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Certification report for the reference materials ERM-AE102a, -AE104a, -AE120, -AE121 and -AE122
(2010)
Isotope reference materials are essential to enable reliable and comparable isotope data. Besides the correction of mass fractionation or mass discrimination isotope reference materials are indispensible for validation and quality control of analytical procedures. This article describes the production and certification of a set of five isotope reference materials ERM-AE102a, 104a, AE120, 121 and 122, for boron isotope analysis. The isotopic composition of all materials has been adjusted by mixing boron mother solutions enriched in 10B or 11B with a boron mother solution having natural-like isotopic composition under full gravimetric control. All mother solutions have been analysed for their boron mass fraction as well as their boron isotopic composition by TIMS using IDMS as calibration technique. For all five reference materials the isotopic composition obtained on the basis of the gravimetric data agrees very well with the isotopic composition obtained from different TIMS techniques. Performed stability and homogeneity studies show no significant influence on the isotopic composition as well as on the related uncertainties.
The certified isotope abundances for 10B are 0.29995 (27) for ERM-AE102a and 0.31488 (28) for ERM-AE104a. The certified δ11B values are -20.2 (6) ‰ for ERM-AE120, 19.9(6) ‰ for ERM-AE121 and 39.7 (6) ‰ for ERM-AE122.
Together with the formerly certified ERM-AE101 and -AE103 a unique set of seven certified reference materials (CRM) for boron isotope analysis is now available from BAM.
The classification of solid oxidizers according to the GHS (Globally Harmonized System of Classifica-tion and Labelling of Chemicals) and according to regulations on the transport of dangerous goods (based on the UN Recommendations/Model Regulations and implemented in all carrier domains as transport by road, railway, sea, air) is performed on the basis of the results of the UN test O.1 (―Test for oxidizing solids‖ described in chapter 34.4.1 in the Recommendations on the Transport of Danger-ous Goods, Manual of Tests and Criteria, Fifth revised edition, United Nations, New York and Geneva, 2009). This test was introduced into the UN Test Manual in 1995 as a replacement for a similar test from 1986. Even though the O.1 test is much better than the previous one there are still many prob-lems with this test. For this reason the IGUS-EOS working group (international group of experts on the explosion risks of unstable substances – working group: energetic and oxidizing substances) installed an ad-hoc working group in 2002 assigned with the task of proposing solutions for the existing prob-lems. The adequacy of such proposals has to be proven preferably by interlaboratory comparison (interlaboratory test) before they are presented to the UN Sub Committee for adoption into the UN Test Manual. The present report is the evaluation of an interlaboratory test which was designed by the Ad-hoc working group in order to find out whether the current method of comparing combustion times of test mixtures with those of reference mixtures is suitable in principle and whether some approaches for improvement of the method can be identified.
Transfer admittance spectra of technically induced surface wave fields are analyzed in theory and experiments. Theoretical admittance spectra of layered soils are obtained by integration in wavenumber domain and compared with experimental admittances due to hammer or vibrator excitation. The admittance spectra are strongly influenced by the layering and damping of the soil. Deep stiff-soil layers yield a low-frequency cutoff, whereas a strong damping yields a high-frequency cutoff. A sharp cutoff in a narrow frequency band, which is measured at some sites, can be explained by a damping that increases with frequency, such as viscous material or scattering damping.
The attenuation of the amplitudes with distance of technically induced surface wave fields is analyzed in theory and experiments. Experimental results of technically induced ground vibration are presented and collected from literature, which show a power-low attenuation A ~ r–q of amplitudes A with distance r and exponents q > 0.5 higher than for elastic surface waves. Additional attenuation effects are analyzed theoretically. The most important effect is due to the material or scattering damping. Each frequency component is attenuated exponentially as A ~ exp(–kr), but for a broadband excitation, the sum of the exponential laws yields a power law with a higher exponent. Some more effects are discussed, for example the dispersion of the Rayleigh wave due to the layering of the soil, which yields a stronger attenuation A ~ r–q–dq, including an additional exponent of dq = 0.5 in case of an impulsive loading.