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Dissimilar metal weld overlays of nickel-base alloys on low-alloy steel components are commonly used in the oil and gas, petrochemical, and power generation industries to provide corrosion and oxidation resistance in a wide range of service Environments and temperatures. Traditionally, dissimilar weld overlays are produced using cold or hot wire gas tungsten arc welding.
This study aims to identify and evaluate potential advantages of low heat input gas metal arc welding processes over the conventional gas tungsten arc welding in the production of such overlays. Parts I and II of this publication series described characteristics of the heat-affected zone and the transition zone region of alloy 625 on grade 22 steel overlays. These results indicate a good resistance against hydrogen-assisted cracking, which is being verified within this third part of the publication series. To determine the hydrogen-assisted cracking susceptibility, welded samples are tested using the delayed hydrogen-assisted cracking test. Fractography is performed using scanning electron microscopy along with energy dispersive spectroscopy. The results confirm the suitability and efficiency of low heat input gas metal arc welding for dissimilar weld overlays. Variation of the postweld heat treatment procedure bears potential for improvement in this respect.
The present research work encloses results of experimental investigations of the interaction between welding process parameters for laser-beam and hybrid-laser-arc as well as type of the filler metal and the achievable mechanical properties of the weld joints on steel grade X8Ni9+QT640 for cryogenic service containing 9% nickel. The results obtained contribute to the development and conversion in the industrial practice a new laser beam-based welding technology for the automated manufacturing of facilities for the liquefaction, storage and the transport of natural gases (LNG facilities). The results show, that the martensitic microstructure of the laser weld metal including low amount of retained austenite not exceeding 3.5% leads to the relatively low V-notch impact energy. The remarkable heterogeneity in the chemical composition of the weld metal through the weld thickness could be recognized in the case of hybrid-laser-arc welding with ERNiCrMo-3 austenitic filler metal, what also led to insufficient impact toughness of the weld metall. The most promising results could be achieved by using 11%Ni filler wire, which is similar to the base metal and provides a homogeneous microstructure with uniform distribution of Ni through the weld seam. It is remarkable, that a correlation between Charpy impact toughness and wire feeding speed and respectively process heat input exists. The highest toughness values were 134±58 J at -196C. The both laser as well as laser-hybrid welds passed the tensile test. The failure stress of 720±3 MPa with a fracture location in the base material was achieved for all samples tested.
This study examines the relationship between the magnetic mesostructure with the microstructure of low carbon steel tungsten inert gas welds. Optical microscopy revealed variation in the microstructure of the parent material, in the heat affected and fusion zones, correlating with distinctive changes in the local magnetic stray fields measured with high spatial resolution giant magneto resistance sensors. In the vicinity of the heat affected zone high residual stresses were found using neutron diffraction.
Notably, the gradients of von Mises stress and triaxial magnetic stray field modulus follow the same tendency transverse to the weld. In contrast, micro-X-ray fluorescence characterization indicated that local changes in element composition had no independent effect on magnetic stray fields.
Low heat input gas metal arc welding for dissimilar metal weld overlays part II: the transition zone
(2018)
Dissimilar metal weld overlays (DMWOL) of nickel base alloys on low alloy steel components are commonly used in the oil and gas, petrochemical, and power generation industries to provide corrosion and oxidation resistance in a wide range of service environments and temperatures. Traditionally, dissimilar weld overlays are produced using cold or hot wire gas tungsten arc welding. This study aims to identify and evaluate potential advantages of low heat input gas metal arc welding processes over the conventional gas tungsten arc welding in the production of dissimilar weld overlays. In order to evaluate the quality of these overlays regarding resistance against hydrogen-assisted cracking, their transition zone region is investigated in this part of the publication series. Metallurgical characterization, including energy-dispersive x-ray spectroscopy, is performed on Alloy 625/grade 22 steel overlays. The transition zone is characterized by a narrow planar growth zone and steep compositional gradients from the fusion boundary towards the weld metal. Evidence of low carbon contents in the planar growth zone, as well as for carbide precipitation in the cellular growth zone was found. The microstructure in the transition zone region of the fusion zone shows characteristics known to be suitable for good resistance against hydrogen embrittlement.