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Über die Farben der Sonne und des Himmels: Rayleigh- und Miestreuung in Demonstrationsexperimenten
(2002)
Studies of the evolution of the optical properties of metal clusters as a function of size have gained considerable attention in the last few years. One theoretical approach starts from large metal clusters, which can be described by classical electrodynamics, provided the dielectric functions of the clusters are known. the resulting resonant features in the absorption spectra are commonly called surface plasmons and are collective excitations of the electron system.The present paper discusses the electrodynamic (Mie) theory for large clusters of different metals, also considering the range of validity of this approach towards smaller cluster sizes. More details can be found in an extended review on this topic which is to be published soon [1].
Results on laser-induced desorption of metal atoms from small metal particles are presented. Experiments have been performed on sodium, potassium, and silver particles supported on a LiF(100) single-crystal surface under ultrahigh vacuum conditions. Measurements include the determination of the desorption rate as a function of laser wavelength, laser intensity, average particle size, and substrate temperature, the determination of the kinetic energy of the desorbed atoms, the investigation of the optical spectra of the supported metal particles, and the study of the influence of adsorbate molecules on the desorption rate. Furthermore, theoretical extinction and absorption spectra of the metal particles have been calculated with the classical electrodynamical Mie theory as a function of average particle size and excitation wavelength. Also, the radial electric field at the particle surface was computed. The results of the experiments and theoretical calculations are combined to give a consistent picture of the mechanism of metal-atom desorption by electronic excitation with laser light. A realistic surface potential from which the atoms escape and nonlocal optical effects are taken into account. The latter introduce additional absorption channels by the formation of electron-hole pairs in the surface layer of the particle which relax into antibonding states before desorption occurs. Finally, the mechanism is discussed in the light of similar phenomena observed for thin metal films. Possibilities for future work are outlined.
© 1993 The American Physical Society
Laser-induced desorption of metal atoms from the surface of small metal particles has been investigated as a function of the shape of the particles and the polarization of the incident laser light. The particles were supported on LiF, quartz or sapphire substrates. In a first set of experiments, the shape of the particles was determined by recording optical transmission spectra with s- and p-polarized light incident under an angle of typically 40° with respect to the surface normal. The metal particles turn out to be oblate, the ratio of the axes perpendicular and parallel to the substrate surface being on the order of 0.5. This ratio decreases with increasing particle size. Also, the particles change shape if the temperature is raised. In further experiments, s- and p-polarized light has been used to stimulate desorption of atoms via surface plasmon excitation. It is found that the desorption rate markedly depends on the polarization of the light. This is explained by excitation of the collective electron oscillation along different axes of the non-spherical particles.
Width of cluster plasmon resonances: Bulk dielectric functions and chemical interface damping
(1993)
The damping of collective electron resonances in clusters which develop into plasmon polaritons at larger sizes is investigated for free, supported, and embedded neutral metal clusters. Embedding of free 2 nm Ag clusters of 2-nm diameter into a SiO2 matrix leads to an increase of the width of the resonances by more than a factor of 3. The optical spectra are compared with the Mie theory using size-effect-modified dielectric functions of the solid state. The results corroborate the assumption that the widths of the resonances strongly depend on chemical interface effects. The results are briefly discussed with regard to limited-mean-free-path and quantum-size-effect theories and a recent approach by Persson. It is demonstrated that the widths of the spectra of supported and embedded clusters have to be interpreted with care since true intrinsic size effects of the clusters appear to be less effective than previously believed and can be obscured by the chemical interface damping.
© 1993 The American Physical Society
Small sodium and silver particles were generated on dielectric substrates like LiF, quartz and sapphire under ultrahigh vacuum conditions. The optical transmission spectra of the clusters were measured as a function of cluster size and shape, for low and high substrate temperatures as well as for s- and p- polarization of the incident light. Excitation of dipolar surface plasmon oscillations in the directions normal and parallel to the substrate surface could be identified. Furthermore, optical spectra for Na and Ag clusters were calculated with the classical Mie theory. The measured spectra vary strongly if the experimental conditions are changed and can be exploited, for example, to characterize the particles with regard to their size and shape. In particular, the axial ratio of the spheroidal clusters could be determined. Its value is considerably different for the two investigated metals and depends on the substrate material. Furthermore, the temperature of the substrate has a pronounced influence on the shape of the particles. At low temperature of T=100 K two-dimensional island growth is predominant. The particles extend only little in the direction perpendicular to the surface and coalesce readily at small coverage of metal atoms. In contrast, the clusters are truly three-dimensional at T=300 K. At this stage, sodium particles still exhibit a rather small axial ratio whereas silver clusters appear almost spherical. Thus, measurements of the optical spectra permit direct in situ monitoring of cluster growth during the nucleation of adsorbed atoms and of temperature induced shape variations. In addition to investigations of the shape of the particles, the quadrupolar surface plasmon mode was observed for Ag clusters.
Old and new laboratory experiments on atmospheric optics with a focus on mirages, rainbows, and halos are presented. Some qualitative demonstrations serve primarily didactical purposes, e.g., by proving the existence of curved light rays in media with a gradient of the index of refraction, by directly visualizing the minimum-deviation curve for rainbow paths in water droplets, or by helping to elucidate the ray classes in hexagons that contribute to a specific halo. In addition, quantitative experiments allow a direct comparison of angular positions and intensities with analytical computations or Monte Carlo simulations of light scattering from small water droplets or ice hexagons. In particular, the latter can help us to understand complex halo phenomena.
© 1998 Optical Society of America
Some laboratory demonstrations on atmospheric optics are presented. The focus is on dispersion effects in mirages, lateral mirages, and inferior mirages produced with small hot plates. We also show a demonstration of the upper-tangent-arc halo, produced with a hexagonal prism, rotating about two axes.
© 2003 Optical Society of America
Thermography of Microsystems
(2004)
A procedure to experimentally simulate pollen coronas is discussed. Observed coronas are due to pine and birch pollen having different geometries. Using computer simulations, two-dimensional projections of a large number of pollenlike objects with adjustable shapes, with or without preferential orientation and statistical or regular spatial distribution, are generated. The photograph of the printout allows samples with typical sizes between 20 and 200 µm. Their diffraction patterns can closely resemble the ones observed in nature and predicted by theory.
© 2005 Optical Society of America
Light scattering from small particles changes if the particles are absorbing. Whereas the effect is small for coronas and Bishop's ring, glories show pronounced attenuation with increasing absorption. Results indicate suitable wavelength regions for studies of glory scattering from cloud tops. The behavior of core-shell particles could have applications for studying the atmosphere of Venus; in addition it provides more insight into the simple ray-path model of the glory.
© 2005 Optical Society of America
We present simple radiative transfer models for the radiance and color of atmospheric optical phenomena. Skylight, halos, and rainbows are treated as singly scattered sunlight that is depleted by scattering as it passes through a plane-parallel atmosphere and a vertical rain shaft or a geometrically thin cloud layer. Skylight in a molecular atmosphere grades from deep blue at the zenith to pale blue near the horizon whenever the solar zenith angle sun ≤ 80°. Skylight near the horizon is orange resulting from wavelength-dependent scattering by air molecules and aerosol particles through a long oblique path through the atmosphere when the sun is low in the sky (sun ≥ 85°). Halos (and coronas) seen through clouds facing the sun are brightest for cloud optical depth τcld ≈ cos(sun), and fade to obscurity for τcld ≥ 5. Rainbows (and glories), seen by light that is backscattered from clouds, also appear most dramatic when 0.2 ≤ τcld ≤ 1, but remain visible even in the thickest clouds.
The Moon’s time-dependent luminance was determined during the 9 February 1990 and 3 March 2007 total lunar eclipses by using calibrated, industry standard photometers. After the results were corrected to unit air mass and to standard distances for both Moon and Sun, an absolute calibration was accomplished by using the Sun’s known luminance and a pre-eclipse lunar albedo of approximately 13.5%. The measured minimum level of brightness in the total phase of both eclipses was relatively high, namely −3.32 mvis and −1.7 mvis , which hints at the absence of pronounced stratospheric aerosol. The light curves were modeled in such a way as to let the Moon move through an artificial Earth shadow composed of a multitude of disk and ring zones, containing a relative luminance data set from an atmospheric radiative transfer calculation.
© 2008 Optical Society of America
Irradiance and color during the total lunar eclipses of 2007 and 2008 are simulated using a ray tracing model that includes refraction, scattering by molecules, and observed or climatological distributions of aerosols, ozone, clouds, and topography around the terminator. Central portions of the umbra appear deep red for almost all eclipses due to preferential removal of short wavelengths in the spectrum of sunlight by scattering in the lower troposphere. The fringe of the umbra appears turquoise or blue due to selective removal of wavelengths around 600 nm by the Chappuis absorption bands of ozone in the stratosphere. Asymmetric distributions of clouds and aerosols, particularly for the 2008 eclipse, produce minimum calculated irradiance up to 17 arc min from the umbra center, while high ozone content over the arctic makes the northern edge of the umbra deepest blue.
© 2008 Optical Society of America
Irradiance during total lunar eclipses is simulated using a pinhole model. The Moon is illuminated by direct sunlight that is refracted into the Earth’s shadow as it passes through the atmosphere at the terminator but is depleted by scattering by molecules, extinction by aerosol particles, absorption by ozone, and obstruction by clouds and elevated land. On a spherical, sea-level Earth, and a cloudless, molecular atmosphere with no ozone, the eclipsed Moon appears red and calculated irradiance at the center of the umbra is reduced by a factor of about 2400 from direct moonlight. Selective absorption mainly of light around 600 nm by stratospheric ozone turns the periphery of the umbra pale blue. Typical distributions of aerosol particles, ozone, mountains, and clouds around the terminator reduce irradiance by an additional factor of the order of 100.
© 2008 Optical Society of America
Solar load and reflection effects and respective time constants in outdoor building inspections
(2009)
Rainbows, water droplets, and seeing—slow motion analysis of experiments in atmospheric optics
(2011)
Many physics processes underlying phenomena in atmospheric optics happen on a rather short time scale such that neither the human eye nor video cameras are able to analyze the details. We report applications of high-speed imaging of laboratory experiments in atmospheric optics with subsequent slow motion analysis. The potential to study respective transient effects is investigated in general and for a few phenomena in detail, in particular for rainbow scattering due to single oscillating droplets during free fall, and for light propagation effects through atmospheric paths with turbulences, leading, e.g., to scintillation of stars or shimmering of mirage images.
© 2011 Optical Society of America
Model simulations of laboratory-generated and natural crepuscular rays are presented. Rays are created in the laboratory with parallel light beams that pass through artificial fogs and milk–water solutions. Light scattered by 90° in a dilute mixture of whole milk first increases in intensity with distance from the source to a maximum as a result of multiple scattering by mainly small angles before decreasing exponentially due to extinction as distance continues to increase. Crepuscular rays are simulated for three cloud configurations. In case 1, the Sun at the zenith is blocked by a cloud with an overhanging anvil. The rays appear white against blue sky and are brightest when atmospheric turbidity, β≈11 . Shading by the anvil separates maximum brightness from apparent cloud edge. In case 2, a ray passes through a rectangular gap in a cloud layer. The ray is faint blue in a molecular atmosphere but turns pale yellow as β and solar zenith angle, ϕsun , increase. At ϕsun=60° it appears most striking when the cloud is optically thick, β≈5 , and the beam width Δx≈1000 m . In these cases, increasing aerosol radius, raer , to about 1000 nm brightens, narrows, and shortens rays. In case 3, the twilight Sun is shaded by a towering cloud or mountain. The shaded rays are deeper blue than the sunlit sky because the light originates higher in the atmosphere, where short waves have suffered less depletion from scattering. The long optical path taken by sunlight at twilight makes color and lighting contrasts of the rays greatest when the air is quite clean, i.e., for β−1≪1 . In all cases, the brightest rays occur when sunlight passes through an optical thickness of atmosphere, τ≈O(1) .
© 2011 Optical Society of America
Gasdetektion mit Infrarotkameras ist eine relativ neue Anwendung. Aufgrund der industriellen Bedeutung einiger Gase wurden sensitive Kameras mit Schmalbandfiltern entwickelt. Heute gibt es kommerzielle Systeme für die Detektion flüchtiger Kohlenwasserstoffe, Schwefelhexafluorid und Kohlenmonoxid. In dieser Arbeit werden Laborergebnisse der Detektion von CO2 vorgestellt und potenzielle Anwendungen diskutiert.
Beleuchtet man die Oberfläche eines Festkörpers mit Laserlicht, können darauf adsorbierte Atome oder Moleküle abgelöst werden. Solche Desorptionsprozesse sind in jüngster Zeit in zahlreichen Experimenten untersucht worden, wobei sich das Interesse sowohl auf die Erforschung der zugrundeliegenden Mechanismen als auch auf mögliche Anwendungen dieser Reaktionen, zum Beispiel zur gezielten Modifizierung von Oberflächen, konzentriert. Besonders interessant ist das laserinduzierte Aufbrechen von Bindungen zur Oberfläche dann, wenn es nicht einfach als thermischer Prozeß durch eine Temperaturerhöhung hervorgerufen wird, sondern direkt auf einer elektronischen Anregung beruht. Solche nichtthermischen Prozesse werden selbst für Metalle beobachtet, obwohl die Kopplung der elektronischen Anregung an das Substrat hier besonders schnell abläuft. Der zugrundeliegende Mechanismus beruht auf dem Zusammenspiel einer kollektiven Elektronenoszillation und einer lokalisierten Einzelelektronenanregung, wobei auch nichtlokale optische Effekte in der Metalloberfläche eine wichtige Rolle spielen.