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AbstractThe minor and trace element composition of minerals provides critical insights into a variety of geological processes. Multi-element mapping by laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) is an important technique applied for this purpose and although the method is rapidly advancing, there remains a fundamental compromise between spatial resolution, detection limit, and experiment duration when using sequential mass analyzers. To address the limitation of limited analyte selection for high spatial resolution maps imposed by the sequential nature of typical quadrupole (Q)-ICP-MS, we tested the Aerosol Rapid Introduction System (ARIS) for repeat mapping of the same area. The ARIS is a high-speed transfer tubing system that reduces aerosol washout times, permitting resolution of individual pulses at 40–60 Hz. Here, the ARIS was tested not for pulse resolution but with novel operating conditions optimized to perform fast, high spatial resolution mapping of minor and trace element distribution in pyrite and marcasite. For this purpose, ablation was conducted with a 5 µm beam aperture, a repetition rate of 50 Hz, and a continuous stage scan speed of 40 µm s−1. For each LA-Q-ICP-MS map, data were acquired for six elements with an acquisition time of 20 ms per element. This deliberately reduced the individual pulse resolution of the ARIS but instead exploited the spatial resolution and sensitivity gains afforded by the high-laser repetition rate combined with efficient aerosol transfer. The new method successfully mapped trace elements at single to double-digit parts per million levels, and the maps reveal fine-scale zoning of trace elements with an effective x and y resolution of 5 µm, while white light interferometry showed that for each experiment, only ca. 1 µm of the sample was removed. Repeated mapping of the same area showed excellent correspondence not only between element concentrations in successive experiments but also in the shape, dimension, and location of regions of interest defined by concentration criteria. The very good repeatability of the elemental maps indicates that for studies requiring more analytes, successive mapping of additional elements is possible. By contrast with conventional very small spot (i.e., 5 µm) analysis, fast repetition rate and stage scan speed mapping avoids down-hole fractionation effects and minimizes accidental analysis of buried invisible inclusions. Compared to conventional LA-ICP-MS mapping, the method reduces the experiment time by 4–8 times.
Geophysical methods are able to contribute significantly to geotechnical site characterization. In-situ parameters are collected and gaps between boreholes or other direct tests are filled with information. However the limited resolution has to be considered and the indirect geophysical parameters have to be translated into something geotechnically useful. Moreover, the limitations have to be evaluated when including geophysical data into geostatistical models. If done properly, the use of geophysics will help in an efficient and effective site characterization. A comprehensive overview on existing geophysical (mostly seismic) methods is given as well as information on the calibration of geophysical against geotechnical parameters, pitfalls and limitations and some hints how to include these data into geostatistical/geotechnical models.
Modern geophysical methods might be either directly applied to concrete structures or integrated into existing testing schemes to assist in quality assurance and inspections. This paper gives an overview on some ideas and developments from the author’s work:
• Vibrator technologies to improve pile integrity testing.
• Ideas from vertical seismic profiling used in multichannel pile inspection
• Cross- and downhole seismics to check the diameter of jet grouting columns
• Improving the parallel seismic methods for precise length measurement of piles and foundation walls
• Seismic migration methods to improve ultrasonic imaging of foundation slabs
• Seismological tools to monitor subtle changes in concrete constructions
The authors strongly believe that the cooperation between geophysics and civil engineering, which is obviously becoming stronger and stronger, will lead to a large number of innovative approaches.
Modern geophysical methods might be either directly applied to concrete structures or integrated into existing testing schemes to assist in quality assurance and inspections. This paper gives an overview on some ideas and developments from the author’s work:
• Vibrator technologies to improve pile integrity testing.
• Ideas from vertical seismic profiling used in multichannel pile inspection
• Cross- and downhole seismics to check the diameter of jet grouting columns
• Improving the parallel seismic methods for precise length measurement of piles and foundation walls
• Seismic migration methods to improve ultrasonic imaging of foundation slabs
• Seismological tools to monitor subtle changes in concrete constructions
The authors strongly believe that the cooperation between geophysics and civil engineering, which is obviously becoming stronger and stronger, will lead to a large number of innovative approaches.
Numerous case histories show evidence that geophysical
methods are valuable tools for levee inspection and
monitoring. National and international standards and
recommendations recommend the use of geophysics for a
variety of tasks. However, in some cases reported have
been flaws missed or false indications given. Due to the
larger variety in type, size and construction of levees and
the even larger variety of potential tasks and targets the
success of geophysical surveys still pretty much depends on
the available budget and the experience and capabilities of
the clients and contractors involved.
It is strongly recommended that all relevant parties agree
on the detailed objectives of the survey, required accuracy
and reliability of the results and any follow up measures.
For the most common tasks more research and practical
work using techniques as POD (probability of detection),
which are well established in other fields of non-destructive testing, would be of benefit.