@phdthesis{Akhtar2022, author = {Akhtar, Fatima}, title = {Graphene synthesis under Si-CMOS compatible conditions}, doi = {10.26127/BTUOpen-5927}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:co1-opus4-59270}, school = {BTU Cottbus - Senftenberg}, year = {2022}, abstract = {Due to the unique electronic band structure, graphene has opened the great potential to extend the functionality of a large variety of graphene-based devices in health and environment, energy storage, or various microelectronic applications, to mention a few. At this point, the implementation of graphene into Silicon (Si) semiconductor technology is strongly dependent on several key challenges. Among them, high-quality and wafer-scale graphene synthesis on CMOS compatible substrates is of the highest importance. Though large-area graphene can be achieved on substrates like copper, platinum, silicon carbide, or single-crystal Ni, however, high growth temperatures, unavailability of large scale, or contamination issues are the main drawbacks of their usage. In this PhD work, 8-inch scale graphene synthesis is attempted on alternative substrates such as epitaxial Germanium on Si and polycrystalline Nickel on Si. To achieve the growth of the highest quality of graphene, this work focuses on the investigations of various nucleation and growth mechanisms, substrate-graphene interfaces, effects of different substrate orientations, and detailed microscopic and macroscopic characterization of the grown films. Finally, it should also be stressed that the experiments in this work were carried out in a standard BiCMOS pilot-line, making this study unique, as its results might directly pave the way to further graphene integration and graphene-based device prototyping in mainstream Si technologies.}, subject = {Graphene; Chemical vapor deposition; Growth; Oxidation; Germanium; Nickel; Graphen; CVD; Wachstum; Oxidation; Graphen; Keimbildung; Wachstum; CVD-Verfahren; Nickel; Germanium}, language = {en} }