Synthesis of Novel Fullerene Architectures with Mixed Octahedral Addition Pattern

Synthese neuartiger Fulleren Architekturen mit gemischtem oktaedrischen Additionsmuster

Please always quote using this URN: urn:nbn:de:bvb:29-opus4-88265
  • The exohedral multi-functionalization of C60 is one of the most important and promising topics in fullerene chemistry. The introduction of different addends with varying functional moieties is a challenging task in this manner. Inspired by the protection-deprotection strategy for the regioselective synthesis of C2v symmetrical fullerene [5:0] pentakisadducts, developed by HÖRMANN et al., within the present work a novel synthetic concept for the regioselective introduction of different functional groups to a C60 core has been investigated. The first step, which is the key-step in the synthesis is the regioselective formation of protected e bisadducts. In this regard, a novel syntheticThe exohedral multi-functionalization of C60 is one of the most important and promising topics in fullerene chemistry. The introduction of different addends with varying functional moieties is a challenging task in this manner. Inspired by the protection-deprotection strategy for the regioselective synthesis of C2v symmetrical fullerene [5:0] pentakisadducts, developed by HÖRMANN et al., within the present work a novel synthetic concept for the regioselective introduction of different functional groups to a C60 core has been investigated. The first step, which is the key-step in the synthesis is the regioselective formation of protected e bisadducts. In this regard, a novel synthetic approach has been developed, which opend the way to the facile synthesis of highly mixed fullerene multi-adducts.show moreshow less

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Metadaten
Author:Ekaterini Vlassiadi
Persistent identifiers - URN:urn:nbn:de:bvb:29-opus4-88265
Referee:Andreas Hirsch
Document Type:Doctoral Thesis
Language:English
Year of publication:2017
Date of online publication (Embargo Date):2017/10/01
Publishing Institution:Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU)
Granting institution:Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Naturwissenschaftliche Fakultät
Acceptance date of the thesis:2017/07/24
Release Date:2017/10/11
Tag:Bingel reaction
SWD-Keyword:fullerene; C-60
Institutes:Naturwissenschaftliche Fakultät
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
open_access (DINI-Set):open_access
Licence (German):Keine Creative Commons Lizenz - es gilt der Veröffentlichungsvertrag und das deutsche Urheberrecht