Ingenieurwissenschaften und zugeordnete Tätigkeiten
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Erscheinungsjahr
- 2023 (2) (entfernen)
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- Englisch (2)
Referierte Publikation
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Schlagworte
- C-F bond activation (1)
- Catalysis (1)
- Dispersive XAS (1)
- HF-shuttle (1)
- Heterogeneous catalysis (1)
- In situ (1)
- Structure analysis (1)
- ZCF (1)
Organisationseinheit der BAM
An amorphous Lewis-acidic zirconium chlorofluoride as HF shuttle: C–F bond activation and formation
(2023)
An exceptional HF transfer reaction by C–F bond activation of fluoropentane and a subsequent hydrofluorination of alkynes at room temperature is reported. An amorphous Lewis-acidic Zr chlorofluoride serves as heterogeneous catalyst, which is characterised by an eightfold coordination environment at Zr including chlorine atoms. The studies are seminal in establishing sustainable fluorine chemistry.