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Eingeladener Vortrag
- nein (149)
The demands for modern flame retardants are higher than ever: a flame retardant must function effectively in a certain polymer matrix and avoid critical alterations to the material’s properties. Ideally, a flame retardant additive should be easily miscible and show no sign of leaching or blooming from the matrix. Additionally, the flame retardant should be non-toxic, non-accumulating and biocompatible. Hyperbranched polymers are a promising group of multifunctional flame retardants which fulfill these demands: their complex shape enables high miscibility and avoids leaching or blooming, while their high molecular weight potentially increases biocompatibility and lowers accumulation and toxicity. Moreover, they exhibit a low impact on polymer properties and a good flame retardant performance.
This work examines the efficacy and mode of action of phosphorus-based hyperbranched polymeric flame retardants in bisphenol A-based epoxy matrices. To investigate the effect of the complex shape, the hyperbranched polymers are compared to their corresponding monomeric variants. Furthermore, the materials are synthesized to contain systematically varying oxygen-to-nitrogen ratios, allowing for new insight into what role the chemical surrounding of phosphorous plays in flame retardant efficacy.
Using a multi-methodical approach, including thermogravimetric analysis coupled with Fourier transform infrared spectroscopy (FTIR), hot stage FTIR, micro combustion calorimetry, differential scanning calorimetry, oxygen index (LOI), UL-94 tests and cone calorimetry experiments, the decomposition mechanisms and the flame retardant modes of action of these flame retardants in epoxy resins are investigated, shedding new light on the chemistry of flame retardancy.
Intumescent coatings for fire protection offer advantages over (non-intumescent) cementitious coatings and boards regarding speed of construction, architectural aesthetics, sometimes costs, and other features. However, conventional organic intumescent coatings as well as soluble silicate (waterglass) coatings form foams with low mechanical stability, and the latter coatings generally suffer from low resistance against humidity. Therefore, the search for novel intumescent coatings for more demanding conditions (e.g., abrasive environments) is a necessity in the context of steadily increasing requirements of society and industry.
In this contribution, we present results on intumescent aluminosilicate coatings for fire protection that form foams with significantly increased mechanical strength. Two base formulations, a metakaolin/silica-based mix, adapted from Krivenko et al., and a silica/corundum-based mix, developed at Curtin University, as well as formulations modified with additives (Al(OH)3, Mg(OH)2, B2O3, Na2B4O7), were applied to steel plates (75 mm × 75 mm) and exposed to simulated fire conditions (fire curve according to ISO 834-1:1999). Temperature-time curves were recorded to assess the degree at which the coatings insulated the substrate. In addition, XRD, TG, oscillatory rheometry, and SEM were employed to characterise the coatings.
The coatings were observed to partly expand during hardening due to H2 formation. When the hardened coatings were exposed to elevated temperatures they intumesced as expected, with the degree and nature of expansion dependent on the formulation. Oscillatory rheometry provided insights into the intumescent processes in an apparently brittle material. It revealed that the hardened aluminosilicate coatings became viscous (loss factor > 1) at 75–225 °C, in the temperature range of major water release, as opposed to a “standard” metakaolin-based geopolymer, which continued to behave as a solid. This explains the intumes¬cent behavior of the coatings, i.e. further expansion and foam formation. Microstructural analysis confirmed pore expansion and coalescence; XRD showed that the phases formed after heating (max. temperature ~840 °C) were of ceramic-type.
The fire protection (defined here as the time for the steel substrate to reach the critical temperature of 500 °C) depended mainly on the thick¬ness of the fully expanded coating, i.e. after intumescence. An alumino¬silicate coating free of additives with an original thickness of 12 mm was able to protect the steel for >30 min. The addition of 10 % anhydrous borax (Na2B4O7) caused a significant improvement, such that an original coating thickness of only 6 mm was sufficient to protect the steel for ~30 min. This was caused by the formation of sodium metaborate dihydrate (NaB(OH)4) in the coating that led to a significantly extended dehydration plateau in the temperature-time curve at ~100 °C during the fire exposure.
A preliminary analysis has been presented on the advantages for Mexico to migrate the cargo from trucking to railways. While the approach is highly unrealistic, it describes interesting figures that should animate the interest of Mexico to develop its railway infrastructure. Adverse situations due to the topographic characteristics of the mostly populated area of Mexico. The data presented in this paper suggest that the building of railway infrastructure is economically feasible.
Thermoplastic starch polymer blends as biodegradable materials are well known and used mainly as packaging material. In order to exploit new application fields for these materials, additional properties such as flame retardancy or increased mechanical strength are required. This work focuses on the flammability and fire behavior of a thermoplastic starch/polyester blend reinforced with natural fibers derived from Mexican industry processes wastes, such as keratin fibers from the tannery industry or coconut fibers[1]. Different fiber contents as well as combinations of varying contents of aluminum trihydroxide, expandable graphite or ammonium polyphosphate were tested in LOI, UL94, cone calorimeter and TG-FTIR in order to investigate and assess the concentration dependence of the fibers and flame retardants as well as synergistic effects between both components. In combination with ammonium polyphosphate, the coconut fibers induce a synergistic effect by reinforcing the char residue and creating a more stable heat barrier during forced flaming combustion in the cone calorimeter. Synergism is also observed in the oxygen test. The recycling of otherwise wasted material is a true challenge in material development, thus this work is a first step in the direction of sustainable and biodegradable materials.
Immer wieder werden Feuerwehren bei Einsätzen mit brandbeaufschlagten Acetylenflaschen konfrontiert. Im Falle eines Behälterversagens stellen diese eine enorme Gefährdung für die Einsatzkräfte dar. Die BAM beschäftigt sich seit vielen Jahren mit den Auswirkungen im Falle eines solchen Behälterversagens. Der Beitrag stellt die Arbeit der BAM auf diesem Gebiet vor und zeigt verschiedene Handlungsoptionen auf, um das Risiko für die Einsatzkräfte zu verrringern. Weiterhin wird ein Merkblatt zu brandbeaufschlagten Acetylenflaschen vorgestellt, welche zusammen mit der DGUV im Jahr 2018 herausgegeben werden.