, language = {en} } @article{StehlikovaProbstNentvichetal.2018, author = {Stehlikova, Veronika and Probst, Anne-Catherine and Nentvich, Ondrej and Urban, Martin and Sieger, Ladislav and D{\"o}hring, Thorsten and Hudec, Ren{\´e}}, title = {Study of multiple layers coatings for X-ray mirrors}, series = {Contributions of the Astronomical Observatory Skalnat{\´e} Pleso}, volume = {2018}, journal = {Contributions of the Astronomical Observatory Skalnat{\´e} Pleso}, number = {48}, editor = {Skopal, August{\´i}n}, pages = {488 -- 497}, year = {2018}, abstract = {This paper focuses on a theoretical background that motivated the experimental campaign of multiple layer coatings of X-ray mirrors, and the first results of the testing of the prepared samples. Simulations of the use of different overcoats were performed in order to improve the reflectivity of thin iridium coatings designed for X-ray optics effective in the energy up to 10 keV. Samples based on these simulations were prepared and are being tested for the properties that influence the X-ray optical performance, such as layer homogeneity, density and surface micro-roughness. Further the topic of the coating stress was addressed, as it is an issue in case of thin, lightweight X-ray mirrors and affects the time stability of layers. The discussion and preliminary results conclude our contribution.}, subject = {R{\"o}ntgenspiegel}, language = {en} } @article{DoehringHudec2018, author = {D{\"o}hring, Thorsten and Hudec, Rene}, title = {JEUMICO and TRILAMICO: Dimensions of successful Bavarian-Czech cooperation}, series = {Contributions of the Astronomical Observatory Skalnat{\´e} Pleso}, volume = {2018}, journal = {Contributions of the Astronomical Observatory Skalnat{\´e} Pleso}, number = {Vol. 48 / 3}, editor = {Skopal, August{\´i}n}, pages = {430 -- 436}, year = {2018}, abstract = {In December 2017 the two projects JEUMICO (an acronym for Joint European Mirror Cooperation) and TRILAMICO (standing for Trilateral Mirror Collaboration) are ending. Different aspects of this Bavarian-Czech collaboration between Aschaffenburg University and the Czech Technical University in Prague are discussed. The multiple dimensions of this cooperation are scientific achievements, public relation measures, internationalization of education, financial aspects, inter-cultural communication, and also the actual political situation within Europe.}, subject = {R{\"o}ntgenspiegel}, language = {en} } @article{HudecDoehring2017, author = {Hudec, Rene and D{\"o}hring, Thorsten}, title = {JEUMICO: Czech-Bavarian astronomical X-ray optics project}, series = {Contributions of the Astronomical Observatory Skalnat{\´e} Pleso}, volume = {2017}, journal = {Contributions of the Astronomical Observatory Skalnat{\´e} Pleso}, number = {47}, editor = {Slovak Academy of Sciences Astronomical Institute,}, pages = {170 -- 177}, year = {2017}, abstract = {Within the project JEUMICO, an acronym for Joint European Mirror Competence, the Aschaffenburg University of Applied Sciences and the Czech Technical University in Prague started a collaboration to develop mirrors for X-ray telescopes. Corresponding mirror segments use substrates of at silicon wafers which are coated with thin iridium � lms, as this material is promising high re ectivity in the X-ray range of interest. The sputtering parameters are optimized in the context of the expected re ectivity of the coated X-ray mirrors. In near future measurements of the assembled mirror modules optical performances are planned at an X-ray test facility.}, subject = {Iridium}, language = {en} }