Analytische Chemie
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Fatigue is one of the most prevalent issues, which directly influences the service life expectancy of concrete structures. Fatigue has been investigated for years for steel structures. However, recent findings suggest that concrete structures may also be significantly subjected to fatigue phenomena that could lead to premature failure of certain structural elements. To date, fatigue of reinforced concrete has been given little focus. Knowledge on the influence factors and durability/capacity effects on this material should be improved. Current technological means to measure fatigue in civil structures like bridges and wind turbines (both onshore and offshore) are outdated, imprecise and inappropriate.
Meanwhile, this topic has got much more attention as time-variant loading on concrete structures plays an increasing role, e.g. in bridges with increasing traffic and heavier trucks, and for wind turbines for renewable energy production, e.g. for offshore wind turbine support structures affected by wind and waves.
The European Innovative Training Networks (ITN) Marie Skłodowska-Curie Actions project INFRASTAR (Innovation and Networking for Fatigue and Reliability Analysis of Structures - Training for Assessment of Risk) provides research training for 12 PhD students. The project aims to improve knowledge for optimizing the design of new structures as well as for more realistic verification of structural safety and more accurate prediction of the remaining fatigue lifetime of existing concrete structures.
First, the INFRASTAR research framework is detailed. Then it will be exemplified through the presentation of the major results of the four PhD students involved in the work package dealing with auscultation and monitoring. This includes the development and improvement of Fiber Optics (FO) and Coda Wave Interferometry (CWI) for crack sizing and imagery, new sensor technologies and integration, information management, monitoring strategy for fatigue damage investigation and lifetime prediction.
The analysis of the chemical composition of cement-based materials like concrete is a crucial task in civil engineering. Concrete is a multi-phase material made of cement, water, aggregates, additives and admixtures. During the damage assessment of concrete structures, the external ingress of harmful species like chlorine, alkalis or sulfates needs to be determined. In order to provide a fast and precise analysis of concrete the application of LIBS offers unique possibilities as the technique can detect all elements at air atmosphere.
To determine the condition of concrete, the information about the chemical composition, the ingress of harmful species as well as the evaluation of characteristic values like the used cement type or the type of aggregates are needed. This work presents the two-dimensional evaluation of concrete samples using LIBS and multivariate data analysis of atomic and molecular emission. For the evaluation of the main components different classification methods will be applied to identify the heterogeneity of the samples. With respect to their specific phase, different species will be quantified using multivariate regression (PLS) and important figures of merit will be presented. All results will be verified using Standard procedure of wet chemistry (XRF, potentiometric titration and ICP-OES).
Zahlreiche Schädigungsprozesse in Baustoffen stehen im engen Zusammenhang mit Feuchteeintrag und Feuchtetransport. Als Beispiel sind die schädigende Alkali-Kieselsäurereaktion (AKR) von Beton sowie Frost-Tauwechsel induzierte Gefügeschäden genannt. Zur zerstörungsfreien, ortsaufgelösten Feuchtemessung eignet sich die im Bereich der Geophysik etablierte, aber im Bauingenieurwesen noch wenig verbreitete, Messmethode der Nuklear Magnetischen Resonanz (NMR). Unter Verwendung der NMR-Relaxometrie sind sowohl Aussagen zum Feuchtegehalt und dessen räumliche Verteilung als auch die Charakterisierung der Porengrößen möglich, die das Transportverhalten eines porösen Materials maßgeblich beeinflussen.
Zur Erfassung der Mikro- und Mesoporen in Baustoffen ist dabei die Auflösung von kurzen T2 Relaxationszeiten unabdingbar. Bisher ist es mit gängigen NMR-Laborgeräten nur begrenzt möglich, solche kurzen T2-Zeiten schichtselektiv zu erfassen. Vor diesem Hintergrund wurde ein speziell für die Messung an mineralischen Baustoffen optimierter NMR-Tomograph beschafft. Dieser ermöglicht sowohl schichtselektive Messungen von Bohrkernen mit Durchmessern von bis zu 70 mm als auch bildgebende Untersuchungen an Proben mit Durchmessern ≤ 40 mm.
Erste Untersuchungsergebnisse an Sandstein, Tuffstein und Beton zeigen die Leistungsfähigkeit des neuen NMR-Tomographen zur Erfassung der porengrößenspezifischen Feuchteverteilung. In diesem Beitrag werden erste Ergebnisse verschiedenartiger Laborversuche exemplarisch dargestellt.
Für Sandsteine mit unterschiedlichsten Porengrößenverteilungen wurden mit dem neuen NMR-Tomographen und einem herkömmlichen NMR-System vergleichbare T2 Zeitenverteilungen ermittelt. Am sehr heterogenen Tuffstein konnten unterschiedlich poröse (und feuchte) Bereiche räumlich aufgelöst werden. Im Beton ließ sich der Feuchtetransport im Zementstein porengrößenspezifisch, schichtselektiv und zeitlich aufgelöst verfolgen.
Die bisher gewonnenen Ergebnisse zeigen das breite Anwendungsspektrum des neuen NMR Tomographen auf und ermöglichen ein besseres Verständnis des Feuchtetransports und der oft damit einhergehenden Schädigungsprozesse in Baustoffen.
The propagation of ultrasonic waves in concrete is affected by its micro- and macro-structure, geometry and properties as well as external influences as stress, temperature or moisture. In addition, age and degradation have a strong influence. Therefore, Ultrasound has been used to monitor concrete samples and structures since decades. However, early applications using conventional techniques as time-of flight or changes in amplitudes have been limited to detect changes in a late stage close to serviceability or ultimate load states.
Around 2000, several new, more sensitive techniques adopted from geophysics or other field of material sciences have been introduced to research in ultrasonic monitoring of concrete. The most discussed methodologies are coda wave interferometry, a technique which allows to detect very subtle changes from repeated ultrasonic measurements. Nonlinear acoustic techniques help to identify e. g. cracks even in an inhomogeneous background. Both techniques can be combined.
This paper reviews methods and results achieved so far on the laboratory scale and with full scale models the directions for future research and application is given as well.
Ultrasonic transmission measurements are used to monitor concrete elements mostly on a laboratory scale since decades. Recently, coda wave interferometry, a technique adapted from seismology, has been introduced to civil engineering experiments. It can be used to reveal subtle changes in concrete samples and even large construction elements without having a transducer directly at the location where the change is taking place. The methodology works best with embedded transducers to avoid coupling issues or excessive environmental influence. These transducers can be used for newly built and existing structures. Recently, large concrete beams have been equipped with a network of transducers and loaded until failure. Using code wave interferometry, it was possible to visualize stress fields and damaged areas. This paper gives an overview of the state of the art, recent results achieved at BAM and a task list for further results and development.
Seismic methods are increasingly used to improve ultrasonic imaging and monitoring of concrete. At BAM, we are research mainly the use of Reverse Time Migration to get better images from ultrasonic echo data of thick, complex concrete structures. Coda wave interferometry is used to detect subtle changes in concrete constructions, e. g. using embedded ultasonic transducers.
Ultrasonic transmission measurements are used to monitor concrete elements mostly on a laboratory scale since decades. Recently, coda wave interferometry, a technique adapted from seismology, has been introduced to civil engineering experiments. It can be used to reveal subtle changes in concrete samples and even large construction elements without having a transducer directly at the location where the change is taking place. The methodology works best with embedded transducers to avoid coupling issues or excessive environmental influence. These transducers can be used for newly built and existing structures. Recently, large concrete beams have been equipped with a network of transducers and loaded until failure. Using code wave interferometry, it was possible to visualize stress fields and damaged areas. This paper gives an overview of the state of the art, recent results achieved at BAM and a task list for further results and development.
Ultrasonic non-destructive testing methods have found various applications in quality assurance and condition assessment of nuclear concrete structures. This includes but is not limited to the localization of construction features (thickness measurements, reinforcement, tendon ducts, and others) and damage detection (e. g. corrosion or cracks). However, there are still limitations, e. g. limited penetration depth and resolution, issues when testing hybrid steel/concrete structures as well as absence of standards and regulations.
This presentation will show progress in some of these issues and will focus on advanced instrumentation and validation of ultrasonic NDT for concrete structures.
Ultrasonic echo testing has been limited to a penetration depth of less than one meter in reinforced concrete. The development of the LAUS (Large Aperture Ultrasonic System), using a large array of ultrasonic transducers and wider offsets between transmitter and receiver, allows to reach up to 5 m in reinforced concrete and 9 m in unreinforced concrete. This capability has been demonstrated by collecting data from an engineered salt concrete barrier in an underground nuclear waste storage facility. Due to an increasingly competitive environment, commercial manufacturers will continue to develop equipment with enhanced penetration and/or increased resolution.
To quantify the capabilities and reliability of ultrasonic tests, validation mockups with engineered flaws are required. EPRI and BAM have built a large-scale mockup at a test site close to Berlin (BAM-TTS, Horstwalde) using a design which is repeated at other places. This presentation will also cover the methods deployed on engineered flaws and the repeatability of the test results.
The propagation of ultrasonic waves in concrete is affected by its micro- and macro-structure, geometry and properties as well as external influences as stress, temperature or moisture. In addition, age and degradation have a strong influence. Therefore, Ultrasound has been used to monitor concrete samples and structures since decades. However, early applications using conventional techniques as time-of flight or changes in amplitudes have been limited to detect changes in a late stage close to serviceability or ultimate load states.
Around 2000, several new, more sensitive techniques adopted from geophysics or other field of material sciences have been introduced to research in ultrasonic monitoring of concrete. The most discussed methodologies are coda wave interferometry, a technique which allows to detect very subtle changes from repeated ultrasonic measurements. Nonlinear acoustic techniques help to identify e. g. cracks even in an inhomogeneous background. Both techniques can be combined.
This paper reviews methods and results achieved so far on the laboratory scale and with full scale models the directions for future research and application is given as well.