@article{HerrmannMoldovanFecheteetal., author = {Herrmann, Volker and Moldovan, Dumitrita and Fechete, Radu and Demco, Dan Eugen and Culea, Eugen and Bl{\"u}mich, Bernhard and Heinz, Manfred}, title = {Heterogeneity of Nanofilled EPDM Elastomers Investigated by Inverse Laplace Transform 1H NMR Relaxometry and Rheometry}, series = {Macromolecular Chemistry and Physics}, volume = {211}, journal = {Macromolecular Chemistry and Physics}, number = {14}, doi = {https://doi.org/10.1002/macp.201000086}, pages = {1579 -- 1594}, abstract = {The heterogeneous effects due to filler interactions and chain dynamics of reinforcing nano-filler particles were characterized on a series of filled EPDM elastomers using the Payne effect and low field NMR, 1H transverse (T2), longitudinal (T1) and longitudinal in rotating frame (T1ρ) relaxation time measurements. Measurement of the Payne effect and NMR relaxation curves were used to obtain the distribution of filler/filler interactions and chain dynamics by one-dimensional Laplace inversion. Distributions of shear-strain constants in the Payne effect reveal the existence of weak, medium and strong filler/filler interactions which were correlated to filler properties and content. The analysis of relaxation-time distributions leads to the identification of multimodal polymer network dynamics.}, language = {en} } @article{HerrmannMoldovanFecheteetal., author = {Herrmann, Volker and Moldovan, Dumitrita and Fechete, Radu and Demco, Dan Eugen and Culea, Eugen and Bl{\"u}mich, Bernhard and Heinz, Manfred}, title = {The heterogeneity of segmental dynamics of filled EPDM by 1H transverse relaxation NMR}, series = {J. Magn. Res.}, volume = {208}, journal = {J. Magn. Res.}, number = {1}, doi = {https://doi.org/10.1016/j.jmr.2010.10.019}, pages = {156 -- 162}, language = {en} }