7.4 Baustofftechnologie
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Paper des Monats
- ja (12)
The early hydration of calcium sulfoaluminate (CSA) cement in water (CSAH) and in 2 M sodium hydroxide (CSA2M), both with a liquid/solids ratio of 0.5, was investigated. Hydration kinetics were assessed using in situ X-ray diffraction, isothermal conduction calorimetry, ultrasonic pulse velocity (UPV) and mechanical strength measurements. The maximum heat release occurred earlier in the CSA2M system and UPV measurements revealed a more rapid increase in mechanical stiffness. The presence of alkalis accelerated the dissolution of ye’elimite and anhydrite, leading to a shorter induction period and faster precipitation of ettringite. The phase refinement confirmed a higher dissolution rate of anhydrite in the alkaline environment, while the formation of ettringite stabilised within 10 h. At age 25 h, the ettringite content was 58.3% in CSAH and 48.2% in CSA2M. This finding confirms that the UPV measurements provided a reliable indication of the onset of setting and early structural development in CSA cements and contribute to a deeper understanding of the early hydration mechanisms of CSA cements and the impact of alkalis on phase evolution.
The Influence of Biochar on the Flow Properties, Early Hydration, and Strength Evolution of Paste
(2023)
In order to reduce the carbon footprint, biochar can be used as CO2 negative concrete constituent.The paper shows results of experiments with cement paste and mortar mixtures with 5%, 15% and 30% of cement volume replaced by biochar. The density of the char is measured with a pycnometer I dried and wet conditions, workability is assessed using a spread flow test, and hydration characteristics are measured using isothermal heat flow calorimetry. In addition strength results are presented. The results show that char does not interfere with the cement hydration at early ages, but the water entrapped in the particles can have a slight retarding effect. In general workability and strength were negatively affected by the presence of biochar. However, small amounts of biochar can even have a positive effect on strength without negatively affecting the other properties of the material. The fact that at dosages above 5% the performance specifications of paste and mortar deteriorated has a detrimental effect on the use of biochar as carbon sink in structural concrete.
EDGE Sustainability Benchmarking for Construction: The relevance of concrete building materials
(2023)
With growing concern about the impacts of climate change on the environment, benchmarking and certifying sustainable development is becoming more important. Benchmarking construction projects is the process of quantifying the impacts of a project and comparing them to a baseline or standard. Certifications schemes for sustainable benchmarking are typically awarded when a project reduced impacts to specified point below a baseline or demonstrates a specific amount of impact mitigations in the project.
Chemical admixtures are an integral component of modern concrete and enable the careful tailoring of fresh and hardening properties. Herein we investigate candidate materials from the bioeconomy in idealized system and discuss the methodology as a possible rapid evaluation technique to categories the role of the candidate biopolymers at selected dosages.
To rapidly reduce the environmental impacts from building materials, carbon-storing biochars have been proposed as a means of capturing and storing CO2 in cement-based materials. Herein we investigate the implications of various replacement rates of biochar and applications of chemical admixtures in cement-based materials. Notably, the complex microstructure of the biochar itself drives dynamic interactions between moisture content and density, thus complicating possible applications.
With growing environmental impacts over the construction of and lifetime of built infrastructure, tools are needed to guide emissions reduction strategies. Herein, the EDGE Application by the International Finance Corporation (IFC) is investigated via case studies to understand hidden assumptions in the system and potential gaps in early efforts such as the EDGE tool. This work highlight questions around how baselines are selected, what are appropriate and feasible mitigation strategies, and if the quantified impacts lead to meaningful improvement.
Industrial sectors, especially those with significant global CO2 emissions like the cement and concrete industries, are striving to achieve net-zero emissions by 2050. It is anticipated that carbon dioxide removal will be required to meet these goals. Hydrated cement in concrete can react with atmospheric CO2 to form carbonate minerals (i.e. carbonation), and in doing so, act as a carbon uptake mechanism. This carbonation process can be accelerated via various engineering interventions, such as crushing concrete after demolition. In this literature review, we examine key parameters, including porosity, exposure conditions, CO2 concentration, curing methods, coatings, and the use of supplementary cementitious materials, that affect CO2 uptake in concrete to inform better quantification of life cycle emissions. These findings can inform the feasibility of implementing carbonation as a method for reducing emissions from cement-based materials and identify data limitations that need further study for future modeling efforts. Presently, it has been estimated that 9%–17% of concrete production emissions could be re-adsorbed during use and end of life. However, such estimates of uptake have only considered limited data sets, without fully addressing the comingled effects of the parameters impacting carbonation. Further, some carbon uptake modeling efforts may require input values that are not readily available, or may be challenging to repeat, and do not accurately account for carbon fluxes over the life cycle. Findings from this review highlight the importance of development of systematic approaches to assess cradle-to-grave life cycle assessments using dynamic carbon accounting when measuring concrete carbonation.
As future populations are projected to boom, cement and concrete consumption in Africa is expected to explode. With increasing interest in the socio-economic development of this region tied to recent investment in production capacity by development banks, we investigate the current state of production, consumption and the related environmental impacts for cement in Africa. Trade and production statistics are used to map the source of production and understand regional material fluxes. A harmonized environmental impact model is assembled that represents the technology and energy sources of each area to model the production emissions from each unit of material. Herein, greenhouse gas (GHG) emissions as well as water demands, water consumption, particulate matter, and other notable air pollutants are modeled to provide information on climate related impacts as well as those directly related to human health. Median 2022 import reliance by country or area was ~37% with 15 areas fully reliant on imports. While GHG-related impacts are similar, there were shifts in particulate matter and water related impacts between imported and domestically produced materials. Together this model enables the exploration of potential impact shifting and raises important question about material sovereignty and the ability for local areas to regulate the embodied environmental impacts of the building material that are critical to future socio-economic development in their regions.
To compensate for the CO2-intensive cement production, ways must be found to (i) actively remove CO2 from the atmosphere, (ii) capture and sequester CO2 from production emissions, and (iii) develop novel, ideally waste-based SCMs to reduce clinker content. This study presents an approach to create a new generation of reactive, CO2-negative SCMs (BC-SCMs, BC = biochar) generated by coupling biomass pyrolysis and clay calcination. The starting materials used for producing the BC-SCMs are microalgal biomass, which allows the capture of CO2 from air or flue gases, textile wastes (cotton), wood (spruce) and clay. The carbon embodied in the algae, textile waste and wood can be largely bound by pyrolysis. Simultaneously, the resulting BC-SCMs exhibited pozzolanic reactivity by calcining the clay fraction. The results of the R3 reactivity test [1] indicate that for co-pyrolyzed clay + cotton and clay + wood, the total released heat increased from 53.4 J/g to 458.3 J/g and 33.1 J/g to 443.3 J/g, respectively, compared to corresponding pyrolyzed single fraction. A 10 wt.% co-pyrolyzed clay + algae blended in CEM I showed an 8% increase in compressive strength after 7 days compared to the reference sample using CEM I. Thus, the presented approach highlights a pathway towards a more resource-efficient, waste-preventing, and climate-friendly circular economy by the long-term stabilization of carbon in reactive biochar-binder composites.
3DCP introduces monitoring demands absent in cast concrete: the material is simultaneously being deposited, self-loading, and hardening, with failure modes — collapse, inter-filament cracking, interfacial voids — that are invisible to any external sensor. This presentation reported preliminary results from an embedded PZT sensor system addressing this gap through two complementary modalities operating from the same array.
The electromechanical impedance (EI) modality tracks local elastic property development through resonance frequency shift and conductance decrease. Paste-level validation across four mix designs (w/c = 0.32, 0.36, 0.40, and 0.36 + 0.5% NaP retarder) demonstrated sub-10-minute sensitivity to early hydration and a clear quantitative correlation between normalised conductance decrease and independently measured shear modulus. In full printed beam specimens (68 × 30 × 17 cm), three embedded sensors tracked EI evolution through 700 hours, corroborated by thermal kinetics, Vicat set behaviour, and external wave velocity measurements.
The wave propagation modality used the same array in actuator-receiver configuration to measure time-of-flight and signal energy between sensor pairs. A key finding was directional asymmetry: longitudinal pairs stiffened faster than the transverse pair crossing the inter-layer interface, providing direct in-situ evidence of deposition-induced mechanical anisotropy. Energy inflection points at approximately 100–200 hours were interpreted as the transition from stiffening-dominated to damage-dominated regimes, consistent with post-hardening XCT observations of drying shrinkage cracking along inter-filament contacts.
The presentation closed with an honest challenge: even with a functioning sensor system, four embedded sensors cover less than 1% of the element's information field. The sensing density problem was posed as an open question to the committee, framing it not as an instrumentation failure but as a geometric inevitability of the sequential deposition process demanding new thinking on distributed sensing architectures.