TY - JOUR A1 - Claire, Strasser A1 - Jürgen, Blumm A1 - Jürgen, Hartmann T1 - Characterizing Vitrification by Thermal Analysis During Curing of an Epoxy–Amine System JF - Journal of Applied Polymer Science N2 - During curing, the glass transition temperature of thermosets increases with conversion. When the process is carried out isothermally or at very low heating rates, the glass transition temperature of the resin may rise faster than the material temperature, eventually reaching the latter. This leads to vitrification: The partially cured resin enters the glassy state. The reaction rate drops drastically because it is no longer chemically controlled, but diffusion controlled. As a result, the final product may not be completely cured, which has a severe impact on its mechanical and thermal quality and is therefore crucial for the process. The concept of diffusion-controlled kinetics during the curing reaction has been widely reported and documented. However, the systematic study of the influence of vitrification on specific heat, dielectric properties, and/or thermal diffusivity during crosslinking under isothermal and dynamic conditions has never been performed so far. This work investigates the impact of vitrification on the specific heat, ionic conductivity, and thermal diffusivity during dynamic and isothermal curing of an epoxy–amine system. Y1 - 2025 UR - https://doi.org/10.1002/app.57077 U6 - https://doi.org/10.1002/app.57077 VL - 142 IS - 26 SP - e57077 ER - TY - BOOK A1 - Hartmann, Jürgen T1 - Quantitative Bestimmung lokaler thermischer Eigenschaften in polykristallinem Diamant Y1 - 1996 PB - Köster CY - Berlin ER - TY - CHAP A1 - Hartmann, Jürgen T1 - Radiometrie im UV und IR BT - future led Seminar „UV-IRED LED Seminar“ Y1 - 2009 CY - Berlin ER - TY - CHAP A1 - Hartmann, Jürgen T1 - Modernste Radiometrie und Photometrie BT - WTT Seminar „Beleuchtung mit LEDs“ Y1 - 2008 CY - Berlin ER - TY - CHAP A1 - Hartmann, Jürgen A1 - Anhalt, Klaus A1 - Hollandt, Jörg T1 - Nearly as hot as the sun: High-temperature fixed-points for radiation thermometry and radiometry BT - NCSLI Symposium Metrology’s Impact on Products and Services Y1 - 2007 CY - St. Paul (USA) ER - TY - CHAP A1 - Hartmann, Jürgen T1 - Photometrie und Radiometrie BT - 125 Jahre Lichttechnik an der TU Berlin Y1 - 2007 CY - Berlin ER - TY - CHAP A1 - Hartmann, Jürgen T1 - Legal metrology on clinical thermometers in the European Union BT - Seminar der Japan Measuring Instruments Federation Y1 - 2004 CY - Tokyo (Japan) ER - TY - CHAP A1 - Hartmann, Jürgen T1 - Radiation thermometry at PTB BT - Seminar der Japan Measuring Instruments Federation Y1 - 2004 CY - Tokyo (Japan) ER - TY - CHAP A1 - Hartmann, Jürgen A1 - Reichling, M. T1 - Complete Characterisation of local thermal heat transfer in high quality chemical vapour deposited diamond BT - 10th International conference on Photothermal and Photoacoustic Phenomena Y1 - 1998 CY - Rom (Italien) ER - TY - CHAP A1 - Hartmann, Jürgen A1 - Reichling, M. T1 - Microscopic heat transfer in high quality polycrystalline diamond BT - EAA Symposium on Molecular and Quantum Acoustics Y1 - 1997 CY - Ustron (Polen) ER - TY - JOUR A1 - Hartmann, Jürgen A1 - Knopp, Kevin A1 - Shandy, Amir A1 - Winterstein, Achim A1 - Arduini, Mariacarla A1 - Hemberger, Frank A1 - Vidi, Stephan A1 - Manara, Jochen A1 - Müller, Michael T1 - Thermophysikalische Charakterisierung von Wärmedämmschichten T1 - Thermophysical characterization of thermal barrier layers JF - tm - Technisches Messen N2 - Die Effizienzsteigerung moderner Gasturbinen erfordert die stetige Anhebung der Betriebstemperatur. Die derzeitigen Brenngastemperaturen liegen mit über 1400 °C signifikant über der kritischen Temperatur der verwendeten Turbinenstähle. Zur Gewährleistung der Betriebssicherheit werden die Turbinenschaufeln neben Aktivkühlung durch Beschichtung mit thermischen Schutzschichten, sogenannten thermal barrier coatings (TBC), geschützt. Da es sich bei den TBC um Keramikschichten handelt, ist für die Erhöhung der Haftfestigkeit das Aufbringen eines Haftvermittlers (Verbindungsschicht) notwendig. Da die Eigenschaften dünner Schichten stark von den Eigenschaften des Bulkmaterials abweichen können und zudem von der Herstellungsmethode beeinflusst werden, ist eine Untersuchung der thermischen und infrarot-optischen Eigenschaften der tatsächlichen Schichtstrukturen unumgänglich, insbesondere im Hochtemperaturbereich. Hierfür wurden Proben des reinen Trägerstahls, des Trägerstahls mit Haftvermittlerschicht und des kompletten Schichtsystems aus Trägerstahl, Haftvermittlerschicht und Wärmedämmschicht verschiedener Dicken hergestellt und mittels Laser-Flash-Methode untersucht. Die Auswertung erfolgte dabei analytisch, ausgehend von der Trägerstahl-Einschichtprobe, über die Zweischicht- und Dreischichtsysteme. Vervollständigt wurden diese Untersuchungen durch infrarot-optische Charakterisierungen, mit denen sich die Wärmeausbreitung durch die Schichtsysteme beschreiben lässt. Zusammen mit den Laser-Flash Messungen erlaubt dies eine spätere Quantifizierung der einzelnen, bei Keramiken auftretenden, Wärmetransportmechanismen. N2 - Increasing the efficiency of modern gas turbines requires the increase of operating temperature. Current fuel gas temperatures above 1400 °C significantly exceed critical temperatures of the turbine steels used. To ensure operational safety, the turbine blades are actively cooled and also protected by protective layers, the so-called thermal barrier coatings (TBC). Since the TBC are ceramic layers, an adhesion promoter (bond coat) must be applied to increase the adhesive strength. Since properties of thin layers can differ from properties of the bulk material and are also influenced by the manufacturing method, an investigation of the thermal and infrared-optical properties of the actual layer is essential, especially in the high temperature range. For this purpose, samples of the pure carrier steel, the carrier steel with bond coat and the complete layer system of carrier steel, bond coat and TBC of various thicknesses were produced and examined using the laser flash method. The evaluation was carried out analytically, starting from the single-layer sample, via the two-layer and three-layer systems. These investigations were completed by infrared-optical characterizations, allowing the description of the heat transport through the layer systems. These measurements allow a future quantification of the individual heat transport mechanisms occurring in ceramics. KW - kontaktlose Messung KW - thermische Charakterisierung KW - thermische Wärmeschutzbarrieren KW - Kontaktwiderstand KW - Laser-Flash-Verfahren KW - Contactless measurement KW - thermal characterization KW - thermal barrier coatings KW - contact resistance KW - laser flash method Y1 - 2021 U6 - https://doi.org/10.1515/teme-2021-0074 VL - 88 IS - 12 PB - Oldenbourg Wissenschaftsverlag ER - TY - CHAP A1 - Hartmann, Jürgen A1 - Manara, Jochen A1 - Stark, Thomas A1 - Arduini, Mariacarla A1 - Ebert, Hans-Peter A1 - Knopp, Kevin A1 - Shandy, Amir T1 - Non-contact detection of the adhesive properties of ceramic coatings for high temperature applications using infrared thermography; Transactions BT - Transactions Y1 - 2022 PB - SMiRT-26 CY - Berlin/Potsdam ER - TY - CHAP A1 - Harrer, S. A1 - Dotterweich, C. A1 - Hartmann, Jürgen A1 - Zink, M. A1 - Schnitzler, Tim A1 - Ebert, Hans-Peter A1 - Hemberger, Frank T1 - Paraffine als Phasenwechselmaterialen in der elektrischen Isolierung von Hochspannungsbauteilen BT - ETG-Fachbericht-VDE-Hochspannungstechnik Y1 - 2016 ER - TY - CHAP A1 - Hartmann, Jürgen A1 - Hollandt, Jörg A1 - Anhalt, Klaus A1 - Sperfeld, P. A1 - Sakharov, M. A1 - Pikalev, Yu. A1 - Ogarev, S. A1 - Sapritsky, V. ED - Zvizdic, D. T1 - Thermodynamic measurements for the melting curves of Re-C, TiC-C, and ZrC-C eutectics BT - LPM/FSB T2 - Proceedings of Tempmeko 2004 Y1 - 2005 SP - 189 EP - 194 CY - Zagrep ER - TY - CHAP A1 - Hartmann, Jürgen A1 - Anhalt, Klaus A1 - Hollandt, Jörg A1 - Machin, Graham A1 - Lowe, D. A1 - McEvoy, H. A1 - Sakuma, F. A1 - Ma, L. ED - Zvizdic, D. T1 - Comparison of the high-temperature scales of the NMIJ and the NPL with the scale of the PTB in the temperature range from 1000 °C up to 2900 °C for measurements within the EU project HIMERT BT - LPM/FSB T2 - Proceedings of Tempmeko 2004 Y1 - 2005 SP - 1063 EP - 1068 CY - Zagrep ER - TY - CHAP A1 - Hartmann, Jürgen A1 - Thomas, R. A1 - Ma, C.K. A1 - Steel, A. A1 - Hill, K. ED - Zvizdic, D. T1 - Bilateral comparison of the local realizations of the ITS-90 between the Silver point and 1700 °C using vacuum Tungsten-strip lamps as transfer standards between NRC and PTB BT - LPM/FSB T2 - Proceedings of Tempmeko 2004 Y1 - 2005 SP - 1069 EP - 1073 CY - Zagrep ER - TY - CHAP A1 - Hartmann, Jürgen A1 - Edler, F. A1 - Anhalt, Klaus ED - Zvizdic, D. T1 - Novel fixed point cell design for simultaneous contact and non-contact temperature measurement BT - LPM/FSB T2 - Proceedings of Tempmeko 2004 Y1 - 2005 SP - 873 EP - 878 CY - Zagrep ER - TY - CHAP A1 - Hartmann, Jürgen A1 - Taubert, Dieter Richard A1 - Friedrich, R. A1 - Sperfeld, P. A1 - Hollandt, Jörg ED - Zvizdic, D. T1 - Long-Term Stability of the Spectral Responsivity of Filter Radiometers at the PTB BT - LPM/FSB T2 - Proceedings of Tempmeko 2004 Y1 - 2005 SP - 977 EP - 982 CY - Zagrep ER - TY - CHAP A1 - Hartmann, Jürgen A1 - Ishii, J. A1 - Fukuzaki, T. A1 - McEvoy, H.C. A1 - Simpson, R. A1 - Machin, Graham A1 - Gutschwager, B. A1 - Hollandt, Jörg ED - Zvizdic, D. T1 - A comparison of the blackbody cavities for infrared ear thermometers of NMIJ, NPL, and PTB BT - LPM/FSB T2 - Proceedings of Tempmeko 2004 Y1 - 2005 SP - 1093 EP - 1098 CY - Zagrep ER - TY - CHAP A1 - Gutschwager, B. A1 - Schiller, S. A1 - Hartmann, Jürgen A1 - Hollandt, K. ED - Zvizdic, D. T1 - A lens-free InGaAs transfer radiation thermometer with an extended calibration range above 960 °C BT - LPM/FSB T2 - Proceedings of Tempmeko 2004 Y1 - 2005 SP - 605 EP - 610 CY - Zagrep ER -