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Impact resistance of reinforced concrete (RC) structures can be significantly improved by strengthening RC members with thin composite layers featuring high damage tolerance. Indeed, to limit the well-known vulnerability of cement-based materials against impact loading, the synergistic effects of short fibres and continuous textile meshes as hybrid reinforcement has been proved to be highly beneficial. This paper addresses the characterisation of novel cement-based hybrid composites through accelerated drop-weight impact tests conducted on rectangular plates at different impact energies. Two distinct matrices are assessed, with particular interest in a newly developed limestone calcined clay cement (LC3)-based formulation. Important parameters quantifying energy dissipation capability, load bearing capacity and damage are cross-checked to compute the ballistic limit and estimate the safety-relevant characteristics of the different composites at hand. Although textiles alone can improve the damage tolerance of fine concrete to some extent, the crack-bridging attitude of short, well-dispersed fibres in hybrid composites imparts a certain ductility to the cement-based matrices, allowing a greater portion of the textile to be activated and significantly reducing the amount of matrix spalling under impact.
Binary systems composed of Portland cement (PC) and calcium sulfoaluminate (CSA) cement have stood out for applications requiring high early strengths. Nevertheless, the application of these systems may be limited due to their properties in the fresh state, which requires a better understanding of the rheological behavior of these materials. Thus, this study evaluated the incorporation of different polycarboxylate-based superplasticizer (SP) contents (0.15, 0.20, and 0.25 wt%) on PC and PC-CSA binary cement pastes. Rotational rheometry, isothermal calorimetry, X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and nitrogen adsorption and desorption tests to assess the pore size distribution of cement pastes were conducted. While the SP incorporation reduced the dynamic yield stress of PC pastes, it progressively increased the yield stress of PC-CSA systems. The increase in SP content increased the main heat flow peak of PC-CSA pastes, although it did not significantly affect the cumulative heat after 160 h of hydration. FTIR and XRD confirm higher ettringite contents in the binary systems and indicate the presence of carboaluminates phases after 7 d of hydration in both PC and PC-CSA and hemicarboaluminate in PC-CSA pastes. The CSA incorporation reduced the cumulative pore volume by up to 32% compared to PC pastes, while the SP content evaluated did not significantly affect the porosity of PC-CSA pastes.
A thorough characterization of base materials is the prereq- uisite for further research. In this paper, the characterization data of the reference materials (CEM I 42.5 R, limestone pow- der, calcined clay and a mixture of these three components) used in the second funding phase of the priority program 2005 of the German Research Foundation (DFG SPP 2005) are presented under the aspects of chemical and min- eralogical composition as well as physical and chemical properties. The data were collected based on tests performed by up to eleven research groups involved in this cooperative program.
The mechanical properties of unstabilised earthen building materials are distinctively influenced by changes in material moisture content. However, this moisture-dependency often remains unconsidered in the calculation of the load-bearing capacity of earth constructions. This paper aims to derive a convenient way to sufficiently consider the impact of different material moisture contents on the mechanical properties of unstabilised earth masonry. Therefore, the influence of relative humidity and temperature on the strength and deformation characteristics of unstabilised earth blocks, earth mortar and earth masonry is evaluated by conducting compression tests under various climate conditions. The results show that the compressive strength and the modulus of elasticity are linearly correlated with the relative humidity, whereas changes in temperature at constant relative humidity have no significant influence. To account the distinct moisture-dependency, a general applicable modification factor for unstabilised earthen materials is provided, which enables the adjustment of the compressive strength and the modulus of elasticity in dependency of arbitrary hygroscopic material moisture contents.
Admixtures are important constituents to enhance the performance of concrete. They allow for more efficient use of binders which can mitigate negative environmental impacts from producing cement-based materials. Commonly used rheology modifying agents like polycarboxylate ethers or cellulose ethers are synthetic or semi-synthetic, respectively. This requires additional energy consumption for their production and global supply chains particularly for many developing regions, which will be large consumers of concrete in the future. However, many locally available bio-based polysaccharides could be effectively used instead. These polymers are often overlooked by engineers and scientists due to their limited distribution and inherent complexity, yet they represent an underleveraged source of precursors for admixtures. This study investigates the action mechanisms of some bio-based rheology modifying agents, i.e., acacia gum and miscanthus gum, and provides a comparison to a conventionally modified starch. The results show that the mechanism of action of these polymers is closely related to the composition of the mixture, mixing regime, and the composition of the aqueous phase. Depending on the agent, either plasticizing or stabilizing effects on rheology can be revealed.
In this article, a partial selection of experiments on enhancing the impact resistance of structural components with non-metallic, textile-reinforced concrete is discussed. The focus is on the experimental investigations in which the impact resistance of thin, textile-reinforced concrete plates is characterized. The article discusses the materials, fabrics and test setup used. For the experimental work, a drop tower from the Otto Mohr Laboratory, which belongs to the Technische Universtät Dresden, was used. Furthermore, the experimental results are presented and evaluated using different methods. Based on the collected data, a suitable approach to determining the perforation velocity of an impactor through the investigated thin, textile-reinforced concrete plates is shown.
The effect of resting time on the rheological properties of cement suspensions is generally explained by early formed structure and overconsumption of polycarboxylate superplasticizers (PCEs). In this paper, we propose that the influence of resting time on the rheological properties is closely related to size variation of non-absorbed PCE. To identify this, glass bead suspensions were prepared with various amounts of PCE and ionic solution, and their rheological properties were evaluated at various times. We found that the yield stress increases with time at higher PCE concentrations and higher ionic strength solutions. Adsorbed PCE during resting tends to bridge the particles rather than disperse them. In addition, it was found that hydrodynamic radius of PCE increased with resting time, and depletion forces resulting from non-absorbed PCE size changes correlate well with the increased yield stress.
Die heute in der Anwendung befindlichen Bemessungskonzepte für Ermüdung von Beton stammen zum Teil noch aus den 1990er Jahren und sind speziell hinsichtlich hochfester Betone konservativ ausgelegt. Um die Vorteile von Türmen für Windkraftanlagen, vor allem auch aus hochfesten Betonen, im Zuge des geplanten Ausbaus der Windenergieversorgung in Deutschland wirtschaftlich nutzbar zu machen, müssen diese Bemessungskonzepte weiterentwickelt werden. Dafür sind umfangreiche Untersuchungen zur Ermittlung von Bruchlastwechselzahlen und zur Charakterisierung der Schädigungsentwicklung unter Ermüdungsbeanspruchung erforderlich. Allgemein anerkannte bzw. verbindliche Regelwerke oder Verfahren zur experimentellen Bestimmung der Ermüdungsfestigkeit (Bruchlastwechselzahlen) an Betonproben gibt es zurzeit aber nicht und die bisher durchgeführten Untersuchungen variieren in Parametern wie Probengeometrie, Probengröße und Prüffrequenz. Eine vergleichende Analyse der Ergebnisse der Studien und insbesondere die Übertragbarkeit auf bauteilrelevante Abmessungen ist auf dieser Grundlage nur sehr eingeschränkt möglich.
Quenching and partitioning (Q&P) steels are characterized by an excellent combination of strength and ductility, opening up great potentials for advanced lightweight components. The Q&P treatment results in microstructures with a martensitic matrix being responsible for increased strength whereas interstitially enriched metastable retained austenite (RA) contributes to excellent ductility. Herein, a comprehensive experimental characterization of microstructure evolution and austenite stability is carried out on a 42CrSi steel being subjected to different Q&P treatments. The microstructure of both conditions is characterized by scanning electron microscopy as well as X‐ray diffraction (XRD) phase analysis. Besides macroscopic standard tensile tests, RA evolution under tensile loading is investigated by in situ XRD using synchrotron and laboratory methods. As a result of different quenching temperatures, the two conditions considered are characterized by different RA contents and morphologies, resulting in different strain hardening behaviors as well as strength and ductility values under tensile loading. In situ synchrotron measurements show differences in the transformation kinetics being rationalized by the different morphologies of the RA. Eventually, the evolution of the phase specific stresses can be explained by the well‐known Masing model.
This paper aimed to perform an exploratory literature review, focusing on the aspects of hydration and rheological properties of cementitious composites with açaí fibers. The use of natural fibers as a reinforcement in cementitious matrices has been widely studied, and açaí fiber is a promising option due to its unique characteristics. However, there is still a lack of knowledge regarding the correlation between fiber parameters and the technological properties of composites, which limits the development of new applications, such as 3D printing. The review provided an overview of the main characteristics of açaí fibers and the parameters for their application in cementitious matrices. Alkali treatment with 5% NaOH solution for 1 h shows increased mechanical and physical properties in açaí fibers. Despite the potential advantages of these composites, they pose challenges due to the different fiber surface treatment and interfacial transitions and the processing conditions of the fibers. Although small addition of açaí fibers slightly decreases the cement hydration process, keeping the cross-compatibility index high (>95). To overcome these challenges, it is necessary to evaluate the rheological behavior of cementitious materials with açaí fibers, which has not been reported in the literature. By doing so, it will be possible to optimize the processing conditions and develop new applications, such as additive manufacturing, which has never been explored with açaí fibers.