7.4 Baustofftechnologie
Filtern
Erscheinungsjahr
- 2022 (19) (entfernen)
Dokumenttyp
- Beitrag zu einem Tagungsband (7)
- Vortrag (5)
- Zeitschriftenartikel (4)
- Beitrag zu einem Sammelband (1)
- Dissertation (1)
- Posterpräsentation (1)
Referierte Publikation
- nein (19) (entfernen)
Schlagworte
- Structural build-up (4)
- Additive manufacturing of concrete (2)
- Bingham fluid (2)
- Cement (2)
- Hydration (2)
- Modelling (2)
- Non-destructive testing (2)
- Process monitoring (2)
- Rheological properties (2)
- Superplasticizer (2)
- Abwassersysteme (1)
- Acid attack (1)
- Acid resistance (1)
- Admixture (1)
- Alkali-activated materials (1)
- Alkalisch aktivierte Bindemittel (1)
- Alkalische Aktivierung (1)
- Alternative Bindemittel (1)
- Angle of repose (1)
- BOFS (1)
- Blended cement (1)
- Bodenfilter (1)
- Brick clay (1)
- Calcined clay (1)
- Cement hydration (1)
- Compatibility (1)
- Concrete Carbonation (1)
- Concrete repair (1)
- Dauerhaftigkeit (1)
- FTIR-ATR Measurements (1)
- Flow properties (1)
- Flowability (1)
- Gel-bound Colorants (1)
- Hausner ratio (1)
- Hydraulic reactivity (1)
- Illite (1)
- Instandsetzung (1)
- Kalzinierte Tone (1)
- Kinetics (1)
- Leichte Gesteinskörnung (1)
- MIC (1)
- Mauerwerkbruch (1)
- Papierasche (1)
- Penetration test (1)
- Polyphosphate (1)
- Polysaccharides (1)
- Pore solutions (1)
- Portland Cement (1)
- Potato starch (1)
- Powders (1)
- Realkalisierung (1)
- Reparatursysteme (1)
- Rheological (1)
- Rheology (1)
- Rohstoffliches Recycling (1)
- Sekundärrohstoff (1)
- Sift-proofness (1)
- Stability (1)
- Sulfide oxidation (1)
- Superplasticizers (1)
- Texture analyzer (1)
- Thermal Gravimetric Analysis (1)
- Thixotropy (1)
- Verbund (1)
- Viscosity modifying agents (1)
- Working mechanism (1)
- XANES (1)
- Zement (1)
- Ziegelton (1)
- pH Indicator (1)
Organisationseinheit der BAM
- 7 Bauwerkssicherheit (19)
- 7.4 Baustofftechnologie (19)
- 4 Material und Umwelt (2)
- 4.4 Thermochemische Reststoffbehandlung und Wertstoffrückgewinnung (2)
- 7.7 Modellierung und Simulation (2)
- 8 Zerstörungsfreie Prüfung (2)
- 8.2 Zerstörungsfreie Prüfmethoden für das Bauwesen (2)
- 3 Gefahrgutumschließungen; Energiespeicher (1)
- 3.1 Sicherheit von Gefahrgutverpackungen und Batterien (1)
- 7.1 Baustoffe (1)
Eingeladener Vortrag
- nein (5)
Die Zementindustrie erzeugt etwa 6-7% der globalen CO2-Emissionen und steht damit als Industriezweig vor dem Hintergrund einer anvisierten Klimaneutralität vor gewaltigen Herausforderungen. Der Prozess der Klinkerherstellung wurde über die vergangenen Jahrzehnte bereits kontinuierlich optimiert. Seit 1990 ist es der deutschen Zementindustrie gelungen, die spezifischen CO2-Emissionen der Zementproduktion u. a. durch den Einsatz alternativer, nicht fossiler Brennstoffe und durch Absenkung des Klinkergehalts im Zement um 20 % zu senken. Weitere konventionelle Minderungsstrategien versprechen jedoch nur noch wenig zusätzliche Reduktion. Im Falle des Portlandklinkers besteht die Schwierigkeit darin, dass zwei Drittel der CO2-Emissionen rohstoffbedingt durch die Entsäuerung des Kalksteins (CaCO3) anfallen, die durch die beschriebenen Maßnahmen nicht weiter abgesenkt werden können. Vielmehr wird es erforderlich sein, noch zu entwickelnde oder zu optimierende Technologien anzuwenden und ggf. alle relevanten Ebenen wie Produktion, Weiterverarbeitung und Anwendung von Zement und Beton neu zu denken. Neben technologischen Ansätzen zur CO2-Abscheidung mit nachfolgender langfristiger Speicherung (Carbon Capture and Storage – CCS) oder Verwertung (Carbon Capture and Utilisation – CCU) werden auch alternative Rohstoffe für die Zementproduktion und alternative Bindemittel in Betracht zu ziehen sein.
Viscosity modifying agents: Key components of advanced cement-based materials with adapted rheology
(2022)
Viscosity modifying agents (VMAs) are essential ingredients for the production of flowable cement-based materials. This paper presents an overview of commonly used VMAs and attempts to shed some light on the underlying physics at the origin of their mechanisms of action. The main molecular parameters of VMA controlling the rheological properties of the cement pore solution are highlighted. As the mechanisms of action of VMAs in cement-based materials are closely related to their affinity with the surface of cement particles, the adsorption of the main VMA types is discussed. The effect of VMAs on flow properties and stability of cement-based materials is presented for VMAs added without any superplasticizer, and then in systems incorporating both VMAs and superplasticizers. Finally, the effect of VMAs in enhancing concrete properties to secure adequate performance of different construction applications, and perspectives for future developments of novel cement-based materials made with VMAs are showcased.
Cementitious materials are frequently applied in environments in which they are exposed to acid attack, e.g., in sewer systems, biogas plants, and agricultural/food-related industries. Alkali-activated materials (AAMs) have repeatedly been shown to exhibit a remarkably high resistance against attack by organic and inorganic acids and, thus, are promising candidates for the construction and the repair of acid-exposed structures. However, the reaction mechanisms and processes affecting the acid resistance of AAMs have just recently begun to be understood in more detail. The present contribution synthesises these advances and outlines potentially fruitful avenues of research. The interaction between AAMs and acids proceeds in a multistep process wherein different aspects of deterioration extend to different depths, complicating the overall determination of acid resistance. Partly due to this indistinct definition of the ‘depth of corrosion’, the effects of the composition of AAMs on their acid resistance cannot be unambiguously identified to date. Important parallels exist between the deterioration of low-Ca AAMs and the weathering/corrosion of minerals and glasses (dissolution-reprecipitation mechanism). Additional research requirements relate to the deterioration mechanism of high-Ca AAMs; how the character of the corroded layer influences the rate of deterioration; the effects of shrinkage and the bond between AAMs and substrates.
With increasing focus on industrialized processing, investigating, understanding, and modelling the structural build-up of cementitious materials becomes more important. The structural build-up governs the key property of fresh printable materials -- buildability -- and it influences the mechanical properties after the deposition. The structural build-up rate can be adjusted by optimization of the mixture composition and the use of concrete admixtures. Additionally, it is known, that the environmental conditions, i.e. humidity and temperature have a significant impact on the kinetic of cement hydration and the resulting hardened properties, such as shrinkage, cracking resistance etc. In this study, small amplitude oscillatory shear (SAOS) tests are applied to examine the structural build-up rate of cement paste subject to different temperatures under controlled humidity. The results indicate significant influences of the ambient temperature on the intensity of the re-flocculation (Rthix) rate, while the structuration rate (Athix) is almost not affected. A bi-linear thixotropy model extended by temperature dependent parameters coupled with a linear viscoelastic material model is proposed to simulate the mechanical behaviour considering the structural build-up during the SAOS test.
With increasing focus on industrialized processing, investigating, understanding, and modelling the structural build-up of cementitious materials becomes more important. The structural build-up governs the key property of fresh printable materials -- buildability -- and it influences the mechanical properties after the deposition. The structural build-up rate can be adjusted by optimization of the mixture composition and the use of concrete admixtures. Additionally, it is known, that the environmental conditions, i.e. humidity and temperature have a significant impact on the kinetic of cement hydration and the resulting hardened properties, such as shrinkage, cracking resistance etc. In this study, small amplitude oscillatory shear (SAOS) tests are applied to examine the structural build-up rate of cement paste subject to different temperatures under controlled humidity. The results indicate significant influences of the ambient temperature on the intensity of the re-flocculation (Rthix) rate, while the structuration rate (Athix) is almost not affected. A bi-linear thixotropy model extended by temperature dependent parameters coupled with a linear viscoelastic material model is proposed to simulate the mechanical behaviour considering the structural build-up during the SAOS test
Synopsis: Lately, there has been rising attention to superplasticizers (SP) based on polyphosphate esters. However, the influence of the molecular structure of the polyphosphate polymers on time-dependent properties such as structural build-up has not been examined yet intensively. To investigate this effect, three comb polyphosphate superplasticizers with different charge densities were synthesised by free radical polymerisation. Our findings indicate that SP with the lowest and medium charge densities extend the induction period more strongly than the SP with the highest charge density. The reduction of the structural build-up rate is linearly dependent on the dosage and concentration of the functional group of polyphosphate SP in the cementitious system. This study proposes a mathematical equation expressing the relationship between the structural build-up rate during the induction period and the molecular structure of the polyphosphate SP.
Organic admixtures are an indispensable component of modern concrete. Thus, their purposeful application is not only technically and economically viable but in addition an inevitable tool to make concrete more environmentally friendly. In this context, the use of polysaccharides has increasingly gained interest in the built environment as sustainable resource for performance enhancement. However, due to its origin, biopolymers possess a vast variety of molecular structures which can result in incompatibilities with other polymers present in concrete, such as superplasticizers. The present study highlights effects of the joint application of different types of starches and polycarboxylates with respect to their influence on cement hydration and structural build-up of cement pastes.
Für die flächige Instandsetzung von Stahlbetonkonstruktionen kommen nahezu ausschließlich zementgebundene Systeme mit hohem Zementgehalt zum Einsatz (1). Bereits 2008 war die Zementproduktion für 5% des weltweiten, anthropogenen CO2-Ausstoßes verantwortlich (2). Um die prozessbedingten CO2-Emissionen zu senken, wird der Zement bereits durch gewisse Mengen an Sekundärrohstoffen wie Flugasche, Silicastaub oder Hüttensandmehl (Hochofenschlacke) substituiert. Das Potenzial für weitere Modifikationen ist inzwischen begrenzt (3). Zudem ist eine hohe Lebensdauer der Konstruktionen in vielen Anwendungsbereichen nur bedingt realisierbar. Spätestens mit Erreichen der geplanten Nutzungsdauer müssen Stahlbetonkonstruktionen mit zementgebundenen Systemen instandgesetzt werden, was im ökonomischen und ökologischen Sinne keine nachhaltige Lösung darstellt. Die Verwendung neuer Baustoffe wie alkalisch aktivierte Mörtel hält sich bisher in Grenzen (4), sodass die Akzeptanz durch praxisnahe Forschung adressiert werden muss.
Vorangegangene Forschungsergebnisse zeigen, dass alkalisch aktivierte Bindemittel vielversprechende technische Eigenschaften besitzen. So zeigen sich im Vergleich zu herkömmlichem Portlandzement ein ausgesprochen wirkungsvoller Verbund zu Stahl und Zementmörtel (5), (6), eine hohe chemische Beständigkeit sowie ein Erfolg versprechendes Abwitterungsverhalten bei Frost-Tau-Wechseln (7). Mit diesen Eigenschaften können alkalisch aktivierte Mörtel einen erheblichen Beitrag zur dauerhaften Betoninstandsetzung leisten und somit durch die verringerten CO2-Emmissionen dem Prinzip des nachhaltigen Bauens gerecht werden. Wichtig für die Produktion im größeren Maßstab ist die Verfügbarkeit der möglichen Reststoffe, um eine CO2-positivere Bilanz abzubilden.
Im Zuge des Forschungsvorhabens sollen Rezepturen für Instandsetzungsprodukte entworfen werden, die auf alkalisch aktivierte industrielle Reststoffe zurückgreifen und die Anforderungen an konventionelle Instandsetzungsprodukte erfüllen. Hierzu wurden potenzielle Ausgangs-stoffe mit Natriumcarbonat aktiviert und die Verarbeitbarkeit der Leime sowie die Druckfestigkeiten nach sieben Tagen verglichen. Hüttensandmehl reagiert ausreichend mit diesem Aktivator, was sich mit Ergebnissen von (8) und (9) deckt. Es werden 〖CO〗_3^(2-)-Ionen in das System eingebaut, was zu einer anfänglichen Erstarrung des Gefüges durch die Bildung von Carbonaten (Calcit und Hydrotalcit) führt. Nach einer längeren dormanten Phase bilden sich zusätzlich Hydratphasen, die die Festigkeit weiter erhöhen. Weiterhin ist die chemische Zusammensetzung der Schlacken für die Erhärtung und die späteren Eigenschaften von großer Bedeutung (10), (11), was mit einer Parameterstudie im laufenden Jahr an natriumcarbonataktivierten Schlacken näher betrachtet werden soll. Erkenntnisse aus vergleichenden Versuchen durch (12) bestätigen die Einflussnahme der chemischen Zusammensetzung. Die übrigen Reststoffe konnten mit anderen Aktivatoren (z. B. Natriumsilicat und -hydroxid) zu einer Reaktion angeregt werden. Im Hinblick auf die Akzeptanz der alkalisch aktivierten Bindemittel stellen diese Aktivatoren jedoch bei der Herstellung höhere technische Anforderungen an das Personal und die verwendeten Geräte im Vergleich zur konventionellen Beton- und Mörteltechnik. Die Aktivierung mittels Alkalicarbonaten ermöglicht die Herstellung von Beton bzw. Mörtel nach dem üblichen „just add water“-Prinzip (13).
Aktuell wird unter Einbindung einer studentischen Abschlussarbeit eine Rezeptur mit Hüttensandmehl hinsichtlich der Frisch- und Festeigenschaften charakterisiert und einer Referenzmischung – basierend auf Portlandzement – gegenübergestellt. Hieraus resultierende Ergebnisse sollen neben den Erkenntnissen aus den Vorversuchen zur Konferenz vorgestellt und ein Ausblick auf die weitere Forschungsarbeit gegeben werden.
The oxidation of sulfur in aqueous solutions is an important process in several geochemical and industrial contexts. In concrete technology, it is particularly relevant for the protection of steel reinforcement in slag cement-based concretes, as the presence of sulfides affects the passivation of the steel and corrosion initiation in the presence of chlorides. However, the knowledge about the kinetics of sulfide oxidation in alkaline solutions, such as concrete pore solutions, is incomplete. To address this issue, we prepared solutions with 0.80 M NaOH, and nominally 10, 100 and 350 mM HS−, respectively, and followed the evolution of the sulfur species during bubbling with oxygen-containing gas (concentration 100% or 22%) using X-ray absorption near-edge structure (XANES) spectroscopy at the sulfur K-edge. Polysulfide, thiosulfate, sulfite and sulfate were identified and quantified via linear combination fitting of the spectra, using previously measured standards. A preliminary analysis of the results shows that the initial rate constant of sulfide oxidation depends strongly on the HS− concentration, while it less strongly depending on the oxygen concentration, in line with previous results for lower pH values. Approaches to fit the data to obtain the rate constants of all relevant reactions will be discussed.
Calcined clays as supplementary cementitious materials (SCMs) have been identified and credited to be a viable solution in mitigating the CO2 emissions related to cement production and consumption. Calcined clays range from a variety of different clay types based on an assortment of varying minerals and compositions. While extensive data is available on kaolinitic clays (based on the 1:1 clay type), other clays such as brick clays (based on the 2:1 clay type) are currently understudied, although such clays are largely more available than the kaolinitic clays.
The aim of this thesis is to draw attention to the varying compositions present in two selected brick clays in Germany and elaborate on how such compositions affect their suitability to be used as SCMs in blended cement systems. The novelty of this thesis explains the relationship between the reactivity of the bricks to their varying compositions and their suitability for their employment as SCMs. This was based on their chemical and physical transformations in the calcination temperature range 650–900 or 950 °C, and the performance of the calcined brick clays in blended cement systems measured by their heat evolution, strength development and durability-related properties. The results of their performance were compared to two kaolinitic clays with varying compositions. While the kaolinitic clays generally exhibited the best performance as SCMs, the brick clay with a lower Fe2O3 content showed promising results similar to the kaolinitic clays when an optimum calcination temperature is applied and when substituted at a moderate cement substitution rate. Thus, this finding promoted further efforts made to improve the reactivity of the brick clay by producing a mixed clay composed of 50 % brick clay (with lower Fe2O3 content) and 50 % kaolinitic clay. The mixed clay was compared to the two individual brick clays and one kaolinitic clay, whereby optimum calcination conditions were performed in large-scale simulating an industrial-scale production of SCMs. All calcined clays exhibited pozzolanic reactivity, with the performance of the brick clays inferior to the kaolinitic clay, however, the mixed clay performed very similar to the kaolinitic clay.
At a similar degree of hydration compared to plain Portland cement, the good performance of the mixed clays was especially evident in the strength development and improved chloride penetration resistance, which was caused by a refinement in the pore structure in the cementitious systems. Moreover, it was deduced that not only the high surface area, but also, the solubility of Si and Al ions in the resulting calcinate of the mixed clays plays a significant role when calcined at ~600–700 °C, which points to viable options for optimal employment of brick clays in cementitious systems.