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EU project ODYSSEUS - year 1
(2022)
Vorstellung EU-Projekt ODYSSEUS zum Thema Home-Made-Explosives sowie erste Ergebnisse bzgl. Rezepten, Ausgangsstoffen und Home-Made-Explosives in diesem Zusammenhang.
The volumetric energy density of a gas can be increased by liquefaction, which occurs when the gas is cooled below the saturation point. Liquefied gases of great importance to the energy transition are Liquefied Hydrogen (LH2) and Liquefied Natural Gas (LNG), which can be liquefied at temperatures below 160°C. Systems for storing these gases typically must be overpressure resistant and require thermal super insulations (TSI) to hold cryogenic conditions and minimize boil-off losses from evaporation. TSI with vacuum and MLI or perlites are suitable for many applications involving LNG and LH2. Such systems are typically double-walled structures where the inner wall is in contact with the cryogenic liquefied gas. MLI or perlites are located in the gap between the inner and the outer wall, that is kept under vacuum conditions. This combination of insulations strongly reduces the heat transfer between the environment and the cryogenic liquefied gas. From an economic point of view the systems are well sophisticated. However, knowledge of the behavior of this kind of systems in a typical event such as a fire is limited, but necessary to evaluate the safety of the increasing number of applications.
The objective of the research is to determine how TSI behaves at different fire temperatures during fire exposure and afterwards. Special attention is paid to changes in the heat flux, the material properties and vacuum state over time. For this purpose, thermogravimetric analysis (TGA) studies have been carried out. In addition, a test rig was developed that allows testing of TSI at temperatures up to 1000°C under realistic integration conditions and subsequent analysis of the TSI samples. In the test rig the double-wall with vacuum and MLI or perlites inside is simulated. The fire conditions are simulated on one side of the double-wall by adjustable electrical heating elements. This process allows the implementation of repeatable heat flows of up to 100 kW/m². On the other side of the double-wall, cold or cryogenic conditions are simulated with a heat exchanger through which water or the vapor of liquid nitrogen (approx. -196°C) flows. The heat exchanger is also used to determine the heat flux through the double-wall. Thus, the test rig allows thermal loading and performance analysis of TSI samples at the same time.
Compared to tests with real cryogenic systems, tests with this experimental setup have the advantage that, first, the instrumentation is easier to realize, and a higher repeatability is ensured. Second, the local heat flow can be determined over time, and the sample of a TSI can be taken non-destructively and thus analyzed. Third, the tests are less risky as well as time+ and material intensive, so that more tests and variants can be investigated with the same budget.
Preliminary results obtained considering several types of MLI under vacuum show that all observed typs of MLI can be damaged under strong thermal loading. The damages observed were outgassing, melting, shrinkage, cracking, lump formation, and concomitant local loss of the MLI's function as a radiation shield. However, the study also shows that a damage does not always have an extreme effect on the insulating performance.
Earth buildings and adobe construction have been in use for thousands of years. Loam is locally available, environmentally friendly and has a small CO2 footprint mainly resulting from extraction and transport. Because of these reasons loam is one of the building materials of the future.
Water resistance is an important aspect when using loam as a construction material. If the structural option of building protruding roofs cannot be implemented, the water resistance of clay can be improved by stabilization.
Positive properties of the material should not be diminished by stabilization. For example, the desired regulation of air humidity, which however cannot be fully preserved by cement stabilization.
For an alternative and more appropriate stabilisation, different mixtures with calcined clays with alkali activator were examined. The calcination temperature for clays is usually lower than for cement and starts at 600° C. The calcined clays therefore also have a lower CO2 footprint compared to cement. To keep the mixture environmentally friendly potassium was used as alkali ion. It could be proven that the alkali activated polymer enhances water resistance of the loam mixture. Provided some further optimization the material shows potential to replace cement without compromising on the positive properties of clay.
The low calcination temperature for clays (600° C) and a low CO2 footprint compared to cement make them an interesting material. To find a stabilization method for loam using calcined clays, activation by alkalis was necessary. Therefore (and to keep the mixture environmentally friendly) KOH was used as alkali activator. It could be proven that the alkali activated polymer enhances water resistance of the loam mixture.
Der Vortrag stellt die wesentlichen Inhalte sowie die wichtigsten Änderungen der TRGS 510 "Lagerung von Gefahrstoffen in ortsbeweglichen Behältern" vor.
Die TRGS 510 zeichnet sich durch ein gestuftes Maßnahmenkonzept in Abhängigkeit von der Art und Menge der gelagerten Gefahrstoffe aus. Folgende Maßnahmenstufen werden durch die TRGS 510 beschrieben:
1. Kleinmengen -> Allgemeine Maßnahmen
2. Überschreitung der Kleinmengen -> Lagerung im Lager
3. Überschreitung bestimmter Mengen für spezielle Gefahrstoffe -> Spezielle Maßnahmen
4. Verschiedene Gefahrstoffe und Lagerung im Lager erforderlich -> ggf. Getrenntlagerung und Separatlagerung
According to the NBI database, more than 21,000 in-service U.S. bridges lack sufficient structural documentation necessary for analytical load rating. Among these are a significant proportion of older prestressed concrete bridges. Given the lack of documentation on the reinforcing layout, such structures cannot be load rated analytically and are often subject to engineering judgement as the basis for rating. Otherwise, the typical approach for load rating such bridges is to conduct costly proof load testing and destructive probing together with making conservative assumptions. Therefore, any improvement to current practices will benefit DOTs and taxpayers alike. Accurately reconstructed 3D images of the girders to reflect the internal reinforcement could mitigate the need for costly, if not impractical, destructive testing and proof load testing, and help reduce dependency on conservative assumptions. This study examines a comprehensive NDE approach using ultrasonic tomography and GPR to aid in gathering structural information for load rating purposes. Different types of AASHTO and hollow core girders were tested.
Reaktive Brandschutzsysteme finden im baulichen Brandschutz Anwendung zur Erhöhung des Feuerwiderstands von Stahlkonstruktionen. Neben den Anforderungen an die Feuerwiderstandsdauer können damit auch Ansprüche an die Ästhetik erfüllt werden. Die profilfolgende Applikation und die geringen Trockenschichtdicken der Produkte ermöglichen es, das filigrane Erscheinungsbild von Stahlkonstruktionen aufrechtzuerhalten. Neben der thermischen Schutzwirkung muss auch die Dauerhaftigkeit der Brandschutzbeschichtung sichergestellt werden. Die Bewertungsmethoden, die auf europäischer Ebene durch das EAD 350402-00-1106 zur Verfügung stehen, zielen auf eine Nutzungsdauer von zehn Jahren ab. Prüfverfahren für einen darüber hinausgehenden Zeitraum sind nicht beschrieben. In diesem Beitrag werden experimentelle Untersuchungen zum Einfluss der Bewitterung auf das Expansionsverhalten, zur thermischen Schutzwirkung und zu den während des Aufschäumens im Brandfall stattfindenden Reaktionen vorgestellt. Die Versuche wurden an einem wasserbasierten und einem epoxidharzbasierten reaktiven Brandschutzsystem durchgeführt. Die Ergebnisse wurden im Rahmen des IGF-Forschungsvorhabens 20470 N erzielt.