@phdthesis{Reichmann2022, author = {Reichmann, Felix}, title = {Germanium, Zinn und (Zink-) Galliumoxid f{\"u}r fortschrittliche Mikro- und Optoelektronik : Einblicke in die elektronische Struktur der Oberfl{\"a}che mit Photoemissionstechniken}, doi = {10.26127/BTUOpen-6208}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:co1-opus4-62080}, school = {BTU Cottbus - Senftenberg}, year = {2022}, abstract = {Historically, Ge is one of the oldest materials in the semiconductor industry and its (001) surface has been the subject of extensive investigations by photoelectron spectroscopy. I am going to challenge the predominant attribution of a semi-conducting nature of the Ge(001) surface in this thesis. My investigations reveal the presence of a Ge(001) surface state above the Fermi-level, occupied at room temperature. Employing time- and temperature-dependent angle-resolved photoelectron spectroscopy, I will demonstrate that the presence of this surface state is evidence for the conducting nature of the surface at room temperature. Sparked by the remarkable properties of the GeSn-alloy and a trend towards Ge-Sn-related multiquantum well fabrication, I investigate the surface electronic structure of Ge(001) after adsorption and incorporation of Sn. With an in-depth analysis of surface core-level shifts, I will extend the growth model of the Sn wetting layer formation by also detailing structural changes in the subsurface region. At the same time, the modifications of the electronic structure will be detailed, observing the removal of the Ge(001) surface states, the creation of a new, Sn-related surface state and the initial stages of the Schottky barrier formation. β-Ga₂O₃ a transparent semi-conducting oxide that has sparked a lot of interest over the last decade, because it offers an ultra-wide band gap and high break down voltage. However, due to its monoclinic crystal structure, device fabrication is rather challenging and researchers are already looking into alternative materials. One of these candidates is ϵ-Ga₂O₃ and this work presents a combined study by photoelectron spectroscopy and ab initio calculations of its electronic structure. (Hard) X-rays reveal the impact of photoelectron recoil and the absence of a band bending to the surface, while the dispersion of experimentally determined valence states compares favorably with the calculations based on hybrid density-functional theory. Another alternative to β-Ga₂O₃ be ZnGa₂O₄ and I will present an investigation on the electronic structure of its (100) surface. Due to the novelty of ZnGa₂O₄ single-crystals, I am first going to explore the preparation of a clean and well-ordered surface by standard in-situ sputtering and annealing. I will show that already low annealing temperatures induce Zn-deficiency, leading to non-stoichiometric surfaces, further exacerbated by sputtering. By changing the sputtering parameters and the annealing conditions, the preparation of a surface with sufficient quality for subsequent investigations will be demonstrated. The results by photoemission techniques compare favorably with the expectations from theory and allowing the first fundamental insights into the surface electronic structure.}, subject = {Angle-resolved photoemission spectroscopy; X-ray photoelectron spectroscopy; Germanium-tin; Zinc gallium oxide; Surface science; ARPES; Gallium-Zink-Oxid; XPS; Halbleiteroberfl{\"a}che; Bandstruktur; Elektronenstruktur; Germaniumverbindungen; Galliumverbindungen; ARPES; R{\"o}ntgen-Photoelektronenspektroskopie}, language = {en} }