Analytische Chemie
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Paper des Monats
- ja (31)
The reconstruction of cone-beam computed tomography data using filtered back-projection algorithms unavoidably results in severe artefacts. We describe how the Direct Iterative Reconstruction of Computed Tomography Trajectories (DIRECTT) algorithm can be combined with a model of the artefacts for the reconstruction of such data. The implementation of DIRECTT results in reconstructed volumes of superior quality compared to the conventional algorithms.
Laser-induced breakdown spectroscopy (LIBS) and principal component analysis (PCA) are frequently used for analytical purposes in research and industry, but they seldom are part of the chemistry Curriculum or laboratory exercises. This case study paper describes the combined application of LIBS and PCA during a research internship for an undergraduate student. The instructional method applied was based on a one-on-one mentorship, in which case the learner was engaged in a Research work. The learning activities included theoretical introductions to the LIBS and PCA methods, numerical simulation, experiments, and data analysis.
The study covered three main topics: analysis of LIBS spectra, application of PCA for clustering, and use of PCA for experimental design. The realization of the study was instructive for all parties involved: from the mentorship point of view, it is concluded that the topics can be covered during an internship or developed into a one semester long research-based module of a chemistry program or a final year project. The student, on the other hand, developed profound technical skills in performing experiments and using PCA software for data analysis.
Aktive Thermografie wird zunehmend für die zerstörungsfreie Prüfung insbesondere von dünnwandigen Bauteilen eingesetzt. Neben der Ortung und der Bestimmung der lateralen Ausdehnung von Fehlstellen und Inhomogenität in der Ebene parallel zur Oberfläche sind in den Messdaten auch Informationen über die Tiefe bzw. Überdeckung von Fehlstellen enthalten. In der Vergangenheit wurden verschiedene analytische Ansätze zur Rekonstruktion dieser Tiefeninformationen umgesetzt:
- Bestimmung der Blindfrequenz über die Phaseninformationen der Puls-Phasen-Thermografie
- Bestimmung des Phasenkontrastes bei der Lockin Thermografie
- Bestimmung der Fehlstellentiefe mittels Thermal Signal Reconstruction (TSR), d. h. aus dem
doppeltlogarithmisch dargestellten zeitlichen Verlauf der Abkühlung nach impulsartiger Erwärmung
Nachteil aller bisherigen analytischer Verfahren basierend auf eindimensionalen Modellen ist, dass der Einfluss lateraler Wärmeleitungseffekte nicht berücksichtigt wird. Dieser kann jedoch bei kleineren Fehlstellen nicht mehr vernachlässigt werden, wozu bisher jedoch nur teilempirische Ansätze realisiert wurden. Erst numerische Rekonstruktionsverfahren ermöglichen eine Rekonstruktion auch komplexerer Defektgeometrien unter Berücksichtigung lateraler Wärmeleitungsprozesse sowie anisotroper thermischer Materialeigenschaften. In diesem B
eitrag werden die verschiedenen Ansätze in der 3D-Datenanalyse der aktiven Thermografie miteinander verglichen und die Möglichkeiten und Grenzen der Verfahren vorgestellt.
In most cases where a POD is calculated based on continuous data obtained by active thermography, the signal-to-noise ratio (SNR) of the signal, the difference of the defect signal to the background or the absolute signal is analyzed as a function of the aspect ratio (ratio of the size of a defect to its overage), although a distinct linear relationship on a linear or logarithmic scale could not be satisfactorily shown and is also not expected. Therefore, a multi-parameter probability of detection (POD) model was developed, where an â versus a continuous signal analysis was based on the linear relationship between the SNR and a multi-parameter a. This POD model is based on data which were recorded within a flash thermography round robin test with nine participants. Metal test specimens with flat bottom holes (FBHs) were analyzed by calculating the SNR of the defect signatures in the thermograms as well as in the phase images as a function of defect parameters. The linear relationship of the experimental data to the multi-parameter a was verified by comparison to data obtained from an analytical model that is considering lateral thermal heat diffusion as well as to data obtained by numerical simulation. The resulting POD curves for the thermograms and phase images give an estimation for the detectability of the FBHs with known geometry in steel using different equipment and obtained by different participants. By comparing the SNRs of FBHs with similar geometries, this POD model was transferred to aluminum and copper as well.
Der Umfang der durch Impacts in Faserverbundmaterialien erzeugten Schäden ist abhängig von der Energie des Impacts, von der Zusammensetzung und dem Aufbau der Faserverbundwerkstoffe und von der Geometrie der Bauteile und hier im Wesentlichen von der Dicke des Bauteils. Der zerstörungsfreie Nachweis dieser Schädigungen kann sowohl mit Ultraschallverfahren als auch mit Verfahren der aktiven Thermografie erfolgen. Ein Vergleich der Nachweisempfindlichkeiten dieser Verfahren für die unterschiedlichen Schädigungen wird in diesem Beitrag in Abhängigkeit vom verwendeten Faserverbundwerkstoff (CFK und GFK), der Dicke des Materials und von der Impactenergie durchgeführt. Ergänzt werden die im Anschluss an die Schädigung eingesetzten ZfP-Verfahren mit zeitlich hochaufgelösten Thermografiemessungen, die bereits während des Impacts aufgenommen wurden.
Quantification of impact damages in CFRP and GFRP structures with thermography and ultrasonics
(2018)
For the quantification of impact damage in CFRP and GFRP structures, first passive thermography measurements have been performed at the front and rear side of the test specimens during low velocity impact load. After loading, the damaged structures have been investigated non-destructively with active thermography with flash excitation and with step heating and with two different ultrasonic methods (phased array and air coupled ultrasonics). The damage sizes quantified with all methods are evaluated and compared. In addition, the depth of the greatest damage inside the different test specimens is analysed.
A round robin test on flash thermography was organized within the scope of a standardization research project. This test gives information on reliability, comparability and efficiency of different testing situations. Data recorded on metal and CFRP test specimens with flat bottom holes (FBH) were analysed by evaluating the detectability and by calculating the signal-to-noise ratio (SNR) of the defect signatures as a function of defect parameters. For the investigation of the influence of material properties on the spatial resolution as well as on penetration depth, test specimens made of steel and copper with crossed notches and a notch ramp were constructed and investigated. Here, the minimum resolvable notch distance and the maximum detectable depth of the ramp were analysed.
Within the scope of a DIN INS project, a flash thermography round robin test that evaluates reliability, comparability, and efficiency of different testing situations was organized. The results give information about the detectability of defects, e.g. depending on their size and depth, the evaluation methods and the materials used. Besides, the influences of equipment and parameters used by the participants on the results were analysed. All of the quantitative results as well as the feedback given by the participants will be presented in a DIN committee in order to contribute to a flash thermography standard.