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The ultrasonic echo technique is frequently used in non-destructive testing (NDT) of concrete structures for thickness measurements, geometry determinations as well as localization of built-in components. To improve ultrasonic imaging of complex structures in concrete, we transferred a geophysical imaging technique, the reverse time migration (RTM), to NDT in civil engineering. In contrast to the conventionally used synthetic aperture focusing technique (SAFT) algorithms, RTM is a wavefield continuation method in time and uses the full wave equation. Thus, RTM can handle complicated wave propagations in any direction without dip limitation. In this paper, we focused on the application and evaluation of a two-dimensional (2D) elastic RTM algorithm considering compressional waves, vertically polarized shear waves, and Rayleigh waves. We tested the elastic RTM routine on synthetic ultrasonic echo data generated with a 2D concrete model consisting of several steps and circular air inclusions. As these complex structures can often be found in real-world NDT use cases, their imaging is especially important. By using elastic RTM, we were able to clearly reproduce vertical reflectors and lower edges of circular air voids inside our numerical concrete model. Such structures cannot be imaged with conventional SAFT algorithms. Furthermore, the used elastic RTM approach also yielded a better reconstruction of a horizontal reflector and upper boundaries of circular air inclusions. Our encouraging results demonstrate that elastic RTM has the potential to significantly improve the imaging of complex concrete structures and, thus, is a step forward for detailed, high-quality ultrasonic NDT in civil engineering.
The Boltzmann plot method is widely used to determine the temperature of laser induced plasma. It involves the use of individual lines that are not easy to find in complex spectra and/or in the spectral range available. If the number of such lines is not enough to build a reliable Boltzmann plot, overlapping lines are often used, which are separated by software. However, line separation is a rather imprecise procedure, which, in addition, requires significant computational costs. This study proposes an extension of the Boltzmann plot method that allows a specific group of unresolved lines to be included in a Boltzmann plot without the need to separate them. This group of lines are multiplets, lines of the same element with similar upper and lower transition states. The multiplet lines along with the individual lines are included in the algorithm, which also includes a correction for self-absorption and is used to determine the plasma temperature. The algorithm is tested on synthetic spectra which are consistent with the model of a homogeneous isothermal plasma in local thermodynamic equilibrium and is shown to be superior to the standard Boltzmann plot method both in more accurate determination of the plasma temperature and in a significant reduction in the computational time. The advantages and disadvantages of the method are discussed in the context of its applications in laser induced breakdown spectroscopy.
Volatile organic compound (VOC) emissions from consumer products contribute to human inhalation exposure and may cause adverse health effects. Existing methods to determine long-term VOC emissions from e.g. building products need to be verified for their suitability to reliably detect initial VOC emissions from consumer products within the first hours and days of use, which would facilitate realistic inhalation exposure assessments. To investigate this issue, VOCs emitted from a test sample were determined in a large-scale emission test chamber and in two micro-chambers of different volumes, and the results were compared.
Ultrasonic coda wave interferometry can detect small changes in scattering materials like concrete. We embedded ultrasonic transducers in the Gänstorbrücke Ulm, a monitored road bridge in Germany, to test the methodology. Since fall 2020, we've been monitoring parts of the bridge and comparing the results to commercial monitoring systems. We calculate signal and volumetric velocity changes using coda waves, and long-term measurements show that the influence of temperature on strains and ultrasound velocity changes can be monitored. Velocity change maps indicate that different parts of the bridge react differently to environmental temperature changes, revealing local material property differences. A load experiment with trucks allows calibration to improve detectability of possibly damaging events. Our work focuses on measurement reliability, potential use of and distinction from temperature effects, combination with complementary sensing systems, and converting measured values to information for damage and life cycle assessment.
Ultrasonic coda wave interferometry can detect small changes in scattering materials like concrete. We embedded ultrasonic transducers in the Gänstorbrücke Ulm, a monitored road bridge in Germany, to test the methodology. Since fall 2020, we've been monitoring parts of the bridge and comparing the results to commercial monitoring systems. We calculate signal and volumetric velocity changes using coda waves, and long-term measurements show that the influence of temperature on strains and ultrasound velocity changes can be monitored. Velocity change maps indicate that different parts of the bridge react differently to environmental temperature changes, revealing local material property differences. A load experiment with trucks allows calibration to improve detectability of possibly damaging events. Our work focuses on measurement reliability, potential use of and distinction from temperature effects, combination with complementary sensing systems, and converting measured values to information for damage and life cycle assessment.
Accurate and precise isotope ratio measurements of heavy elements are playing an increasinglyimportant role in modern analytical sciences and have numerous applications. Today, isotope ratio measurements are typically performed with two principal techniques: thermal ionization mass spectrometry (TIMS) and multiple collector-inductively coupled plasma mass spectrometry (MC-ICP-MS). To obtain accurate results by mass spectrometry, isotopic certified reference materials (iCRMs) are needed for mass bias correction and for the validation of the method used for analysis.Thus, it is of paramount importance to achieve measurement comparability of all data reported, and to assess measurement capability of each CRM producer/National Metrology Institute (NMI). Therefore, the international comparison (CCQM-P213) was performed to assess the analytical capabilities of NMIs for the accurate determination of copper isotope ratio delta values in high purity materials. The study was proposed by the coordinating laboratories, National Research Council Canada (NRC), National Institute of Standards and Technology (NIST), Bundesanstalt für Materialforschung und -prüfung (BAM) and Physikalisch-Technische Bundesanstalt (PTB), as an activity of the Isotope Ratio Working Group (IRWG) of the Consultative Committee for Amount of Substance - Metrology in Chemistry and Biology (CCQM). Participants included six NMIs and one designated institute (DI) from the six countries. Although no measurement method was prescribed by the coordinating laboratories, MC-ICP-MS with either standard-sample bracketing (SSB) or combined SSB with internal normalization (C-SSBIN) models for mass bias correction were recommended. Results obtained from the six NMIs and one DI were in good agreement.
This study describes an interlaboratory comparison (ILC) among nine (9) laboratories to evaluate and validate the standard operation procedure (SOP) for single-particle (sp) ICP-TOFMS developed within the context of the Horizon 2020 project ACEnano. The ILC was based on the characterization of two different Pt nanoparticle (NP) suspensions in terms of particle mass, particle number concentration, and isotopic composition. The two Pt NP suspensions were measured using icpTOF instruments (TOFWERK AG, Switzerland).
Two Pt NP samples were characterized and mass equivalent spherical sizes (MESSs) of 40.4 ± 7 nm and 58.8 ± 8 nm were obtained, respectively. MESSs showed <16% relative standard deviation (RSD) among all participating labs and <4% RSD after exclusion of the two outliers. A good agreement was achieved between the different participating laboratories regarding particle mass, but the particle number concentration results were more scattered, with <53% RSD among all laboratories, which is consistent with results from previous ILC studies conducted using ICP-MS instrumentation equipped with a sequential mass spectrometer. Additionally, the capabilities of sp-ICP-TOFMS to determine masses on a particle basis are discussed with respect to the potential for particle density determination. Finally, because quasi-simultaneous multi-isotope and multielement determinations are a strength of ICP-TOFMS instrumentation, the precision and trueness of isotope ratio determinations were assessed. The average of 1000 measured particles yielded a precision of below ±1% for intensity ratios of the most abundant Pt isotopes, i.e. 194Pt and 195Pt, while the accuracy of isotope ratios with the lower abundant isotopes was limited by counting statistics.
Per- and polyfuoroalkyl substances (PFAS) are emerging organic pollutants and can occur in surface and groundwater. To identify the degree of pollution in surface water with PFAS, often targeted HPLC–ESI–MS/MS has been employed in which commonly 30–40 compounds are analyzed. However, other PFAS and organofuorines remain undetected. We sampled surface water of the river Spree and the Teltow Canal in Berlin, Germany, which are afected by the efuent discharge of wastewater treatment plants. Here, we employed high-resolution continuum source graphite furnace molecular absorption spectrometry (HR-CS-GFMAS) for measuring extractable organofuorines (EOF) and compared in a mass balance approach the total fuorine to the identifed and quantifed PFAS from the targeted analysis. The analysis highlights that the EOF are in the range expected for an urban river system (Winchell et al. in Sci Total Environ 774, 2021). However, downstream of an efuent discharge, the EOF increased by one order of magnitude, e.g., 40.3 to 574 ng F L−1, along the Teltow Canal. From our target analytes, mostly short-chained perfuorinated carboxylic acids and sulfonates occur in the water, which however makes up less than 10% of the EOF. The increase in EOF in the Teltow Canal correlates well with the increase of perfuorohexanoic acid (PFHxA), indicating that PFHxA is characteristic for the discharged EOF but not responsible for the increase. Hence, it points to PFHxA precursor discharge. The study highlights that EOF screening using HR-CS-GFMAS is necessary to identify the full scale of pollution with regard to PFAS and other organofuorines such as pharmaceutical compounds from the efuent of WWTPs.
Wasserstoff als flexibel einsetzbarer und leicht transportierbarer Energieträger bildet eine Schlüsselkomponente auf dem Weg zu einer klimaneutralen Energiewende. Zur Speicherung von gasförmigem Wasserstoff kommen bei stationären und auch mobilen Anwendungen meist Druckbehälter aus Verbundwerkstoffen zum Einsatz. Dabei ist für den Betrieb der Behälter die Gewährleistung der Sicherheit von großer Relevanz. Structural Health Monitoring (SHM) bietet einen innovativen Ansatz, um sowohl die Sicherheit als auch die Zuverlässigkeit der Druckbehälter zu gewährleisten und kritische Versagensfälle zu vermeiden.
Zur kontinuierlichen Überwachung und Bewertung des Zustands eines Wasserstoffdruckbehälters wird in dem vorliegenden Beitrag eine aktive Methode präsentiert, die auf geführten Ultraschallwellen basiert. Dabei kommt das Pitch-Catch Verfahren zwischen Sender und Empfängern zur Überwachung der strukturellen Integrität zum Einsatz. Auf Grundlage des untersuchten Wellenausbreitungsverhaltens im Druckbehälter sowie der Geometrieeigenschaften wird ein Sensornetzwerk aus piezoelektrischen Flächenwandlern (PZT) zur Abdeckung des zu überwachenden Bereichs entworfen. Ziel ist es mit Hilfe eines Optimierungsalgorithmus eine größtmögliche Abdeckung bei gleichzeitiger Minimierung der Anzahl der Sensoren zu erreichen. Zudem soll eine gleichmäßige und platzsparende Verteilung im Vordergrund stehen, so dass zukünftig weitere Messmethoden auf dem Druckbehälter angewendet werden können (z. B. durch akustische oder faseroptische Sensoren).
Das für die Anwendung optimierte Sensornetzwerk wird anschließend hinsichtlich der Robustheit bei der Schadenserkennung und -lokalisierung durch Aufbringen von künstlichen Schäden evaluiert. Die Ergebnisse zeigen, dass die künstlichen Schäden am Wasserstoffdruckbehälter nachgewiesen werden können.
This presentation provides a short introduction to the Commission on Isotopic Abundances and Atomic Weights (CIAAW). It describes the role of the Commission and provides an insight into its work and the corresponding principal tasks. Finally, it provides the reader with the latest achievements and with the most recent publications.