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Die Arbeit hat den Stand und die Möglichkeiten der Weiterentwicklung der Energieholzerzeugung durch Kurzumtriebsplantagen (KUP) zum Inhalt. Nach der Analyse der Entwicklung dieser relativ neuen Variante zur Bewirtschaftung schnellwachsender Baumarten und ihrer Möglichkeiten werden die damit einhergehenden gesetzlichen Grundlagen analysiert. In diesem Zusammenhang werden neben landwirtschaftlichen Flächen auch andere Optionen der Flächenetablierung betrachtet (Wald, Brachflächen). Schwächen in der Abgrenzung und Förderung, vor allem auf Länderebene, werden diskutiert. Es schließt sich eine ausführliche ökonomische und ökologische Betrachtung des Agrarholzanbaus sowie der Grundlagen der Bewirtschaftung einschließlich der Rohstoffbereitstellung an. Die Analyseergebnisse dienen als Grundlage für die Durchführung von Interviews mit Experten der Thematik schnellwachsender Baumarten. Die Ergebnisse dieser Interviews belegen, dass KUP mehrheitlich als Chance zur langfristigen Energieholzversorgung und Etablierung regionaler Kreisläufe - hauptsächlich im landwirtschaftlichen Sektor - gesehen wird, es jedoch in diesem Zusammenhang noch einer Reihe von Defiziten - unter anderem auf Seiten der Bewirtschaftungstechnik, der Rahmenbedingungen und sonstigen Etablierungshemmnissen - zu begegnen gilt. Nach Überwindung der noch vorhandenen Anlaufschwierigkeiten stehen die Chancen jedoch gut, die Energieholzerzeugung im Kurzumtrieb ökonomisch tragfähig, ökologisch vorteilhaft und sozial verträglich auszubauen und damit sowohl zur Diversifizierung der landwirtschaftlichen Produktion beizutragen als auch den Nutzungsdruck auf den Wald zu verringern.
An empirical and simulation-based assessment of tree growth in temperate alley-cropping systems
(2020)
The potential of biomass generated from dedicated energy crops, used in short-rotation coppices (SRC), progressively grows recognition as a flexible primary source for the generation of energy, heat, fuel, and bio-based materials and chemicals. The alley-cropping systems (ACSs), which can integrate tree strips managed as SRC into agriculturally managed fields, are often regarded as an adaptable multi-crop land-use strategy that can provide ecological and economic benefits. The research aim of the present dissertation has focused on investigating the prospective implications of different site-specific conditions and scenarios on tree growth in ACSs with SRC, thus incorporating several experimental and simulation-based studies. For this, the ability of a process-oriented, eco-physiological tree growth model was investigated in order to (i) impute missing empirical data, thus securing a reliable repository of tree growth characteristics, (ii) simulate the tree growth in terms of woody biomass production in strong relation to the interactions with adjacent crops and their respective resource capture, (iii) predict and evaluate the tree growth sensitivity to prospective climate changes, thus performing risk assessments for the near and distant future, and (iv) derive and assess the land equivalent ratio (LER) and gross energy yield for different climatic, soil, and management scenarios. The findings have corroborated the potential tree growth vulnerability to prospective climatic changes, particularly to changes in water availability, and have underlined the importance of coping management strategies in SRC for forthcoming risk assessments and adaptation scenarios. Both LER and gross energy yields had resulted in a convex curve where the maximum values were achieved when either the tree or crop component was dominant (>75% of the land area) and minimum when these components shared similar proportions of land area. Collectively, the implications of different site-specific conditions and scenarios on tree growth in ACSs with SRC have been investigated in order to improve the decision-making, optimization, and adaptation of such systems. Last but not least, this dissertation has emphasized the considerable potential of modelling approaches in ACSs, as they can impute missing data from scarce available data and simulate tree and crop yields for specific site-conditions in a non-intrusive, inexpensive, and prompt way while supporting early site-setup planning.
Designing and implementing comprehensive reclamation programme during mine operations can minimize environmental damage and decrease potential legal liability. Although Regulation (23) of the Ghana Environmental Assessment Regulation (1999) requires mine proponents to have plans for reclamation, it has been revealed most degraded mine-sites have not been reclaimed. Even in cases where some mining companies made reclamation attempts, such efforts could not produce any favourable outcome due to the failure in adopting such best reclamation management practices as slope stabilization and substrate amendment to promote vegetation establishment. Subsequently, this study was undertaken to (a) investigate the role of biological geotextiles in erosion control and (b) examine effects of organic amendments with stockpiled subsoil on tree growth and on ground vegetation cover. A waste-rock dump was graded to 33% slope and covered with a 70 cm layer of subsoil at the Amoma Pit of Newmont Ghana Gold Limited Ahafo-South project. To achieve the first objective, two kinds of biological geotextiles; Elephant-grass mat and “York” mat, were used with bare ground as control, in a randomized block design with two replications each. Mat performance against erosion was expressed as a percentage from the total sediment yield. Results showed both the Elephant-grass mat and the York mat significantly (p < 0.05) reduced soil loss by 56.6% and 97.3%, respectively, compared to the control. The mats acted as cover and protected the graded mine-slope against erosion and allowed vegetation to establish and grow through them.
Two experimental plots (24 × 15 m) were established on a different portion of the waste-rock dump for the second objective. The treatments, manure (23 t ha-1) and control (no manure), were applied, followed by seeding of Cowpea (Vigna unguiculata) and planting of potted-seedlings of five forest-tree species. The Laser-point-quadrat method was used to estimate ground vegetation cover, whereas erosion was visually observed. Diameter and height data of the planted trees were collected. The results indicated the manure had significant positive influence on tree growth and on ground vegetation cover which facilitated superior soil stabilization, compared to the control. Manure supplied sufficient N to overcome N deficiency of the subsoil and additionally increased soil organic matter that boosted microbial activity and mineralization. The findings of the study highlight the urgent need of implementing best reclamation management practices in protecting the environment and securing successful reclamation during mine operations in Ghana. The achievement of this will promote responsible mining and further contribute to Ghanaians’ acceptability of mining as a sustainable developmental land use activity, rather than as a curse.
Soils deposited can undergo a sudden change in the structure when they are inundated with water resulting decrease in the volume. This process is known as water induced compaction. The decrease in volume occurs without any change in external loads and is only caused by the water, which results in the settlement of soil surface having a resultant potential to damage the structures. The water induced compaction process is characterized by sudden change in the voids or pores of the soil that are loaded at their natural water content and flooded. The objective of this thesis work was to understand the water induced consolidation process at agriculturally used reclaimed soils. The approach was to reproduce the situation occurring when the soil was subjected to water induced compaction at defined loads typical in the top soil (0 kPa to 20 kPa). The glacial till used for the experiments was sampled in the Lusatian lignite-mining district located about 100 km southeast of Berlin, Germany. Sediment samples for different investigations were taken from the pre-cut section at 1500 m west of the eastern end from 3 m depth till 10 m depth. The glacial till used for the experiments derived from the sediment layer of Warthe sub-stage of the saalian glaciation. To characterize the soil properties at the pre-cut section, parameters like grain size distribution, soil bulk density, calcium carbonate content (CaCo3) and water retention characteristics were measured. The stability of the glacial till was evaluated using parameter pre-consolidation load. This was done in three sub-steps. The first step was determination of the stress-strain behaviour under natural conditions. In the second step the stress-strain behaviour of disturbed dry samples was simulated, which would be the situation in summer when the glacial till dries during transport. In the third step we saturated the disturbed dry samples which were subjected to different preloads to simulate the effect of saturation and re-compaction by precipitation. This work was exemplarily done for undisturbed samples and also for disturbed dry samples from 4 depths (4 m, 6 m, 8 m, and 10 m). Disturbed dry and saturated conditions were tested for samples from depths 4 m and 8 m. i) It was found from the grain size distribution that the soil profile is uniformly distributed with different particle sizes. High soil bulk density was recorded, which were in the range of 1.9 g cm-3 to 2.0 g cm-3. We observed that the carbonate content increased with the depths, in our observation it increased up to 5.4 %. From the water retention characteristics we observe that the samples from 4 m and 10 m depth do not have coarse pores where as 6 m and 8 m depth samples have coarse pores. ii) We observed that the undisturbed samples showed a flat curve having the initial void ratio and final void ratio values within a small range (between 0.2 and 0.4), where as the disturbed dry and the disturbed saturated curves showed a huge difference in the initial and final void ratio values. The difference was decreasing with the increase in pre-loads. We found that pre-consolidation stress values obtained were not increasing with the increase in depth. The disturbed saturated samples from the 4 m depth showed over-estimation of the results, where as the disturbed saturated samples from 8 m appeared to be realistic. We found that the magnitude of water induced compaction increased with the increase in preloads and a decrease with respect to the depths
Im Rahmen dieser Arbeit erfolgte die Untersuchung quartärer und tertiärer sandiger Substrate im rekultivierten Bereich des Tagebaus Welzow-Süd im Lausitzer Braunkohlerevier über einen Zeitraum von 28 Monaten. Die Substrate und Substratmischungen wurden auf ihre Benetzungseigenschaften sowohl im Hinblick auf die räumliche Heterogenität und zeitliche Variabilität als auch in Abhängigkeit von Art und Gehalt an organischer Substanz untersucht. Die Bewertung der Benetzungseigenschaften erfolgte mittels Kontaktwinkelmessungen und WDPT-Test in Freiland und Laborstudien.
Während die quartären Substrate im gesamten Untersuchungszeitraum durchgehend gut benetzbar waren und als hydrophil eingestuft wurden, wiesen die untersuchten tertiären Sande im feldfeuchten Zustand zum Teil extreme Benetzungshemmung auf. Wie die vorliegende Untersuchung bestätigt, wurde nachgewiesen, dass trotz kleiner gemessener Kontaktwinkel eine ausgeprägte Benetzungshemmung vorliegen kann.
Die untersuchten tertiären Substrate sind durch eine hohe horizontale und vertikale räumliche Heterogenität der Benetzungseigenschaften gekennzeichnet. Am oberen Hangbereich und auf den Kuppenbereichen lag überwiegend starke Benetzungshemmung vor. Durch den daraus resultierenden Oberflächenabfluss verbunden mit Substratverlagerung wurden zum Teil erhebliche Reliefänderungen, resultierend in einer ausgeprägten Kuppen- und Rinnenstruktur, beobachtet.
Zudem wiesen die tertiären Substrate ein zeitlich stark differenziertes Benetzungsverhalten auf. Während im Winter und im Frühjahr überwiegend eine gute Benetzbarkeit des Substrats bestand, lag im Sommer und im Herbst zum Teil erheblich ausgeprägte Benetzungshemmung vor. Die zeitliche Variabilität der Benetzungseigenschaften des tertiären Substrats wird maßgeblich durch die Luft- und Bodentemperaturen sowie einen kritischen Bodenwassergehalt von 2 Masse-% beeinflusst. Des Weiteren konnten Abhängigkeiten zwischen schwach oder mäßig ausgeprägter Benetzungshemmung und der Niederschlagsmenge nachgewiesen werden. Je höher die Niederschlagsmenge, desto schwächer war die Benetzungshemmung ausgeprägt. Bei vorliegender starker Benetzungshemmung des tertiären Substrats erfolgten Änderungen im Benetzungsverhalten hingegen vor allem durch langanhaltende Niederschlagsereignisse oder Niederschlagsereignisse hoher Intensität.
Die Zugabe organischer Substanz verschiedener Art und Herkunft führte in allen Fällen zur Induzierung von Benetzungshemmung. Sowohl in den Freiland- als auch in den Laborversuchen wurde mit steigendem Gehalt an organischem Kohlenstoff eine stärker ausgeprägte Benetzungshemmung nachgewiesen. Für die untersuchten Substrate konnte ein kritischer Wert von 0,25 % organischen Kohlenstoffs ermittelt werden, unterhalb dessen vorwiegend Benetzbarkeit der Substrate vorlag.
Als Haupteinflussparameter für die Ausbildung der Benetzungseigenschaften des tertiären Substrats wurden die Parameter Globalstrahlung und Lufttemperatur sowie der Bodenwassergehalt mittels multivariater statistischer Methoden identifiziert. Ein konzeptioneller Ansatz zur Implementierung des Parameters Benetzungshemmung in die hydrologische Modellierung ermöglicht mittels meteorologischer und bodenphysikalischer Parameter die exemplarische Zuordnung von tertiären Substratproben in Gruppen mit hydrophilen, mäßig benetzungsgehemmten und sehr stark benetzungsgehemmten Eigenschaften ohne direkte Messung der Benetzungshemmung.
Der integrierte Versuchsansatz zur in situ Charakterisierung der Benetzungseigenschaften verschiedener Substrate und Substratmischungen im Freiland und ergänzender Laborstudien ermöglicht eine verbesserte Analyse der pedologischen und hydrologischen Prozesse der „critical zone“. Erstmalig wurde im Rahmen der vorliegenden Dissertation anhand meteorologischer Parameter und dem Bodenwassergehalt eine Zuordnung von Benetzungseigenschaften durchgeführt.
Die im Rahmen der vorliegenden Datenanalyse gewonnenen Erkenntnisse hinsichtlich der die Benetzungshemmung beeinflussenden Parameter bieten einen konzeptionellen Ansatz zur qualitativen Weiterentwicklung mathematischer Prozessmodelle der Abflussbildung. Die vorliegende Studie ermöglicht eine Abschätzung der vorliegenden Benetzungseigenschaften anhand meteorologischer Parameter sowie kritischer Werte für den Bodenwassergehalt und den Gehalt an organischem Kohlenstoff. Durch die Einbindung in hydrologische und Erosionsmodelle wird damit im Weiteren die Möglichkeit gegeben, Oberflächenabflüsse und Bodenabträge von benetzungsgehemmten Flächen zu prognostizieren.
Vor dem Hintergrund veränderter Niederschlagsmuster mit einer Häufung meteorologischer Extremereignisse ist eine Einstufung der Bodensubstrate in Gefährdungsklassen zweckmäßig, da die Ausbildung von Benetzungshemmung vor allem unter trockenen und warmen Bedingungen begünstigt wird. Somit kann ein Instrument geschaffen werden, um Bodendegradierung als Folge von Benetzungshemmung wirksam vorzubeugen.
In this study the mycorrhizal community of the Ericaceae Comarostaphylis arbutoides was investigated to reveal further ectomycorrhizal fungal species that are associated with this tropical plant. Mycorrhizal systems of selected genera were investigated in more detail regarding their phylogeny, morphology, and anatomy as well as the genetic confirmation of the associated host tree.
The genetic investigation of mycorrhizal systems collected at the Cerro de la Muerte (Costa Rica) detected a diverse fungal community. Most common were species of the genera Russula, Cortinarius, and Cenococcum, as well as not further determined members of the Cantharellaceae and Helotiales. The genera Cenococcum, Clavaria/Clavulina, Phellodon, Piloderma, Sebacina, Tomentella/Thelephora, as well as Xerocomus could be proven genetically for the first time from Costa Rica based on mycorrhizal systems.
Comarostaphylis arbutoides was proven to be mycorrhizal with Leotia cf. lubrica, Sebacina sp., and diverse species of the genus Cortinarius. Species of other genera are also assumed, but their confirmation is still to be made.
On the basis of genetics and the investigation of its mycorrhizal systems, the collected Costa Rican Sebacina sp. may constitute a hitherto not described species. However, to confirm this assumption fruit body investigations are necessary. Sebacina sp. was proven in this study to be also mycorrhizal with Quercus sp.
The ascomycete Leotia lubrica was proven to be mycorrhizal for the first time. However, mycorrhizal findings of this species are still rare in literature and further studies are necessary to underpin its new status. As Leotia lubrica occurs worldwide, other host plants, beside the proven Comarostaphylis arbutoides, are assumed for this species as well.
The mycorrhizal samples of the genus Cortinarius could comprise approximately 15 species. Their final determination is still outstanding, but it is assumed that also hitherto not known species were detected in this study. A host preference is indicated as species of Cortinarius are found to be associated either with Comarostaphylis arbutoides or Quercus sp., but needs to be confirmed by including mycorrhizal samples of Quercus trees.
One third of the sequenced mycorrhizal systems still remain unidentified. Therefore, repeated comparison with sequence databases is recommended. The phylogenetic and morphological/anatomical investigation of already identified as well as unidentified mycorrhizal systems is advised to deliver additional descriptions of Costa Rican ectomycorrhizal fungi and therefore contribute to the knowledge of tropical fungal species.
Influence of Ectomycorrhiza on exudation of Low Molecular Weight carboxylates in Pinus sylvestris L.
(2008)
Ectomycorrhiza has a strong influence on exudation of both Low Molecular Weight (LMW) carboxylates and on the release of inorganic compounds into the rhizosphere. This process of exudation influences the chemical composition of the rhizosphere soil than the bulk soil. This specific chemical environment which is created in the rhizosphere significantly influences mineralization processes in the soil. Exudation is normally related to activities such as growth and physiological development of plant roots. Root secretions are also comprised of large range of organic and inorganic substances. To a large extent nutrient uptake by plants depends on the release of exudates in the form of LMW carboxylates, which in turn mobilize the required elements suitable for metabolic purposes by forming organometallic complexes. Root exudates influence the rhizosphere soil making it conducive for root proliferation. Exudates are well known for stimulating the metabolic activity of microbial communities in the rhizosphere. Correspondingly, microbes may enhance rhizodeposition by roots. The main objective of this research focuses on characterization of Low Molecular Weight (LMW) carboxylates in rhizosphere soil solution and their role in plant nutrition. For a better understanding of the characteristics of the root exudates, Pinus sylvestris L. tree seedlings, distinguished into non-mycorrhized as well as mycorrhized variants and were grown in petridish rhizotron. To reduce the influences of the unknown processes occurring in the natural environment, working under sterile conditions to much extent was preferred. To achieve maximum recovery of LMW carboxylates, density of the roots per volume in our petridish experiments was increased. Rhizosphere soil solutions were collected with the help of sterile plastic mini suction tubes (Rhizon). The types of exudates analyzed in the rhizosphere soil samples were oxalate/oxalic acid, L-malate/L-malic acid, citrate/citric acid, succinate/succinic acid and lactic acid. For identifying possible organometallic complexes, detection of labile ion concentration of the above LMW carboxylates was done using capillary electrophoresis and high performance liquid chromatography instruments. Growth of individual plants, within the treatment and across the variants was supposed to offer more information with regard to the influence of the ectomycorrhizal symbiosis on LMW carboxylate release. For inducing mycorrhization of the tree seedlings, a single strain of ectomycorrhiza (AM747290) was used to avoid influence of allelopathic interactions when more strains are used (Wöllecke 2001). In order to characterize the impacts of mycorrhization on characterization of LMW carboxylates, the plant morphological parameters, such as, root tissue density (RTD) and specific root length (SRL), along with the above and below ground biomass were measured for mycorrhizal and non-mycorrhized seedlings. The task of accurate measurements included the consideration of excess weight contributed by the quartz sand particles adhered to roots. Weight corrections were applied during chemical and morphological measurements to increase the accuracy. Further, the organometallic complexes in the rhizosphere solution were calculated using a geochemical modelling software tool - PHREEQC. Depending on the complex forming abilities of LMW carboxylates present in the rhizosphere, organometallic complexes are formed with the cations. The outcome of this task was a development of a conceptual model to predict and compare the nutrients present in the plant to their availability in the rhizosphere which was supplemented by artificial nutrient supply.
Objective of the Transregional Collaborative Research Centre (CRC/TR) 38 was the study of structures and processes of the initial ecosystem development. It was assumed that the initial phase is characterized by less structured and therefore less heterogeneous ecosystems. Thus, analysis of young ecosystems in their initial stages should provide better insights into ecosystem functioning. Following this basic concept, the idea of the CRC/TR 38 was to analyze the establishment of new structures and processes which lead to a growing structuring and in consequence to a growing complexity and heterogeneity in an artificially created watershed. Further, with the help of this step-by-step development of the ecosystem it was aimed to learn from occurring feedbacks, which appear between old and newly emerging structures and patterns in order to better understand also the behavior of more mature systems. Special emphasis was placed on the spatial and temporal dynamics of both evolving structures and related processes and their interactions. In summary, the CRC/TR 38 was able to identify a number of structures and processes that are considered to be relevant and specific for young systems.
In der Praxis der Braunkohlegewinnung im Lausitzer Tagebaurevier werden natürlich gewachsene Böden in den betroffenen Gebieten zerstört. In der Folge entwickeln sich aus den verkippten Substraten nährstoffarme Rohböden, auf deren Oberflächen als erste Pioniere zumeist Grünalgen, Moose, Flechten und Bakterien siedeln, welche die obersten Bodenpartikel vernetzen und so biologische Bodenkrusten ausbilden. Diese Biokrusten stabilisieren die durch spärliche Vegetation gekennzeichneten Rekultivierungsflächen, wirken erosionshemmend und beeinflussen die Hydrologie und Wasserumverteilung der oberen Bodenschicht.
Ziel dieser Arbeit war die Untersuchung von unterschiedlichen Sukzessionsstadien von Biokrusten auf zwei Rekultivierungsflächen der Bergbaufolgelandschaft in der Niederlausitz, die durch unterschiedliche Substrateigenschaften, Topographie und Rekultivierungszeiten gekennzeichnet sind. Auf einer künstlichen Sanddüne und einer tertiären Fläche wurden Krustentypen hinsichtlich einer divergenten Artenausprägung und den damit verbundenen funktionellen Eigenschaften untersucht.
Parameter der Photosynthese wurden hinsichtlich ihrer Bedeutung für die Charakterisierung und Funktion der Biokrusten analysiert. Des Weiteren wurde der Einfluss der Biokrusten auf den Kohlenstoff- und Stickstoffhaushalt der Böden untersucht. Zuletzt sollte festgestellt werden, ob und wie die kleinräumige Mosaikstruktur der Biokrusten die Hydrologie sowie Funktion und Aktivität der Krustenorganismen beeinflusst. In Bezug auf die Artenzusammensetzung der Bodenkrusten konnten auf beiden Standorten Übereinstimmungen als auch Unterschiede festgestellt werden, da es sich bei allen Organismen um ubiquitäre Arten handelte. Auf beiden Standorten fanden sich die Grünalgen Zygogonium und Ulothrix, die Moose Ceratodon und Polytrichum sowie Flechten der Gattung Cladonia. In Schlabendorf wurde aufgrund der längeren Rekultivierungszeit bereits eine höhere Artendichte festgestellt. Das betraf besonders Arten der Flechtengattung Cladonia. Eine standortspezifische Präferenz hinsichtlich des Substrates oder der naturräumlichen Gegebenheiten nicht festgestellt werden konnte.
Die Auswertung der ökophysiologischen Parameter ergab einen Anstieg der Chlorophyllgehalte, des Normalized Difference Vegetation Index (NDVI), der Chlorophyllfluoreszenz sowie der Netto-Photosyntheseraten mit fortschreitender Krustenentwicklung. Der Anstieg der Photosynthese-relevanten Parameter verlief aufgrund der heterogenen Verteilung der Organismen zwischen den Biokrusten des gleichen Sukzessionsstadiums nur in frühen Stadien linear.
Die höchste photosynthetische Aktivität wurde bei den Moos-Krusten festgestellt, gefolgt von den Grünalgen-Krusten und den Flechten-Krusten. Das Verhältnis von Brutto-Photosynthese zu Respiration lies den Schluss zu, dass die CO2-Fixierungsrate in den Flechten-Krusten aufgrund der mycobiontischen Respiration niedriger ausfiel.
Die Infiltration in den Krusten wurde durch das Vernetzen von Sandpartikeln durch Grünalgen-Filamente und den Verschluss der Porenräume gehemmt. Die Wasserspeicherkapazität nahm jedoch aufgrund des organischen Materials zu. Das Auftreten von Moosen förderte hingegen die Infiltration und verringerte die Wasserhaltekapazität, da Rhizoide das Substrat auflockerten bzw. sich präferentielle Fließwege bildeten. Die C- und N-Gehalte der Krusten nahmen durch den Zuwachs der organischen Biomasse bei fortschreitender Entwicklung zu.
With regard to the depletion of global phosphorus reserves and with the aim of ensuring sustainable soil fertility on agricultural soils, a fundamental understanding of mechanisms of fixation and mobilization of inorganic phosphorus in soils is required. Amongst others, phosphorus availability is affected by ad- and desorption reactions on pedogenic Fe- and Al-hydroxide surfaces. The characterization of phosphate binding on those contrasting mineral surfaces can help to find solutions for enhancing the mobilization of fertilized but not available soil inorganic phosphate. Fourier-transform infrared spectroscopic experiments were carried out during phosphorus adsorption on crystalline gibbsite, poorly crystalline 2-line-ferrihydrite and amorphous Fe:Al-hydroxide mixtures. Desorption experiments with CaCl₂, CaSO₄, citric acid (C₆H₈O₇), and humic acid (C₉H₉NO₆) were conducted to determine the capacity of phosphate fixation and mobilization in short- and long-term. Additionally, phosphorus release from the Fe- and Ca-phosphates vivianite and hydroxyapatite were analyzed.
For gibbsite, the formation of AlHPO₄ and Al₂HPO₄ can be assumed, while for ferrihydrite, a FeHPO₄ or Fe₂PO₄ complex and the precipitation of FePO₄ with longer equilibration time were observed. Fe₂HPO₄ or a Fe₂PO₄ surface complex was deduced for amorphous Fe-hydroxides, an AlH₂PO₄ surface complex was identified for Al-hydroxides. The weakly associated amorphous FeO(OH) molecules enhance the precipitation of FePO₄. With high Al content, a weaker phosphate binding of both inner- and outer-sphere complexes and either no or minor quantities of precipitate were formed. Ferrihydrite showed a more rigid structure and a lower extent of precipitation compared to amorphous Fe-hydroxide. The cumulative phosphorus desorption followed the order CaCl₂ < CaSO₄ < humic acid < citric acid for crystalline and amorphous Fe- and Al-hydroxides as well for vivianite and hydroxyapatite. While inorganic anion exchange took part at easily available binding sites and fast exchangeable phosphorus, organic acids additionally affect the more heavily available binding sites and slow exchangeable phosphorus. For humic acid, the accumulation of metal-organic complexes in the desorption solution was suggested, whereas for citric acid the dissolution of the minerals was maintained. The cumulative release rates of the Flow-Through-Reactor setup were higher compared to batch due to a short residence time and a continuous concentration gradient. This could lead either to an over- or underestimation of the available phosphorus pools and influenced the comparability of both methods.