7 Bauwerkssicherheit
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Diese Hinweisbroschüre erläutert allgemeine Planungsvoraussetzungen und Dimensionierungsregelungen, Baugrundsätze und Zulassungsbedingungen zur Anwendung innovativer Belagsdehnfugensysteme (Fahrbahnübergangskonstruktionen) in hochbeanspruchten Verkehrsflächen des Bundesfernstraßenbereiches. Alle planungsrelevanten, baustoffrelevanten, versuchstechnische, qualitätssichernden und baupraktischen Aspekte werden zur Unterstützung der Straßenbauverwaltungen, der Lieferfirmen und Ausführungsbetriebe erläutert. Die Veröffentlichung stellt eine technische Analyse aus Erfahrungssammlungen und Auswertung praktischer Erkenntnisse dar.
Beton ist weltweit einer der wichtigsten Konstruktionswerkstoffe und zeichnet sich durch eine enorme Anpassungsfähigkeit an sich verändernde Anforderungen aus. Damit verbunden ist eine hohe und kontinuierlich zunehmende Komplexität hinsichtlich der Ausgangsstoffe, Rezepturen und des Herstellungsprozesses. Folglich setzt eine Ausschöpfung des technischen und umweltbezogenen Potenzials der Betonbauweise höchste Expertise bei den Einzelakteuren der Bauindustrie voraus.
Der Beitrag berichtet von einer aufwändigen Messkampagne vor Ort, mit der die Emissionen direkt an einer Rohzementmühle, die Transmissionen im Baugrund und die Immissionen in benachbarten Bebauungen genauer untersucht wurden. Im Ergebnis der ausgewerteten Messungen sowie strukturdynamischer Berechnungen zeigte sich, dass der Baugrund zwar aus statischer Sicht sehr gut tragfähig, aber dynamisch als eher ungünstig zu beurteilen ist. Weiterhin wurde festgestellt, dass in dynamischer Hinsicht ein vorgenommener Bodenaustausch tendenziell eine Verschlechterung der Aufstellbedingungen darstellte. Für das betroffene Bürogebäude konnte nachgewiesen werden, dass durch den Betrieb der Zementmühle die Anregung der Deckeneigenfrequenzen zu deutlich spürbaren Resonanzschwingungen führte. Aufgrund der tieffrequenten Anregung durch den Mühlenbetrieb sind Maßnahmen zur Minderung der Schwingungsemissionen generell und insbesondere nach erfolgter Aufstellung der Mühle schwer bzw. gar nicht zu realisieren. Im Beitrag wird daher darauf eingegangen, auf welche Aspekte bei der Planung zur Aufstellung derart großer Mühlen zwingend zu achten ist.
Viscosity modifying agents: Key components of advanced cement-based materials with adapted rheology
(2022)
Viscosity modifying agents (VMAs) are essential ingredients for the production of flowable cement-based materials. This paper presents an overview of commonly used VMAs and attempts to shed some light on the underlying physics at the origin of their mechanisms of action. The main molecular parameters of VMA controlling the rheological properties of the cement pore solution are highlighted. As the mechanisms of action of VMAs in cement-based materials are closely related to their affinity with the surface of cement particles, the adsorption of the main VMA types is discussed. The effect of VMAs on flow properties and stability of cement-based materials is presented for VMAs added without any superplasticizer, and then in systems incorporating both VMAs and superplasticizers. Finally, the effect of VMAs in enhancing concrete properties to secure adequate performance of different construction applications, and perspectives for future developments of novel cement-based materials made with VMAs are showcased.
Synopsis: The paper presents the results of a study on the influence of agitation on the structural build-up of fresh cement pastes using a penetration test. It first presents results about the influence of the penetrating shape’s geometry on the influence on the cement paste specimen. Then, results are shown for the load-deflection curves depending upon time and agitation before testing. Based on the observation of the force required to penetrate the sample, conclusions on the structural build-up can be made. The observations were made over the course of time with samples that were left at rest and partly agitated before testing at different time steps. The setup allows to identify the contribution of the chemical reaction to the structural build-up process. The presence of superplasticizer obviously reduces the load that cement paste can withstand, while the loss of thixotropy is found notably lower than that of neat cement pates
Synopsis: Lately, there has been rising attention to superplasticizers (SP) based on polyphosphate esters. However, the influence of the molecular structure of the polyphosphate polymers on time-dependent properties such as structural build-up has not been examined yet intensively. To investigate this effect, three comb polyphosphate superplasticizers with different charge densities were synthesised by free radical polymerisation. Our findings indicate that SP with the lowest and medium charge densities extend the induction period more strongly than the SP with the highest charge density. The reduction of the structural build-up rate is linearly dependent on the dosage and concentration of the functional group of polyphosphate SP in the cementitious system. This study proposes a mathematical equation expressing the relationship between the structural build-up rate during the induction period and the molecular structure of the polyphosphate SP.
Influence of the hydroxypropylation of starch on its performance as viscosity modifying agent
(2022)
Synopsis: Starch is a commonly used viscosity modifying agent (VMA). The performance of starch as VMA depends on its origin (e.g. potato, corn, cassava, etc.) and corresponding molecular properties, such as molecular weight, ratio between amylose and amylopectin etc. Depending upon the application, the efficiency of starch can be enhanced by hydroxypropylation. The maximum degree of substitution (DoS) cannot be greater than 3.0, which is the number of hydroxy groups per glucose monomer in the polymer. In the current research three potato starches exhibiting the DoS of 0.4, 0.6 and 0.8 were utilised. The influence of the modified starch on the rheological properties and hydration of cement paste, as well as the viscosity of the pore solution were investigated. Our findings show that the starch with the highest DoS increases the dynamic yield stress the most, while the plastic viscosity is less dependent on the DoS. Additionally, starch with the highest DoS retards hydration to lower degree than other starches.
Organic admixtures are an indispensable component of modern concrete. Thus, their purposeful application is not only technically and economically viable but in addition an inevitable tool to make concrete more environmentally friendly. In this context, the use of polysaccharides has increasingly gained interest in the built environment as sustainable resource for performance enhancement. However, due to its origin, biopolymers possess a vast variety of molecular structures which can result in incompatibilities with other polymers present in concrete, such as superplasticizers. The present study highlights effects of the joint application of different types of starches and polycarboxylates with respect to their influence on cement hydration and structural build-up of cement pastes.
The current paper develops a novel accelerated corrosion test method based on Faraday’s law to investigate the performance of different inhibitors in reinforced concrete elements under electrical voltage. Using the proposed method two commercially available and three lab-made inhibitors were tested. Lab-made inhibitors based on potassium fluorosilicate and amine carboxylate showed the best performance over others. Furthermore, it is found that under an electrical potential environment beyond 3.6 V, the higher the concrete strength, the more efficient is the corrosion inhibition. Based on experimental results, a novel model describing the corrosion evolution in reinforced concrete was proposed.