4 Material und Umwelt
Filtern
Dokumenttyp
- Vortrag (443)
- Posterpräsentation (146)
- Beitrag zu einem Tagungsband (77)
- Zeitschriftenartikel (65)
- Buchkapitel (35)
- Zeitschriftenheft (Herausgeberschaft für das komplette Heft) (18)
- Forschungsbericht (17)
- Amtliche Bekanntmachung (13)
- Sonstiges (8)
- Dissertation (7)
Sprache
- Englisch (542)
- Deutsch (298)
- Spanisch (4)
- Französisch (2)
- Chinesisch (2)
- Italienisch (1)
Referierte Publikation
- nein (849) (entfernen)
Schlagworte
- Biocides (40)
- Deponie (32)
- Antimicrobial resistance (28)
- Nano (28)
- Recycling (28)
- Ink (25)
- MIC (22)
- Corrosion (21)
- Phosphor (21)
- Rostasche (20)
- Biofilms (19)
- Klärschlamm (19)
- OECD (19)
- XRF (19)
- Kunststoffdichtungsbahn (17)
- Archaeometry (16)
- Bacteria (16)
- Leaching (16)
- VOC (16)
- Zulassungen (16)
- Anerkennungen (15)
- Evolution (15)
- PFAS (15)
- Richtlinien (15)
- Bauprodukte (14)
- Per- and Polyfluoroalkyl substances (PFAS) (14)
- Phosphorrückgewinnung (14)
- Biofilm (13)
- Methanogens (13)
- Nanomaterial (13)
- Zulassung (13)
- Festlegungen (12)
- Inks (12)
- Emission (11)
- Fungus (11)
- Geokunststoffe (11)
- Manuscripts (11)
- Microbiologically influenced corrosion (11)
- Biocide (10)
- E. coli (10)
- Phosphorus recovery (10)
- Raman spectroscopy (10)
- Zerstörungsfreie Prüfung (10)
- Antimicrobial coating (9)
- Archäometrie (9)
- Klärschlammverordnung (9)
- Manuscript (9)
- Microbiology (9)
- Prüfrichtlinie (9)
- Resistance (9)
- Archaea (8)
- Bottom ash (8)
- CFK (8)
- Disinfection (8)
- Genetics (8)
- Humboldt Codices (8)
- NAP-XPS (8)
- Non-destructive testing (8)
- Papier (8)
- Persistence (8)
- Risk assessment (8)
- Sewage sludge (8)
- Standardization (8)
- Aerosol (7)
- Cascade impactor (7)
- Gichtgasschlamm (7)
- Holzschutz (7)
- Horizontal gene transfer HGT (7)
- Nanopartikel (7)
- PAK (7)
- Resistance evolution (7)
- Reverse glass painting (7)
- Soil (7)
- Tolerance (7)
- Umweltsimulation (7)
- XANES spectroscopy (7)
- BBodSchV (6)
- BEMMA (6)
- Black fungi (6)
- Coptic (6)
- Düngemittel (6)
- EN 16516 (6)
- Ersatzbaustoffe (6)
- Geogitter (6)
- Geruch (6)
- Glutaraldehyde (6)
- Hydraulic reactivity (6)
- Knufia petricola (6)
- Korrosion (6)
- Melanin (6)
- Mikroplastik (6)
- Museum (6)
- Phosphorus (6)
- Pyrometallurgy (6)
- Ringversuch (6)
- Termite (6)
- Weathering (6)
- Zeichenmaterialien (6)
- Alginate (5)
- Analytik (5)
- Anobium punctatum (5)
- Antibiotics (5)
- BOFS (5)
- Biocide tolerance (5)
- Biozide (5)
- Combustion Ion Chromatography (5)
- Combustion ion chromatography (5)
- Construction products (5)
- Cultural heritage (5)
- DRIFTS (5)
- Dead Sea Scrolls (5)
- Elektroofenstaub (5)
- Environmental Simulation (5)
- Environmental evaluation (5)
- Ground water (5)
- Heterogeneity (5)
- ISO 16000-6 (5)
- Indoor air quality (5)
- Ink analyses (5)
- Iron-gall ink (5)
- Klärschlammasche (5)
- Kunststoffdichtungsbahnen (5)
- Laser-induced periodic surface structures (LIPSS) (5)
- Lichtbogenofen (5)
- Lysimeter (5)
- Parchment (5)
- Pigments (5)
- Portland Cement (5)
- Pyrometallurgie (5)
- Reference material (5)
- Reflectography (5)
- Remediation (5)
- Ressourcenrückgewinnung (5)
- Sekundärrohstoffe (5)
- Single cell analysis (5)
- TXRF (5)
- Tantal (5)
- Termites (5)
- Test guideline (5)
- VVOCs (5)
- Verwertung (5)
- Volatile organic compounds (5)
- Wastewater (5)
- Zement (5)
- ZfP (5)
- Zink (5)
- ATR (4)
- Alite (4)
- Analytical method (4)
- Antimony (4)
- Ausnahmegenehmigungen (4)
- Bacterial adhesion (4)
- Bodenmaterial (4)
- Bundesoberbehörden (4)
- Cabonfasern (4)
- Carbon Fibers (4)
- Corrosion products (4)
- Cross-resistance (4)
- Dünger (4)
- ESEM (4)
- Ecotoxicity (4)
- Emission reference materials (4)
- Emissionen (4)
- Fertilizer (4)
- Gefahrgutregeln (4)
- Geosynthetics (4)
- Guideline (4)
- Gypsum (4)
- Hi-Tension (4)
- Horizontal gene transfer (4)
- Kreislaufwirtschaft (4)
- Kulturgut (4)
- LD-Schlacke (4)
- Light (4)
- Makronährstoffe (4)
- Middle Ages (4)
- Mutation rate (4)
- Nanomaterials (4)
- Nanoparticle (4)
- Nassaufbereitung (4)
- Nitrogen (4)
- Non-invasive analysis (4)
- Nährstoffe (4)
- Olivine (4)
- Papyrus (4)
- Phosphat (4)
- Pigment (4)
- Sc-ICP-ToF-MS (4)
- Scandium (4)
- Spannungsrissbeständigkeit (4)
- Spectroscopy (4)
- Stahlwerksschlacke (4)
- Steelmaking slag (4)
- Tantalum (4)
- Transformation (4)
- UFP (4)
- VOC-emission (4)
- X-ray absorption near-edge structure (XANES) spectroscopy (4)
- XANES (4)
- XPS (4)
- Zinc (4)
- Ökotoxizität (4)
- Abfallverbrennung (3)
- Aluminium (3)
- Anoxia (3)
- Antimicrobial surfaces (3)
- Antimicrobials (3)
- Antimikrobielle Resistenz (3)
- Antmikrobielle Oberflächen (3)
- Architecture (3)
- Baustoffrecycling (3)
- Beschleunigte Alterung (3)
- Biofilm formation (3)
- Black fungus (3)
- Blast furnace sludge (3)
- CDW processing (3)
- CIC (3)
- Cairo Genizah (3)
- Carbon steel (3)
- Carbonfaser (3)
- Chamber test (3)
- Chemical durability (3)
- DGT (3)
- DHN melanin (3)
- DIN (3)
- Dichtungskontrollsysteme (3)
- Diffusive Gradients in thin films (DGT) (3)
- EOF (3)
- Ectoine (3)
- Electric Arc Furnace (3)
- Electric arc furnace dust (3)
- Emission reference material (3)
- Emissions (3)
- Environmental simulation (3)
- Ersatzbaustoff (3)
- Extremotolerance (3)
- FFF-3D-Printer (3)
- FIB/SEM (3)
- Fertilzer (3)
- Flow Model (3)
- Formaldehyd (3)
- Fungi (3)
- Geotextilien (3)
- Glass (3)
- Gypsum recycling (3)
- HP14 (3)
- Herculaneum (3)
- Immune gene family (3)
- Immunity (3)
- Ink analysis (3)
- LIPSS (3)
- Landwirtschaft (3)
- Laser-induced breakdown spectroscopy (3)
- Leichtbau (3)
- Low melting (3)
- Luftschadstoffe (3)
- Mantelverordnung (3)
- Manuscript studies (3)
- Material science (3)
- Materials emissions test (3)
- Mechanochemical treatment (3)
- Methanogen (3)
- Methanogen-induced microbiologically influenced corrosion (3)
- Mikrobiell beeinflusste Korrosion (3)
- Modelling (3)
- Nanoparticles (3)
- Non destructive analytical techniques (3)
- Normung (3)
- Odour (3)
- PFC (3)
- Passive sampling (3)
- Perceived Intensity (3)
- Persian manuscripts (3)
- Phenotypic diversity (3)
- Polymere (3)
- Quality assurance (3)
- Raman Spectroscopy (3)
- Recycling materials (3)
- Red Mud (3)
- Reference materials (3)
- Robustness studies (3)
- Rock-inhabiting fungus (3)
- Rotschlamm (3)
- Round robin test (3)
- SC-ICP-ToF-MS (3)
- Schadstofftransfer (3)
- Schutzschicht (3)
- Size (3)
- Sorption (3)
- Standardisierung (3)
- Steelmaking (3)
- Sulfate reducing bacteria (3)
- TED-GC/MS (3)
- Thermochemisch (3)
- Ultrafine particles (3)
- Virus (3)
- Wood protection (3)
- XRF analysis (3)
- 3D printing (2)
- Abdichtungssystem (2)
- AbfKlärV (2)
- Abfallbehandlung (2)
- Abwasser (2)
- Abwasserbehandlung (2)
- Additive Fertigung (2)
- Additive Manufacturing (AM) (2)
- Aerosol measurements (2)
- Aerosole (2)
- Affinity chromatography (2)
- Agronomische Effizienz (2)
- Air exchange rate (2)
- Air quality monitoring (2)
- Alkalien (2)
- Anpassung (2)
- Antibiotic resisitance (2)
- Antibodies (2)
- Antimicrobial (2)
- Antimon (2)
- Antiquity (2)
- Apanteles carpatus (2)
- Arabic Recipes (2)
- Ashdec (2)
- Bacterial adhesion tests (2)
- Bagasse (2)
- Baryscapus tineivorus (2)
- Bauxite Residue (2)
- Behördenklausurtagung (2)
- Bewehrungen aus Kunststoff (2)
- Bewitterung (2)
- Bio-weathering (2)
- Biocorrosion (2)
- Biodiversity (2)
- Biofilm growth (2)
- Biologische Schädlingsbekämpfung (2)
- Biotechnology (2)
- Biozid (2)
- Blauer Engel (2)
- Böden (2)
- CEN (2)
- CO2 assisted impregnation (2)
- CSMC (2)
- Capsules (2)
- Carbide formation (2)
- Carbon feeding (2)
- Carbon ink (2)
- Carbon steel corrosion (2)
- Carbonfasern (2)
- Chemical analysis (2)
- Chemical characterization (2)
- Chinese paper (2)
- Chromium (2)
- Circular Economy (2)
- Circular economy (2)
- Clinker substitute (2)
- Construction Products (2)
- Corona (2)
- Corrosion evolution (2)
- Corynetes caeruleus (2)
- DSLT (2)
- Deponien (2)
- Deponietechnik (2)
- Desinfectant (2)
- Dichtungskontrollsystem (2)
- Diffusive gradients in thin-films (DGT) (2)
- Diffusive sampling (2)
- Disinfectants (2)
- Disposal repository (2)
- Drawings (2)
- Dyes (2)
- E.coli (2)
- Electron microscopy (2)
- Elektronisches Laborbuch (2)
- Element mass concentration (2)
- Elutionsverfahren (2)
- Elutionsverhalten (2)
- Emerging (2)
- Emission test chamber (2)
- Emission testing (2)
- Emissionskammer (2)
- Environmental condition (2)
- Ersatzbaustoffverordnung (2)
- European standard (2)
- Eusociality (2)
- FEM model (2)
- FTIR (2)
- Farbmittel (2)
- Filterstaub (2)
- Fluorescence (2)
- Fume (2)
- Fungal biofilms (2)
- GAeF (2)
- Genetic engineering (2)
- Genomics (2)
- Geruchsmessung (2)
- Glasmalfarben (2)
- Groundwater (2)
- Group defence (2)
- Größenbestimmung (2)
- Gypsum fiberboards and synthetic gypsum (2)
- HAXPES (2)
- HDPE geomembrane (2)
- HI-Tension (2)
- Halomonas CRISPR Ectoine (2)
- Hydrogen (2)
- IAQ (2)
- ICP-MS (2)
- IPM (2)
- ISO (2)
- In-situ analysis (2)
- Ink composition (2)
- Inkwells (2)
- Innenraum (2)
- Interdisciplinary (2)
- Interdisciplinary approach (2)
- Ir DNA staining approach (2)
- Iron (2)
- Iron oxide nanoparticles (2)
- Knufia (2)
- Korynetes caeruleus (2)
- Kunststoffrasen (2)
- Kunststoffschweißen (2)
- LA-ICP-MS (2)
- Landfill liner (2)
- Lapis lazuli (2)
- Laser Powder Bed Fusion (L-PBF) (2)
- Leaching of waste materials (2)
- Leak detection (2)
- Leather (2)
- Leonardo da Vinci (2)
- Loading factor (2)
- Luft (2)
- Manuskripte (2)
- Material emissions (2)
- Metabolism (2)
- Method development (2)
- Micro plastic (2)
- Micro-XRF (2)
- Microbial (2)
- Microbiological influenced corrosion MIC (2)
- Microbiome (2)
- Microcolonial fungi (2)
- Microorganism (2)
- Microplastics (2)
- Mikroorganismen (2)
- Mixed ink (2)
- Modelling studies (2)
- Monoverbrennung (2)
- Monoverbrennungsanlage (2)
- Museum Pests (2)
- Nano particle (2)
- NanoSIMS (2)
- Nanofasern (2)
- Nanomaterialien (2)
- Non invasive analysis (2)
- Non-destructiv testing (2)
- Nuclear waste (2)
- Optics (2)
- P-Recyclingdünger (2)
- PGAA (2)
- PIXE (2)
- Particle gas emission (2)
- Particle size (2)
- Particle size distribution (2)
- Particle size distributuion (2)
- Particles (2)
- Particulate emission (2)
- Partikel (2)
- Pathogen (2)
- Perceived intensity (2)
- Permeable reactive barriers (2)
- Persister cells (2)
- Phopshorus recovery (2)
- Pigment analyses (2)
- Plume (2)
- Pollutants (2)
- Polyglycerol (2)
- Provenance studies (2)
- Prozessmonitoring (2)
- RFA (2)
- Raman (2)
- Recovery (2)
- Recycling fertiliser (2)
- Recycling fertilisers (2)
- Reduction process (2)
- Reductive amination (2)
- Regulations (2)
- Rembrandt (2)
- Reproduzierbarkeit (2)
- Risk assesment (2)
- SCALE (2)
- Sanierung (2)
- Schadstoffaustrag (2)
- Schimmel (2)
- Schutzschichten (2)
- Secondary Recources (2)
- Secondary building materials (2)
- Selective chlorination (2)
- Sequenzielle Extraktion (2)
- Sewage sludge ash (2)
- Sewage sludge ordinance (2)
- Simulation (2)
- Single cell (2)
- Size distribution (2)
- Soil P species (2)
- Solar panel (2)
- Solubility (2)
- Spatter (2)
- Standardisation (2)
- Stress (2)
- Stress tolerance (2)
- Struvit (2)
- Sum parameter analysis (2)
- Sustainability (2)
- Synchrotron (2)
- Termite phylogeny (2)
- Test Guideline (2)
- Testguideline (2)
- Thermal extraction (2)
- Tineola bisselliella (2)
- Total reflection X-ray spectroscopy (2)
- Tricalcium-silicate (2)
- Tricalciumsilikat (2)
- UV radiation (2)
- Umwelt (2)
- Uptake rate (2)
- VIS (2)
- VOC Emissionen (2)
- VOC-Emission (2)
- VOC-Emissionen (2)
- Vitrinen (2)
- Wasserzeichen (2)
- Waste management (2)
- Waste treatment (2)
- Writing inks (2)
- X-Ray fluorescence analyses (2)
- Zeichnungen (2)
- Zementersatz (2)
- Zementklinker (2)
- Zinnschlacke (2)
- Zitronensäure (2)
- Zustimmungen (2)
- fungus (2)
- genetics (2)
- melanin (2)
- 13th century (1)
- 2D nanomaterials (1)
- 3D Printing (1)
- 3D inspection (1)
- A Greek palimpsest (1)
- AMR (1)
- AOF (1)
- ASAP-MS (1)
- ATR-FTIR (1)
- Abdichtungssysteme (1)
- Abfalltrennung (1)
- Abwasserreinigung (1)
- Academia (1)
- Acidobacteria (1)
- Additive Manufacturing (1)
- Additive manufacturing (1)
- Adipokinetic hormone (1)
- Adipokinetic hormone receptor (1)
- Adsorbable organically bound fluorine (AOF) (1)
- Advanced Materials (1)
- Aerosol element alanysis (1)
- Aerosol element mass concentration (1)
- Aerosol spectroscopy (1)
- Aerosolforschung (1)
- Affinity extraction (1)
- Affinity support (1)
- AgBB Bewertung (1)
- Agarose (1)
- Ageing (1)
- Aging test (1)
- Agronomic performance (1)
- Air pollution (1)
- Air quality (1)
- Airborne Particles (1)
- Alit (1)
- Alite hydraulic reactivity (1)
- Alkali zinc borate glass (1)
- Altlasten (1)
- Aluminum (1)
- Aluminum oxide (1)
- Amate (1)
- Ambient aerosol (1)
- Ambient aerosols (1)
- Ambient air (1)
- Ambient air pollution (1)
- Amino acid analysis (1)
- Ammoniak (1)
- Ammonium (1)
- Analytical chemistry (1)
- Analytical standards (1)
- Analytische Methode (1)
- Ancient INKS (1)
- Ancient document production (1)
- Anodization (1)
- Antagonism (1)
- Anti-microbial effects (1)
- Antiadhesive surfaces (1)
- Antibakterielle Oberflächen (1)
- Antibiotic (1)
- Antibody purification (1)
- Antimicrobial Resistance (1)
- Antimicrobial resistances (1)
- Antimony black (stibnite) (1)
- Aquatische Toxizität (1)
- Arabic recipes (1)
- Archaeological provenance (1)
- Archaeometric studies (1)
- Architektur (1)
- Archéométrie (1)
- Aromatic amino acid analysis AAAA (1)
- Aromatic amino acid analysis aaaa (1)
- Artificial ageing (1)
- Ascomycetes (1)
- AshDec (1)
- Aspergillus flavus (1)
- Astrobiology (1)
- Atomic force microscopy (1)
- Aufbau von Festkörpern (1)
- Aufbereitungstechnik (1)
- Auslaugtest (1)
- Auslaugtests (1)
- Auslaugverfahren (1)
- Auswaschung (1)
- Auswaschverlauf (1)
- Auswaschversuche (1)
- Authentifizierung (1)
- Autoclave tests (1)
- Autoklaventest (1)
- BAM Data Store (1)
- BAM-Zulassung (1)
- BEMMA Bewertung (1)
- BFR (1)
- BMU (1)
- BODIPY dye (1)
- BSA (1)
- Bacteria repellent surfaces (1)
- Bacteria-repellent surfaces (1)
- Bacterial attachment (1)
- Bacterial growth (1)
- Bacterial infection (1)
- Bakterien (1)
- Bankia sp (1)
- Basin (1)
- Bassanite (1)
- Bauhaus (1)
- Bauhaus Weimar (1)
- Bauprodukt (1)
- Bauproduktenverordnung (1)
- Bee (1)
- Bees (1)
- Begasung (1)
- Berliner Tuffsteinfassaden (1)
- Bestandserhaltung (1)
- Beständigkeit (1)
- Betondickglasfenster des Glockenturms am Eiermannbau (1)
- Bewertung (1)
- Bewertungsverfahren (1)
- Bio-P-Kläranlage (1)
- Bio-receptive (1)
- Bioactive glass (1)
- Bioavailability (1)
- Biocides in the environment (1)
- Bioconjugation (1)
- Biodegradation (1)
- Biofilme (1)
- Bioilm (1)
- Bioinformatics (1)
- Biological Control (1)
- Biological control (1)
- Biological pest control (1)
- Biologische Bekämpfung (1)
- Bioseparation (1)
- Biosphere (1)
- Biosphere-technosphere interaction (1)
- Biosynthesis (1)
- Biotische/abiotische Faktoren (1)
- Black Ink (1)
- Blattodea (1)
- Blue Angel ecolabel (1)
- Boden (1)
- Bodenbelag (1)
- Bodenbeläge (1)
- Bodenmaterialien (1)
- Book production (1)
- Botrytis (1)
- Botrytis cinerea (1)
- Bovine serum albumin (1)
- Brown-rot fungi (1)
- Building material (1)
- Building product (1)
- Building products (1)
- Byzantine manuscript (1)
- Bürogeräte mit Druckfunktion (1)
- CFRP (1)
- COST (1)
- COST Action (1)
- COVID (1)
- CRISPR dCas9 (1)
- CRM (1)
- Calcareous deposits (1)
- Calcium alkali phosphate (1)
- Calcium silicate (1)
- Calcium sulfate (1)
- Calibration (1)
- Carbon Fibre (1)
- Carbonbeton (1)
- Carolingian (1)
- Carotenoids (1)
- Carrier (1)
- Cascade impector (1)
- Cast iron (1)
- Cathodic protection (1)
- Cell factory (1)
- Chamber measurement (1)
- Chamber-test (1)
- Characterization (1)
- Chemical composition (1)
- Chemische Beständigkeit (1)
- Chemische Löslichkeit (1)
- Chicken manure (1)
- Chinese Paper (1)
- Chlorination (1)
- Climate responsive materials (1)
- Co-combustion (1)
- Coastal protection (1)
- Cockroach (1)
- Codex Miscellaneus (1)
- Codicology (1)
- Colorants (1)
- Colourants (1)
- Colouring (1)
- Combustion ion chromatography (CIC) (1)
- Compatible solute (1)
- Comsumer good samples (1)
- Concrete (1)
- Conditioning layer (1)
- Coniophora puteana (1)
- Conservation (1)
- Constantinomyces (1)
- Construction and demolition waste (1)
- Consumer article (1)
- Consumer articles (1)
- Consumer products (1)
- Contaminant transfer (1)
- Contamination (1)
- Controllable gene expression (1)
- Controlled atmosphere (1)
- Controlled release fertilisers (1)
- Copper (1)
- Coptic papyri (1)
- Coptic studies (1)
- Coptotermes (1)
- Core microbiome (1)
- Core/shell nanoparticle (1)
- Corrosion environment (1)
- Corrosion product (1)
- Covid (1)
- Cribellate spiders (1)
- Crispr-Cas9 (1)
- Crispr/Cas9 (1)
- Cryptoendolithic black fungus (1)
- Crystallization (1)
- Cubical shape (1)
- Cultural Entomology (1)
- Cultural Heritage (1)
- Culuative energy demand (1)
- DGT-Methode (1)
- DIN EN 16516 (1)
- DIN EN 350 (1)
- DIN EN 717-1 (1)
- DMAS (1)
- DNA (1)
- DNA barcode (1)
- Damage repair (1)
- Dauerhaftigkeit (1)
- Density separation (1)
- Deponiebau (1)
- Deponierung (1)
- Deponieverordnung (1)
- Desiccation (1)
- Design of experiments (1)
- Deterioration (1)
- Development (1)
- Dichtesortierung (1)
- Diffusive gradients in thin films (DGT) (1)
- Digitalisation (1)
- Digitalisierung (1)
- Direct material input (1)
- Disease (1)
- Dispay case (1)
- Dispergierung von Glaspartikeln (1)
- Dispersion of carbon pigments (1)
- Dispersion of glass particle (1)
- Display case (1)
- Diversität (1)
- Domestikation (1)
- Downstream processing (1)
- Drawing (1)
- Druck (1)
- Dry treatment (1)
- Durability (1)
- Dyes and pigments (1)
- E$volution (1)
- EDX Analysis (1)
- EN 717-1 (1)
- EOF/AOF (1)
- EPS (1)
- EU EMPIR (1)
- EU regulations (1)
- Early european inks (1)
- Eco-efficiency analysis (1)
- Ecology (1)
- Ecotoxicity testing (1)
- Edible insects (1)
- Effective uptake rate (1)
- Efflux (1)
- Eisengallustinte (1)
- Electrochemical remediation (1)
- Electronic Lab Notebook (ELN) (1)
- Electronic lab notebook (ELN) (1)
- Elektrolichtbogenofen (1)
- Element analysis (1)
- Element mass concetration (1)
- Elimination (1)
- Eluatwerte (1)
- Emerging Contaminants (1)
- Emission Test Chamber (1)
- Emission Testing (1)
- Emission chamber (1)
- Emission chamber testing (1)
- Emission chambers (1)
- Emission test chamber procedure (1)
- Emissions of hazardous gases (1)
- Emissionsfunktionen (1)
- Emissionsmessungen (1)
- Emissionsprüfkammer (1)
- Emisson testing (1)
- Enamel colors (1)
- Encre (1)
- Entwicklung (1)
- Environmental analysis (1)
- Environmental friendly (1)
- Erfurt (1)
- Ergebnisunsicherheit (1)
- Essential oils (1)
- Europa (1)
- European research area (1)
- Exergy (1)
- Experimental evolution (1)
- Exposure risk (1)
- Extracellular polymeric substances (1)
- Extractable organically bound fluorine (EOF) (1)
- Extraktion (1)
- Extraktionen (1)
- Extraktionsversuche (1)
- Extrazelluläre Polysaccharide (1)
- Extreme environments (1)
- Extremophilic fungi (1)
- FFF-3D printing (1)
- FT-Raman (1)
- FTIR spectroscopy (1)
- FTIR-, XRF-, VIS- espectroscopia (1)
- Fakes (1)
- Farbenlehre (1)
- Fassaden (1)
- Fassadenfarbe (1)
- Fassadenfarben (1)
- Façade (1)
- Feeding behaviour (1)
- Femtosecond laser processing (1)
- Fiber (1)
- Fibre (1)
- Fibre analysis (1)
- Filament comparison (1)
- Flame-retardant (1)
- Flammschutzmittel (1)
- Flotation (1)
- Flow chamber system (1)
- Flow system (1)
- Flow-System (1)
- Flow-system (1)
- Fluor XANES (1)
- Fluorescent proteins (1)
- Fluoride nanoparticles (1)
- Fluorides (1)
- Fluorolytic sol−gel (1)
- Fluorometric sensing (1)
- Flügel (1)
- Food safety (1)
- Force distance curve (1)
- Forgery (1)
- Formaldehyde (1)
- Forschungsdatenmanagement (1)
- Forschungsförderung (1)
- Forschungsstrategie (1)
- Foward genetics (1)
- Fractional factorial (1)
- Fragmented manuscripts (1)
- Freisetzung (1)
- Freisetzung und Transfer von Schadstoffen (1)
- Functionalized graphene (1)
- Fungicidal property (1)
- Fällmittel (1)
- Fälschungserkennung (1)
- Gas chromatography (1)
- Gas chromatography - mass spectrometry (GC-MS) (1)
- Gas sensing (1)
- Gas storage (1)
- Gebindekonservierung (1)
- Gebührenverordnung (1)
- Gene network (1)
- Genetic tools (1)
- Genetik (1)
- Genetisches Barcoding (1)
- Genizah du Caire (1)
- Genome editing (1)
- Genome sequence (1)
- Geological formation (1)
- Gesteinskorrosion (1)
- Gesteinskörnungen (1)
- Gesundheit (1)
- Gipsabfälle (1)
- Gipsrecycling (1)
- Giulio Romano (1)
- Glas (1)
- Glasanalyse (1)
- Glass paints (1)
- Glass scanning (1)
- Gleichgewicht (1)
- Gleichwertigkeit Messverfahren (1)
- Gold (1)
- Gold mit Synchrotronstrahlung (1)
- Gothic incursions (1)
- Granulat (1)
- Gray mold fungus (1)
- Green pesticide (1)
- Greenhouse gas accounting (1)
- Greenhouse gas balance (1)
- Greenhouse gas mitigation (1)
- Grundwasser (1)
- Größe (1)
- Gut microbiota (1)
- Gütezeichen (1)
- H2-Abbau (1)
- HR-CS-GFMAS (1)
- HR-GF-MAS (1)
- Halomonas elongata (1)
- Halophile (1)
- Halophilic (1)
- Hausbock (1)
- Hausbockkäfer (1)
- Headspace GC-MS (1)
- Heavy metal removal (1)
- Hebrew studies (1)
- Herculaneum papyri (1)
- Herteogeneous phenotypes (1)
- Heterologous expression (1)
- Heterologous gene expression (1)
- High resolution-continuum source-graphite furnace molecular absorption spectrometry (HR-CS-GFMAS) (1)
- High salinity (1)
- Hinterglasmalerei (1)
- Historic buildings (1)
- Historic ink (1)
- Holy Family (1)
- Holzschutz, (1)
- Holzschutzmittel (1)
- Holzwurm (1)
- Household waste (1)
- Human plasma (1)
- Hydraulic engineering (1)
- Hydrogen permeation (1)
- Hydrophobic interaction (1)
- Hylotrupes bajulus (1)
- Hylotrupes bajulus, Anobium punctatum, natural durability, tropical wood, native wood. (1)
- Hyperbranched polymer (1)
- IEQ (1)
- IPM in museums (1)
- ISO/TC 229 Nanotechnologies (1)
- ISO22196 (1)
- Igg (1)
- Illness-induced anorexia (1)
- Illuminated manuscripts (1)
- Immunoglobulins (1)
- Immunoprecipitation (1)
- Implants (1)
- In situ (1)
- In-vivo mutagenesis (1)
- Incineration bottom ash (1)
- Indoor Air Quality (1)
- Indoor Products (1)
- Indoor emission (1)
- Industrial applications (1)
- Industrielles Abwasser (1)
- Infrared spectroscopy (1)
- Initial attachment (1)
- Ink corrosion (1)
- Ink fingerprint (1)
- Ink terminology (1)
- Innenraumluftqualität (1)
- Innenraumluftqualtität (1)
- Insektenmonitoring (1)
- Instrumental analysis of ink (1)
- Integrated Museum Pest Management (IMPM) (1)
- Iodine (1)
- Ionizing radiation (1)
- Iron oxide (1)
- Isothiazolinone (1)
- Jewish cultures (1)
- Jig (1)
- Johann Wolfgang von Goethe (1)
- Kaiser-Wilhelm-Gedächtniskirche (1)
- Kandelaber des Ensembles am Charlottenburger Tor (1)
- Kleidermotte (1)
- Klimaneutralität (1)
- Kläranlage (1)
- Klärschlammdüngung (1)
- Kontamination (1)
- Kontamination von H2 (1)
- Korynaetes caeruleus (1)
- Kraftstoffabbau (1)
- Kraftstoffbehälter (1)
- Kristallsystem (1)
- Kulturelle Entomologie (1)
- Kulturguterhaltung (1)
- Kumulierter Energieaufwand (1)
- Kunstrasen (1)
- Kunststoff-Dränelement (1)
- Kunststoffsportbeläge (1)
- Kunsttechnologie (1)
- LC-MS/MS (1)
- LCA (1)
- LCC (1)
- LIBS (1)
- Lake Cadagno (1)
- Landwirtschaftliche Klärschlammverwertung (1)
- Langzeitverhalten (1)
- Laser Printer (1)
- Laser processing (1)
- Laser structuring (1)
- Laser-Materialbearbeitung (1)
- Laser-induced pariodic surface structures (1)
- Laser-induced periodic surface structueres (LIPPS) (1)
- Lead (1)
- Lead books (1)
- Lebensmittelindustrie (1)
- Lfe cycle assessment (1)
- Library pests (1)
- Life history data (1)
- Light regulation (1)
- Light sensing (1)
- Light-induced stress (1)
- Lightning talk (1)
- Lightweighting (1)
- Limitations (1)
- Limnoria spp (1)
- Linker (1)
- Low alloy steel (1)
- Low cost aerosol PM sensor (1)
- Low-tech approach (1)
- Lysimeter, Antimony (1)
- MDG ICP-ToF-MS (1)
- MIC Island (1)
- MIC projekt (1)
- MSWI Bottom Ash (1)
- MSWI bottom ash (1)
- Manuscript making (1)
- Manuscripta Americana, Techialoyan (1)
- Manuscrits (1)
- Map production and publishing (1)
- Maps and colours (1)
- Marble (1)
- Marine borers (1)
- Market surveillance (1)
- Mass spectroscopy (1)
- Material Analysis (1)
- Material analysis (1)
- Material degradation (1)
- Material emissions testing (1)
- Material recycling (1)
- Material surface colonisation (1)
- Materialkreislauf (1)
- Materials (1)
- Materials emissions testing (1)
- Materials flow (1)
- Mathematical modelling (1)
- Mechanische Stabilität (1)
- Medieval glasses (1)
- Medieval-stained glass (1)
- Melanins (1)
- Metal organic frameworks (1)
- Metal reducing bacteria (1)
- Metallic silver precipitates (1)
- Metallkorrosion (1)
- Metalls (1)
- Metals (1)
- Methanogene (1)
- Methanogenesis (1)
- Methode (1)
- Methoden (1)
- Methods of scientific analysis (1)
- Microbial abundance (1)
- Microbial communities (1)
- Microbial community modelling (1)
- Microbial survival mechanisms (1)
- Microbiologically Influrenced Corrosion (MIC) (1)
- Microbiologically influenced corrosion (MIC) (1)
- Microdroplet generator (1)
- Microfluidics (1)
- Migration (1)
- Mikrobiell (1)
- Mikrobielle Gemeinschaft (1)
- Mineral weathering (1)
- Mircobially influcenced corrosion (1)
- Mixed Inks (1)
- Mobile anodisation (1)
- Mobile application (1)
- Model (1)
- Model organism (1)
- Modellierung (1)
- Modern painting (1)
- Molecular (1)
- Moriscos (1)
- Moyen-âge (1)
- Multigassensorik (1)
- Multilocus phylogeny (1)
- Municipal solid waste (1)
- Museum insect pest (1)
- Museum pests (1)
- Museumsschädling (1)
- Museumsschädlinge (1)
- Museumsvitrine (1)
- Museumsvitrinen (1)
- Mutagenesis (1)
- Mycotoxins (1)
- NDT (1)
- NFDI (1)
- NIR reflectography (1)
- Nachhaltigkeit (1)
- Nachsorge (1)
- Nano CRM (1)
- Nano characterization (1)
- Nano metal fluorides (1)
- Nano@BAM (1)
- NanoPlattform (1)
- Nanocarrier (1)
- Nanoplattform (1)
- Nanorods (1)
- Nanotechnologie (1)
- Natural abundance of 15N (1)
- Natural products discovery (1)
- Near ambient pressure XPS (1)
- Neozoon (1)
- Netzwerk (1)
- Neuartige Materialien (1)
- Neuropeptide (1)
- Neutralammoniumcitrat (1)
- Neutralammoniumnitrat (1)
- Niedrig schmelzend (1)
- Niobium (1)
- Nitrate (1)
- Nitrification inhibitor (1)
- Nitrogen fixation (1)
- Nitrogen uptake (1)
- Non destructive (1)
- Non-destructive test (1)
- Non-invasive scientific methods (1)
- Norm (1)
- Nostoc (1)
- Novel sample preparation techniques (1)
- Novelle BBodSchV (1)
- Nuclear waste disposal (1)
- Nutrient (1)
- Oberflächenfunktionalisierung (1)
- Office machines (1)
- Oil and gas reservoir (1)
- Oilfield (1)
- On-Line Analyse (1)
- On-line analysis (1)
- OpenBIS (1)
- Operating Procedure (1)
- Optical properties of ink (1)
- Optical properties (1)
- Optische Tomografie (1)
- Ordinance on Contaminated Sites and Soil Protection (1)
- Organo fluorine analysis (1)
- Osmophobic effect (1)
- P-Recyclate (1)
- P-Rückgewinnung (1)
- P-Senken (1)
- P-recovery (1)
- PAH (1)
- PBFSM (1)
- PE-HD (1)
- PFAS analysis (1)
- PFAS analytics (1)
- PM (1)
- PP (1)
- PS (1)
- Paints (1)
- Palaeography (1)
- Palimpsest (1)
- Paper (1)
- Paper sizings (1)
- Paper tinting (1)
- Paratext (1)
- Parerga (1)
- Particle (1)
- Particle Size (1)
- Particulate emissions (1)
- Partikeldurchmesser (1)
- Partikeln (1)
- Pentimenti (1)
- Per- and polyfluorinated alkyl substances (PFASs) (1)
- Per- und Polyfluoroierte Alkylsubstanzen (PFAS) (1)
- Perfluorierte Verbindungen (1)
- Perfluorocarboxylic acid (PFCA) (1)
- Performance comparison (1)
- Pergament (1)
- Pergamonmuseums (1)
- Periodate oxidation (1)
- Permeat (1)
- Perowskit (1)
- Persian historical recipes (1)
- Persian manuscript (1)
- Pflanzenverfügbarkeit (1)
- Pflanzenwurzel (1)
- Phase separation (1)
- Phosphonic acids (1)
- Phosphor-Rückgewinnung (1)
- Phosphorbestimmung (1)
- Phosphorus recycling (1)
- Photocatalytic surfaces (1)
- Photoperception (1)
- Photoreceptors (1)
- Phototrophic bacteria (1)
- Physical and optical characteristics (1)
- Pilz (1)
- Pilze (1)
- Plant growth test (1)
- Plant pathogen (1)
- Plant-availability (1)
- Plasma (1)
- Plastic biofilm (1)
- Plastic pollution (1)
- Poficiency test (1)
- Pollutant (1)
- Polyfluorinated alcohol (PFOH) (1)
- Polymer (1)
- Polymer Matrix Composites (1)
- Polymer foils (1)
- Polypropylen (1)
- Polystyrol (1)
- Portrayal of St Joseph (1)
- Poster presentation (1)
- Pot experiment (1)
- Prallzerkleinerungsverfahren (1)
- Preferential binding (1)
- Preferential exclusion (1)
- Preis- Leistungsverzeichnis (1)
- Preservation (1)
- Printing (1)
- ProMoAM (1)
- Process control (1)
- Process monitoring (1)
- Proficiency Test (1)
- Projekte (1)
- Protective glazing (1)
- Protein (1)
- Protein a (1)
- Protein hydrolysis (1)
- Protein immobilization (1)
- Protein quantification (1)
- Proteomics (1)
- Prüfkammer (1)
- Prürfrichtlinie (1)
- Pseudomonas (1)
- Purification (1)
- Push-out Test (1)
- QA/QC (1)
- Quality assurance/quality control (1)
- Quantum dot (1)
- Qumranrollen (1)
- RAMAN (1)
- REACH (1)
- Radiocarbon (1)
- Radiografische Untersuchung (1)
- Radon (1)
- Raphael school (1)
- Reactive oxygen species (1)
- Recipes (1)
- Recycling fertilizer (1)
- Recyclingdüngemittel (1)
- Red chalk (1)
- Reduction (1)
- Reductive iron assimilation (1)
- Reduktionsprozess (1)
- Reference data (1)
- Reference method (1)
- Reference nanoparticles (1)
- Reference procedures (1)
- Regelwerk (1)
- Reifenabrieb (1)
- Relative agronomische Effizienz (RAE) (1)
- Release kinetics (1)
- Religion (1)
- Research Data Infrastructure (1)
- Research Data Management (1)
- Research data management (1)
- Ressourceneffizienz (1)
- Ressourcenschonung (1)
- Restoration and conservation (1)
- Retentat (1)
- Reverse painting on glass (1)
- Reworking (1)
- Rhizosphere (1)
- Rhodonia placenta (1)
- Ringversuch P-Gehalt in Klärschlamm (1)
- Risikobewertung (1)
- Road construction waste (1)
- Rock-inhabiting black fungi (1)
- Rock-inhabiting fungi (1)
- Röntgenspektroskopie (1)
- Rötel (1)
- Rückgewinnung (1)
- SARS (1)
- SAXS (1)
- SDS-PAGE (1)
- SEM wood characterization (1)
- SEM-EDS (1)
- SERS (1)
- SMPS (1)
- SOP (1)
- SPE extraction (1)
- SRB (1)
- Sapphire (1)
- Scattering (1)
- Schadgase (1)
- Schlacke (1)
- Schmetterlinge (1)
- Schriftrollen vom Toten Meer (1)
- Schutzverglasung (1)
- Schwermetalle (1)
- Schädling (1)
- Scythica Vindobonensia, (1)
- Secondary metabolism (1)
- Secondary raw materials (1)
- Secondary resources (1)
- Sediment (1)
- Sekundärgipse (1)
- Sekundärrohstoff (1)
- Selection (1)
- Selektion (1)
- Self-assembled monolayer (SAM) (1)
- Sensor (1)
- Separate collection (1)
- Sets of archaeometric data (1)
- Setzmaschine (1)
- Sewage extraction (1)
- Sewage sludge incineration (1)
- Shale (1)
- Siderophore (1)
- Signal transduction (1)
- Silver diffusion (1)
- Simulation of materials degradation (1)
- Sintering (1)
- Sixteenth-century painting technique (1)
- Size resolved chemical composition (1)
- Sizing (1)
- Small angle x-ray scattering (1)
- Smartphone (1)
- Social (1)
- Social immunity (1)
- Social insects (1)
- Soil extraction (1)
- Soil-like material (1)
- Soil-like materials (1)
- Solar parks (1)
- Solid phase (1)
- Spectral imaging (1)
- Speziierungsanalyse (1)
- Spielzeug (1)
- Sportböden (1)
- Sportböden auf Kunststoffbasis (1)
- Stained glass (1)
- Stained glass windows (1)
- Stained glasses (1)
- Stainless steel (1)
- Stakeholder (1)
- Stalwerksschlacke (1)
- Standardarbeitsanweisungen (1)
- Standardized test and quantification procedure (1)
- Standsicherheit (1)
- Stoffstromanalyse (1)
- Structural color (1)
- Structured light scanning (1)
- Sub-4nm particles (1)
- Subaerial biofilm (1)
- Subaerial biofilms (1)
- Sugarcane bagasse (1)
- Sum parameter analyis (1)
- Summenparameter (1)
- Superhydrophilic surface (1)
- Superhydrophobic surface (1)
- Surface chemistry (1)
- Surface functionalization (1)
- Surfacewaters (1)
- Synchotron (1)
- Synchrotron-XPS (1)
- Synthetic organic pigments (1)
- TEM (1)
- TXRF ambient air aerosol chemical analysis aerosol element composition (1)
- Tanning (1)
- Tannins (1)
- Tauchtest (1)
- Technologietransfer (1)
- Temperature and humidity (1)
- Teredo sp (1)
- Termite control (1)
- Termite-associated microbes (1)
- Termiten (1)
- Test method (1)
- Test strip (1)
- Teststreifen (1)
- Testverfahren (1)
- Text analysis (1)
- Textilschädling (1)
- Thermal Desorption (1)
- Thermal Extraction (1)
- Thermal desorption (1)
- Thermal imaging (1)
- Thermal properties (1)
- Thermal treatment (1)
- Thermische Abfallbehandlung (1)
- Thermochemical treatment (1)
- Thermochemische Prozesse (1)
- Thermografie (1)
- Thermographie (1)
- Thermoplastic filaments (1)
- Time resolved chemical composition (1)
- Tinting (1)
- ToF SIMS (1)
- ToF-SIMS (1)
- Tomography (1)
- Torah (1)
- Torah Scrolls (1)
- Trait-based ecology (1)
- Transmission electron microscopy (1)
- Transport modeling (1)
- Transposon (1)
- Typology of Inks (1)
- Tyrosine (1)
- UV absorption (1)
- UV protection (1)
- UV tolerance (1)
- UV-VIS Reflectance spectroscopy (1)
- UV-VIS reflectance spectroscopy (1)
- UV-irradiation (1)
- Ultrakurzpuls-Laser (1)
- Ultrashort PFAS (1)
- Ultrashort laser processing (1)
- Umweltbewertung (1)
- Umweltverträglichkeit (1)
- Ungleichgewicht (1)
- Unterirdische Speicher (1)
- Upscaling (1)
- Uranium (1)
- Uranium mining (1)
- Urban mining (1)
- Utilization (1)
- VAMAS (1)
- VIS- Spektroskopie (1)
- VOC Emission (1)
- VOC transfer standards (1)
- Vanadium (1)
- Vasari (1)
- Vegetationsversuche (1)
- Velocimetry (1)
- Vererbung (1)
- Versuchskampagne (1)
- Verwertung Bodenmaterial (1)
- Vienna manuscript (1)
- Virulence (1)
- Vitrine (1)
- Volatile organic compound (1)
- Volatile organic compounds (VOC) (1)
- Vorsorgewerte (1)
- Vues des Cordillères (1)
- WKI flask method (1)
- Wasserbau (1)
- Wasserstofflagerung (1)
- Wasserstoffplasma (1)
- Waste water (1)
- Waste water treatment (1)
- Water analysis (1)
- Weathering tests (1)
- Wet-mechanical treatment (1)
- Wiederholbarkeit (1)
- Wiederverwertung (1)
- Wirksamkeit (1)
- Wooden toys (1)
- Workflows (1)
- Writing Ink (1)
- Wärmedämmverbundsystem (1)
- X-Ray fluorescence (1)
- X-ray adsorption near-edge structure (XANES) spectroscopy (1)
- X-ray based techniques (1)
- X-ray diffraction (1)
- X-ray spectroscopic techniques (1)
- X-rays (1)
- XANES-Spektroskopie (1)
- XRF Analysis (1)
- XRF-, FTIR-, VIS-espectroscopía (1)
- XRF-, VIS- FTIR-spectroscopy (1)
- XRF-, VIS- spectroscopy (1)
- Xestobium rufovillosum (1)
- Zeichnung (1)
- Zentrat (1)
- Zentrifugalsortierer (1)
- Zeolite (1)
- Zertifikate (1)
- Zinnschlacken (1)
- biocide tolerance (1)
- black fungi (1)
- black fungus (1)
- carotenoids (1)
- disinfection (1)
- evolution (1)
- fs-laser processing (1)
- genomics (1)
- heterogeneity (1)
- historic inks (1)
- individual-based modelling (1)
- infrared spectroscopy (1)
- ink (1)
- light (1)
- multi scale testing (1)
- natural ventilation (1)
- openBIS (1)
- papyrus (1)
- pigmentation (1)
- plant pathogen (1)
- signaling (1)
- thermochemische Behandlung (1)
- underexplored phyla (1)
- virulence (1)
- Äquivalenzdurchmesser (1)
- Ökobilanz (1)
- Ökotoxtests (1)
Organisationseinheit der BAM
- 4 Material und Umwelt (849) (entfernen)
UBA und BAM schlagen die Durchführung der Prüfkammermessungen bei 23 °C und 50% relativer Luftfeuchte, einer Beladung von 1,8 m²/m³ und einem Luftwechsel von 0,5 pro Stunde vor. Diese Parameter orientieren sich an der EN 16516, die als zukünftige „Referenznorm“ zu betrachten ist. Die Schmalflächenversiegelung ist auch zukünftig wie in der EN 717-1 beschrieben vorzunehmen. Nach 28 Tagen wird der Mittelwert einer Doppelbestimmung als Endkonzentration („entsprechend der Ausgleichskonzentration“) berechnet. Alternativ dazu kann die Prüfung vorzeitig abgebrochen werden, wenn an 5 Messtagen der Prüfung eine Formaldehydkonzentration von 0,1 ppm nicht überschritten wird.
Prüfungen nach der EN 717-1 sollen weiterhin gleichberechtigt möglich sein. Ergebnisse von Messungen, die nach der EN 717-1 ermittelt wurden, sind mit dem Faktor 2,0 zu multiplizieren.
Abgeleitete Verfahren wie z.B. das Gasanalyseverfahren sollen weiterhin möglich sein. Das Perforatorverfahren entfällt hier, da eine allgemeine für alle Holzwerkstoffe gültige Korrelationen nicht existiert.
Die entsprechenden Änderungen sind in der vom BMUB veröffentlichten „Bekanntmachung analytischer Verfahren für Probenahmen und Untersuchungen für die im Anhang der Chemikalien-Verbotsverordnung genannten Stoffe und Stoffgruppen“ entsprechend zu ändern.
There is a need for an assessment of the emission properties of volatile organic compounds (VOCs) from consumer products. A method comparison was carried out to evaluate adapted and cost-effective procedures for such items. Smaller and automated emission chambers de-picted similar kinetics compared to a 203 L standard chamber. Toy samples made of PVC (Polyvinyl chloride) emitted more VOCs compared to other tested polymeric products. The emissions from 2 selected samples were studied to allow an evaluation of the resulting room concentration and external exposure of a child. Obtained concentrations were not of concern.
Two new approaches towards an emission reference material for use in quality assurance measures for materials emissions testing were developed and intensively tested. The overall goal was to obtain solid materials with homogenous and reproducible (S)VOC release. Since the application in inter-laboratory comparisons is aimed at, it should furthermore be long-term stable to ensure safe shipment to the customer without sustaining compound losses. In the first approach, thermoplastic polyurethane (TPU) was impregnated with the VOC texanol under high-pressure with liquid CO2 as solvent. In the second, styrene (VOC) and the SVOC 2,6-diisopropylnaphthalene (DIPN) were spiked into vacuum grease (VG) and a mixture of paraf-fin/squalane (P/S). For the prediction of the emission rates a finite element model (FEM) was developed for the VG and P/S type materials. All requirements for reference materials were fulfilled, whereas the TPU samples need to be aged for about 10 days until repeatable and re-producible emission rates were obtained.
BEMMA steht für Bewertung von Emissionen aus Materialien für Museumsausstattungen. Es ist die Kurzbezeichnung für ein Schema/Verfahren zur Untersuchung und Bewertung flüchtiger organischer Verbindungen aus Werkstoffen, die im mittelbaren Kontakt mit historischen Materialien des Kunst- und Kulturgutes stehen. Ergebnisse der Untersuchungen seit ca. 2010 bis 2017 werden präsentiert und diskutiert.
Anregungen aus dem N.i.Ke.-Workshop 2017 und künftige Anforderungen. BEMMA steht für Bewertung von Emissionen aus Materialien für Museumsausstattungen. Es ist die Kurzbezeichnung für ein Schema/Verfahren zur Untersuchung und Bewertung flüchtiger organischer Verbindungen aus Werkstoffen, die im mittelbaren Kontakt mit historischen Materialien des Kunst- und Kulturgutes stehen. Hier wird der Status-Quo des Erreichten dargestellt. Wie wird das Schema in der Museumsöffentlichkeit wahrgenommen und seine Akzeptanz.
Comparison of Formaldehyde Concentrations in Emission Test Chambers Using EN 717-1 and EN 16516
(2018)
For more than 25 years EN 717-1 (Wood-based panels - Determination of formaldehyde re-lease - Part 1: Formaldehyde emission by the chamber method) is the standard for formalde-hyde emission testing of wooden boards. In 2017 EN 16516 (Construction products - Assess-ment of release of dangerous substances - Determination of emissions into indoor air) was published as a new harmonised standard for the emission testing of construction products. Because test chamber conditions are different, both standards give different concentrations for formaldehyde. To determine a conversion factor four test series were set up with different wooden boards. For a loading of 1 m²/m³ the conversion factor is 1.6. This means that the formaldehyde concentration measured under the conditions of EN 16516 is a factor of 1.6 higher compared to EN 717-1.
Wood treated with nano metal fluorides is found to resist fungal decay. Sol−gel synthesis was used to synthesize MgF2 and CaF2 nanoparticles. Electron microscopy images confirmed the localization of MgF2 and CaF2 nanoparticles in wood. Efficacy of nano metal fluoride-treated wood was tested against brown-rot fungi Coniophora puteana and Rhodonia placenta. Untreated wood specimens had higher
mass losses (∼30%) compared to treated specimens, which had average mass loss of 2% against C. puteana and 14% against R. placenta, respectively. Nano metal fluorides provide a viable alternative to current wood preservatives.
Zukünftig werden vermehrt P-Recyclate auf den Düngemittelmarkt kommen. Diese müssen ausreichend charakterisiert werden, um Sicherheit und Wirksamkeit beurteilen zu können. Mit dem Vortrag wurde der wissenschaftliche Beirat für Düngungsfragen des Bundesministeriums für Ernährung und Landwirtschaft beraten.
A short natural and cultural history of the webbing clothes moth (Tineola bisselliella). It is generally accepted that the natural habitats of most pest insects can be found outside the synanthropic environment in layers of leaf litter, under bark, as well as in rodent or bird nests. Indeed, most of the common fabric pests have been reported as being facultative nidicolous. Therefore, infestation of commodities by pest insects out of these reservoirs is one possibility to be considered. However, the likelihood of a pest´s occurrence and survival outside of the synanthropic habitat largely depends on its ecological potential and competitiveness against other species of the same ecological guild. Some pest species are rarely found in wild habitats, especially in those regions where they are not native and where they have been introduced by man.
The fabric pest Tineola bisselliella serves as a good example. Most likely originating from Central or Southern Africa, this insect was introduced into Europe probably not earlier than the late 18th century. Being more tolerant to dry environments than other fabric pests, its economical importance increased during the 20th century when the indoor climate changed because of central heating systems. Its occurrence in outdoor natural habitats must be regarded as accidental. Reported finds of webbing clothes moth larvae in bird nests e. g. have been largely overstated in the literature. Tineola bisselliella should be regarded as an invasive and eusynanthropic species in most parts of the world.
Normgerechte Ausführung resultiert in Qualität, aber sie ist nicht allein ein Garant auch für hohe Qualität. Hierfür sind begleitend immer auch nachgeordnete Richtlinien wie z. B. spezifische Gütekriterien zu erfüllen. Der Vortrag erklärt die Normungsarbeit auf nationaler und internationaler Ebene und schildert die Stärken aber auch die Schwächen bei der Erstellung von Normen. Dabei ist die Konsensbildung zwischen unterschiedlichen interessierten Kreisen mit deren Partikularinteressen oftmals ein Hindernis, das aber über Zusatzvereinbarungen und der Norm nachgeordneten Regeln überwunden werden kann.
Auslaugung von Stoffen aus Bauteilen kann zu einer Belastung von Boden und Gewässern führen. Das Simulationsmodell COMLEAM (COnstruction Material LEAching Model) wurde eingesetzt, um die Stoffauswaschung besser zu verstehen und das damit verbundene Umweltrisiko besser einschätzen zu können. Emissionsfunktionen sind Bestandteil dieses Modells. Hier werden fünf verschiedenen Funktionen beschrieben, getestet und hinsichtlich ihrer Eignung für Prognosemodelle bewertet.
In der Berliner Sammlung "Manuscripta Americana" befinden sich Fragmente von Bilderhandschriften, die Alexander von Humboldt 1804 in Mexiko erwarb und der Königlichen Bibliothek schenkte. Die in der frühen Kolonialzeit hergestellten verschiedenartigen Codices waren damals schon nicht mehr an den Orten ihrer ursprünglichen Verwendung. Entsprechend ihres Seltenheitswertes gelangten einzelne Schriftstücke seit der Conquista in die Bestände bedeutender Persönlichkeiten. Hierzu fertigte man auch Abschriften oder Kopien an, oder zerstückelte sogar einzelne Blätter, so dass die Darstellungen auf den abgetrennten Fragmenten oft nur zum Teil abgebildet vorliegen.
Um herauszufinden, ob einige Schriftstücke der "Humboldt Codices" in Bezug zu einander stehen, werden die Dokumente, ihre Symbole und Schriftzeichen und das zur Herstellung verwendete Material miteinander verglichen.
Mit den für die Analyse von Manuskripten bewährten Untersuchungsmethoden werden Papier und Farbmittel identifiziert. Hierzu zählen Raman-, FTIR-, Röntgenfluoreszenz- und VIS- Spektroskopie. Charakteristisch für die Herstellung von schriftlichen Dokumenten in der Kolonialzeit von Amerika ist die Verwendung von indigenem Material wie Papier aus Baumrinde und Pflanzenfarben zusammen mit den aus Europa bekannten Materialien. Geklärt wird, inwieweit neben den bekanntesten Farbstoffen wie Cochenille, Mayablau oder Mischungen mit Tonmineralen auch mineralische Pigmente zum Einsatz kamen.
Vorgestellt werden die auf Tafel 36 in den "Vues des Cordillères et Monuments des Peuples Indigènes de l`Amerique, Voyage de Humboldt et Bonpland" abgebildeten Fragmente. Die hier von Humboldt vorgenommene Zusammenstellung wird mit der Farbpalette der in Berlin archivierten originalen Schriftstücke verglichen. Die Interpretation der Ergebnisse gibt einen Hinweis auf die Zuordnung oder auch Zusammengehörigkeit dieser einzigartigen Dokumente amerikanischer Geschichte. Hierbei wird die Frage aufgeworfen, inwiefern davon auszugehen ist, dass diese mit weiteren Fragmenten in Verbindung gebracht werden können, was für die Beleuchtung der kulturhistorischen Zusammenhänge von großer Bedeutung ist.
Tools for the characterization of secondary raw materials - status of leaching test application
(2018)
Leaching tests are used as tools for the assessment of environmental compatibility of granular waste materials with potential for reuse. The presentation gives an overview on available leaching tests, their field of application and relation to legislation. Furthermore robustness testing to elaborate optimized test conditions as well as performance characteristics from validation studies by BAM are addressed.
Tools for the characterization of secondary raw materials - status of leaching test application
(2018)
Leaching tests are used as tools for the assessment of environmental compatibility of granular waste materials with potential for reuse. The presentation gives an overview on available leaching tests, their field of application and relation to legislation. Furthermore robustness testing to elaborate optimized test conditions as well as performance characteristics from validation studies by BAM are addressed.
Tools for the characterization of secondary raw materials - status of leaching test application
(2018)
Leaching tests are used as tools for the assessment of environmental compatibility of granular waste materials with potential for reuse. The presentation gives an overview on available leaching tests, their field of application and relation to legislation. Furthermore robustness testing to elaborate optimized test conditions as well as performance characteristics from validation studies by BAM are addressed.
Im Beitrag wurden erste Ergebnisse eines laufenden UFOPLAN-Vorhabens zu den neuen Kriterien der Verwertungsmöglichkeiten von Bodenmaterialien außerhalb der durchwurzelbaren Bodenschicht nach den §§ 6 bis 8 der Novelle der BBodSchV vorgestellt. Der Schwerpunkt lag auf Untersuchungen der Schadstoffgruppe der PAK. Dabei wurden Probleme der Vergleichbarkeit und Leistungsfähigkeit verschiedener Elutions- und Analyseverfahren der PAK-Analytik diskutiert.
Im Beitrag wurden Ergebnisse von Elutionsuntersuchungen mit PFC kontaminierten Bodenmaterialien vorgestellt. Zum einen waren das Untersuchungen zur Eignung von Säulenversuchen für diese Schadstoffgruppe und zum anderen vergleichende Schüttel- und Säulenversuche für zwei verschiedene Böden mit unterschiedlichen PFC-Kontaminationsquellen.
Im Vortrag werden Auswaschversuche mit Bauprodukten vorgestellt, die dazu dienen sollen, Bauprodukte mit geringer Auswaschung zu erkennen. Zu verschiedenen Bauprodukten (Lacke für Außenanwendungen, Wärmedämmverbundsystemen, Dachziegel und Dachfolien) werden ausgewählte Ergebnisse vorgestellt. Die Eignung der Auswaschverfahren und die Testergebnisse werden bewertet.
Development of a methodical approach for in-situ analysis of modern reverse paintings on glass
(2018)
The technique of painting on the reverse side of glass was rediscovered by artists in the early 20th century and gained great popularity, especially in Germany. In contrast to other paint techniques (e.g. panel and mural painting), the paint layers are applied in reverse succession starting with the foremost paint layer and ending with the primer (backmost layer). The paintings are viewed in reflected light, thus revealing an impressive gloss, luminosity and depth of colour.
Scientific investigation of the material provides important information for appropriate conservation concepts. Transport of the precious and fragile objects to the lab is often not feasible. Therefore, in-situ, non-invasive analysis is necessary to analyse colorants and binders. However, some analytical problems need to be considered: due to the reverse paint stratigraphy in reverse paintings on glass, the measured layer is always the backmost one. The analytical possibilities are extremely reduced, when the back is covered by a metal foil (or by paper, carton etc.). However, measurements through the glass (using Raman and VIS) can still yield information on the colourants of the front layer.
When the paint layer is accessible, we start our procedure using X-ray fluorescence (Tracer III-SD, Bruker AXS Microanalysis GmbH, 40 kV, 15 μA) and VIS reflectance spectroscopy (SPM 100, Gretag-Imaging AG). Both techniques provide first information on the inorganic colourants. Raman measurements (i-Raman®Plus, Bwtek inc., 785 nm, 50× objective, resolution 4 cm-1) are then carried out to clarify uncertain XRF measurements and to identify synthetic organic pigments (SOP). Diffuse Reflection-Infrared-Fourier-Transform Spectroscopy (DRIFTS; ExoScan, Agilent GmbH, 4000–650 cm-1, 500 scans, spectral resolution 4 cm-1) is used for the classification of the binders. Moreover, it may help to identify SOP, when fluorescence dominates the Raman signal. This analytical sequence yields the best results, when time is the limiting factor.
We present two in-situ studies of the paintings “Kreuzabnahme” (1914-15) by Carlo Mense and “Stadt am Morgen” (1921) by Walter Dexel. The painting “Kreuzabnahme” is an outstanding piece in Mense’s ɶuvre, because the glass plate was painted on both sides (Fig. 1). The results of the back-side show mainly inorganic pigments: basic lead white, talc, red and brown ochre, cinnabar, chrome yellow, viridian, ultramarine blue, Prussian blue and bone black. The classification of binding media using DRIFTS yields positive results for drying oil. Acrylic resin could be identified in two areas, resulting from a previous restauration treatment. For the front side painting, Mense used basic lead white, cinnabar, chrome yellow and umbra as pigments and oil as binder.
Measurements of the abstract painting “Stadt am Morgen” by Walter Dexel show zinc white, basic lead white, chalk, cinnabar, red lead, strontium yellow, cadmium yellow, cobalt blue, Prussian blue, ultramarine blue, brown ochre and bone black as pigments. Moreover, synthetic alizarin (PR83) was identified as dark red colorant. The results of DRIFTS classify oil as binding media.
We conclude that, the use of complementary spectroscopic methods yields the best results for in-situ analysis of reverse paintings on glass.
Brominated flame retardants have widely been used for more than 50 years and have been frequently detected in environmental samples as surface water and fish. Leaching from construction products was identified as one possible source. The use of substances as e.g. hexabromocyclododecane (HBCCD) was restricted recently due to increasing concern about negative impacts on the environment and human health caused by the persistent, bio accumulative and toxic properties. New polymeric brominated flame retardants have been developed to replace HBCCD in expanded polystyrene (XPS), which is used for insulation of buildings. It is assumed that the release from the polymer is much smaller in comparison to release of small molecules as HBCCD. The release from the polymer may include monomers or small fragments of different size. Thus, a sum parameter is needed. According to Schlummer et al. it is possible to detect brominated molecules using X-ray fluorescence spectroscopy by determination of brome content in XPS extracts. As only small brominated compounds can be extracted it also allows for the differentiation between the two classes of compounds. This method was applied to verify the presence of different kinds of flame retardants in XPS samples and to evaluate the leaching behavior.
Zearalenone (ZEN) and its sulfate and glucoside conjugates have been detected in (a broad variety of) food and feed commodities1. Both conjugated derivatives are formed as part of fungal or plant secondary metabolism and thus, belong to the group of modified mycotoxins2. After consumption of contaminated foodstuff, the conjugates can be hydrolyzed by human intestinal microbiota leading to liberation of ZEN that implies an underestimation of the true ZEN exposure. In order to include ZEN conjugates in routine analysis, as well as for toxicological investigation reliable standards are needed.
The objective of the present study was to develop a simple and economic method for biosynthesis of ZEN conjugates. Preceding experiments on the biotransformation of ZEN by Rhizopus and Aspergillus species showed a mixed metabolite formation3. Therefore, these known ZEN conjugating fungal strains were screened for their potential to selectively synthesize the ZEN derivatives ZEN-14-sulfate (Z14S), ZEN-14-glucoside (Z14G) and ZEN-16-glucoside (Z16G). The screening was conducted by adding ZEN to liquid fungal cultures. Cultivation conditions and ZEN incubation time were varied. All media samples were analyzed for metabolite formation by HPLC-MS/MS. Z14S was exclusively formed by A. oryzae. Under optimized conditions a specific biosynthesis of Z14G by R. oryzae and Z16G by R. oligosporus was achieved. After liquid-liquid-extraction and preparative chromatographic cleanup 1H-NMR purities of ≥ 73% for Z14S, ≥ 82% for Z14G and ≥ 50% for Z16G were obtained. In addition, a consecutive biosynthesis was developed by first using Fusarium graminearum for ZEN biosynthesis on rice based liquid medium. After inactivation of Fusarium the subsequent conjugation reaction was conducted utilizing Aspergillus and Rhizopus species under the various optimized conditions.
In this study an easy and cost-efficient biosynthesis for Z14S, Z14G and Z16G was developed. The developed biosynthesis could be also used for other metabolites like ZEL conjugates. Our results of the in vitro screening indicate also the formation of a ZEL-glucoside and α ZEL-sulfate as major metabolites by R. oryzae. In sum, under optimized cultivation conditions fungi can be easily utilized for a targeted and stereospecific synthesis of ZEN conjugates.
Mit dem Fokus auf eine saubere Innenraumluft wird darauf eingegangen, welche Emissionen aus Materialien und Produkten es gibt und wie sie nach Art und Flüchtigkeit definiert sind und wie sie gemessen werden. Im weiteren wird dargestellt, was und wie viel aus Materialien und Produkten emittieren kann und wie die Emissionen zu bewerten sind. Hierbei wird auch auf besonders emissionsarme Materialien und Produkte eingegangen.
Infections with multi-resistant Gram negative pathogens are a major threat to our health system. In order to serve the needs in antibiotics development we selected untapped bioresources and implemented high throughput approaches suitable for the discovery of strains producing antibiotics with anti-Gram negative activity.
Our approaches rely on the hypothesis that Termite associated bacteria are likely to produce potent antibiotics to defend their hosts against entomopathogenic microorganisms. Termite nests and guts harbor suitable, highly diverse microbiomes in which bacterial taxa are present known to potentially produce natural compounds. In
a first step the diversity of Coptotermes species nest microbiomes was assessed carefully by using 16S rDNA amplicon sequencing on the Illumina MiSeq platform and nest material was selected to retrieve viable cells by using Nycodenz density gradient centrifugation. In order to analyze the diversity of the culturable termite nest microbiome, bacterial cells were either distributed in 384-well plates
(approach 1) or encapsulated in small spheric agarose beads by an high throughput microfluidics technique (approach 2). Cultures obtained from approach 1 were scaled-up in 96-well Duetz-systems for characterization of diversity and for rapid supernatant screening using the bioluminescence-labeled E. coli pFU166. The generated
droplets of approach 2 simultaneously received a small population of GFP-tagged Gram negative screening cells and were sorted for low fluorescence using FACS. After elimination of redundancy we performed a fast scale-up of active strains.
Implementation of this pipeline allows us to prioritize antibiotics producing strains in a ultra-high throughput fashion and by cultivation of broad diversity in our approches.
Nach 1850 wurde zur weiteren Herabsetzung der Einbrenntemperatur von Glasmalfarben Borax (Na2B4O7 · 10 H2O) zugesetzt. Das Verhältnis war nun 1 Teil SiO2, 3 Teile PbO und 0,5 Teile Borax. Der analytische Nachweis von Bor in eingebrannten Malschichten war bisher jedoch nicht möglich.Daher wurden in Laborversuchen Glasmalfarben mit unterschiedlichem Gehalt an Borax auf Modellgläser aufgetragen, eingebrannt und anschließend unter simulierten Umweltbedingungen zeitraffend im Klimaschrank bewittert.
Mit Hilfe von elektronenmikroskopischen Untersuchungen können Malschichten charakterisiert werden und somit Hinweise auf mögliche Schadensursachen liefern. Erste Versuche zum Nachweis von Bor erfolgten mit Hilfe von LIBS-Messungen (Laser Induced Breakdown Spectroscopy) an im Labor hergestellten Glasmalfarben mit unterschiedlichem Boraxgehalt.
Nach 1850 wurde zur weiteren Herabsetzung der Einbrenntemperatur von Glasmalfarben Borax (Na2B4O7 · 10 H2O) zugesetzt. Das Verhältnis war nun 1 Teil SiO2, 3 Teile PbO und 0,5 Teile Borax. Der analytische Nachweis von Bor in eingebrannten Malschichten war bisher jedoch nicht möglich.
In Laborversuchen wurden Glasmalfarben mit unterschiedlichem Gehalt an Borax auf Modellgläser aufgetragen, eingebrannt und anschließend unter simulierten Umweltbedingungen zeitraffend im Klimaschrank bewittert. Mit Hilfe von elektronenmikroskopischen Untersuchungen können Malschichten charakterisiert werden und somit Hinweise auf mögliche Schadensursachen liefern. Der Nachweis von Bor erfolgte mit Hilfe von LIBS-Messungen (Laser Induced Breakdown Spectroscopy) an im Labor hergestellten Glasmalfarben mit unterschiedlichem Boraxgehalt.
Initial situation:
Aluminum is an often-used building material in modern architecture, not only for construction but as well for facades and decorative elements. In the 1950th and 1960th, after World War II, many buildings in Germany were constructed with aluminum or contain elements of colored anodized aluminum. In the last years a larger number of these buildings are increasingly in the sight of conservation works including the aluminum parts such as window frames or facade coverings.
Damaged Aluminum Surfaces:
Common damages are a change of color or gloss changes through weathering processes, drill holes or marks due to later modifications, scratches in the anodized layer due to extensive wear e.g. at handrails or door handles.
To repair damaged aluminum surfaces, there are usually two options: smaller damaged areas are repaired by using a touch-up pen. In case of larger damages, the complete re-anodization is necessary. This includes to de-anodize the surface with cleaning and grinding the whole aluminum object. Both possibilities are disadvantageous for the objects. The touch-up pen often does not match the color of the original surface together with an insufficient corrosion protection for outdoors. While the newly anodized surface differs in color and gloss from the originally applied color.
Research Approach:
The whole procedure contrasts with the principal approach in conservation which aims to intervene as less as possible, in case of the conservation of an object. To fulfill this approach in a more appropriate way the research project focuses on a mobile and partial application for colored, anodized aluminum parts.
To anodize aluminum the application of an electrolyte onto the surface together with sufficient voltage and current is necessary. Generally diluted sulfuric acid is used as electrolyte. Different possibilities are examined to enable the mobile application of the electrolyte, e. g. the application by producing a gel matrix or like in electroplating by pen or brush wrapped with a fleece fabric.
Experimental part:
First experiments are conducted to examine the structure of the anodized layer in relation with proper cleaning, anodization time with applied voltage and current and the coloring process. The aim was to reduce the preparation procedure and the anodization time as much as possible to facilitate the mobile application.
Examinations with Keyence microscope, Eddy current testing and REM are performed to characterize the layers. The results are shown in table 1. A clear connection between proper cleaning, anodization time, voltage and amperage and the achieved thickness of the anodized layer is significant. Cracks in the layer show that raising the voltage and amperage results in thicker layers but as well in a crumbled and less stable anodized surface.
Gel preparation:
In addition to the anodization process with a liquid e.g. sulfuric acid a gel application is tested to prevent the electrolyte from rinsing down during the mobile application. For this purpose, several gel-forming agents are tested together with their stability in acid systems. It was observed, that the consistency of the gels varies dependent of the time.
Conductivity:
The conductivity of sulfuric acid combined with different gel-systems was measured and compared in order to predict the possible growth of layers during anodic oxidation process.
Further steps:
Determination and optimization of application parameters like voltage, amperage and anodization-time to build up a preferably stable and sufficient thick anodized layer. Examination of gel preparation to guarantee a stable product, enforcing with textile tape for easy application.
Leachiing tests - a useful tool for the environmental impact assessment of construction products?
(2018)
Construction products and waste materials used for construction can be in contact with the environment and may release potential harmful compounds. Information on the total content of these substances in the product is not sufficient to assess its envrionmental impact since it does not consider realistic exposure conditions.The impact of these compounds is often assessed by using the total content in the product. This estimation lacks realistic exposure conditions.
Concerning the pathway to soil and groundwater by contact with rain or seepage water leaching tests, which were developed and standardized by the European Committee for Standardization, are available. While for secondary construction products and waste this investigation of the leaching behaviour is standard procedure and is already part of regulation in Germany (draft ordinance on reuse of mineral waste) and within Europe (landfill directive) the release from primary construction products got in the focus more recently. Several monitoring studies found unexpected high concentrations of substances used as herbicides and fungicides in surface water and stormwater originating from urban areas. As some of these compounds are even banned for the use in agricultural applications in Europe alternative sources as roof materials and façade coatings exposed to rain were suggested. Further field and laboratory tests confirmed construction products as sources of these substances in water.
The aim of this presentation is to show exemplary results of existing leaching methods and underline the strength and weaknesses of the test system with selected examples from our work. We especially draw the attention to the research which is still needed to close the gap between the results of leaching experiments and the subsequent risk assessment of the products.
The presentation gives an overview about the use of ecotoxicity testing in assessment of waste. Especially in cases with unknown composition this kind of test are useful. Recently, the assessment of the hazard property HP 14 "ecotoxicity" for the labelling of waste was published. The labelling procedure is explained in detail.
Die BAM wurde 2009 u. a. mit der Zulassung von Bewehrungsgittern für den Deponiebau beauftragt. Der Stand von Wissenschaft und Technik bot jedoch keine ausreichende Grundlage, die tatsächlich relevanten Widerstände und die mit diesen Widerständen verbundene Wechselwirkung zwischen Gitter und Boden im Hinblick auf eine mindestens 100-jährige Funktionsdauer realistisch beurteilen zu können. Es wurde daher nur eine vorläufige Zulassungsrichtlinie für diese Produkte erarbeitet. In der Zwischenzeit hat sich ein neuer Kenntnisstand ergeben. Vor diesem Hintergrund hat die AG (Arbeitsgruppe) Geogitter des Fachbeirats der BAM am 26.09.2017 getagt. Es sollen die aktuellen Erkenntnisse und Schlussfolgerungen für die Zulassung in Kürze vorgestellt werden. Die entsprechenden Kapitel beruhen dabei auf einem Arbeitspapier von W.W. Müller und dem Autoren, das der Arbeitsgruppe zur Diskussion vorgelegt wurde.
Weiterhin soll über Entwicklungen in Zusammenhang mit Kunststoffdichtungsbahnen (KDB) berichtet werden. Die Anforderungen an die Schweißzusätze für das Extrusionsschweißen wurden angepasst. Zudem soll über die aktuelle Diskussion der Schweißbarkeit unterschiedlicher HDPE Materialien informiert werden. Die maßgebliche DVS (Deutscher Verband für Schweißen und verwandte Verfahren) Richtlinie 2225-4 wird derzeit offenbar so ausgelegt, dass Materialien mit völlig unterschiedlichen Schmelze-Massefließrate miteinander verbunden werden können. Dies steht allerdings im grundlegenden Widerspruch zum Stand der Technik.
Die BAM wurde 2009 u. a. mit der Zulassung von Bewehrungsgittern für den Deponiebau beauftragt. Der Stand von Wissenschaft und Technik bot jedoch keine ausreichende Grundlage, die tatsächlich relevanten Widerstände und die mit diesen Widerständen verbundene Wechselwirkung zwischen Gitter und Boden im Hinblick auf eine mindestens 100-jährige Funktionsdauer realistisch beurteilen zu können. Es wurde daher nur eine vorläufige Zulassungsrichtlinie für diese Produkte erarbeitet. In der Zwischenzeit hat sich ein neuer Kenntnisstand ergeben. Vor diesem Hintergrund hat die AG (Arbeitsgruppe) Geogitter des Fachbeirats der BAM am 26.09.2017 getagt. Es sollen die aktuellen Erkenntnisse und Schlussfolgerungen für die Zulassung in Kürze vorgestellt werden. Die entsprechenden Kapitel beruhen dabei auf einem Arbeitspapier von W.W. Müller und dem Autoren, das der Arbeitsgruppe zur Diskussion vorgelegt wurde.
Weiterhin soll über Entwicklungen in Zusammenhang mit Kunststoffdichtungsbahnen (KDB) berichtet werden. Die Anforderungen an die Schweißzusätze für das Extrusionsschweißen wurden angepasst. Zudem soll über die aktuelle Diskussion der Schweißbarkeit unterschiedlicher HDPE Materialien informiert werden. Die maßgebliche DVS (Deutscher Verband für Schweißen und verwandte Verfahren) Richtlinie 2225-4 wird derzeit offenbar so ausgelegt, dass Materialien mit völlig unterschiedlichen Schmelze-Massefließrate miteinander verbunden werden können. Dies steht allerdings im grundlegenden Widerspruch zum Stand der Technik.
The presentation gives an overview about the use of ecotoxicity testing in assessment of waste. Especially in cases with unknown composition this kind of test are useful. Recently, the assessment of the hazard property HP 14 "ecotoxicity" for the labelling of waste was published. The labelling procedure is explained in detail.
The presentation gives an overview about the use of ecotoxicity testing in assessment of waste. Especially in cases with unknown composition this kind of test are useful. Recently, the assessment of the hazard property HP 14 "ecotoxicity" for the labelling of waste was published. The labelling procedure is explained in detail.
LD-Schlacken weisen eine große chemische Ähnlichkeit zu Protlandzementklinker auf. Sie enthalten jedoch noch bis zu 30% Eisen, das mineralisch in oxidischer Form gebunden vorliegt. Dadurch kann sich bei der Erstarrung die wichtigste Klinkerphase "Alit" nicht ausbilden.
Durch eine reduzierende Schmelzbehandlung der Schlacke kann des mineralisch gebundene Eisen als Metall separiert werden. Dadurch wird auch die Mineralogie der Schlacke so verändert, dass auch sie nun praktisch einem Portlandzementklinker entspricht.
Entsprechende Versuche wurden am kleintechnischen Lichtbogenofen der BAM durchgeführt. Es werden Ergebnisse vorgestellt und auf Grenzen und Möglichkeiten eines derartigen Prozesses im Hinblick auf eine industrielle Umsetzung eingegangen.
Derzeit gibt es intensive Diskussionen über die Entlassung von Deponien aus der Nachsorgephase. Die Deponie müsste dafür nach der Deponieverordnung (DepV) u. a. „insgesamt dauerhaft standsicher" sein. Geokunststoffe erfüllten ihre Funktion über einen Zeitrahmen von lediglich mindestens hundert Jahren. Dies stehe somit im Widerspruch wird argumentiert. Das neue LANUV-Arbeitsblatt 33 schließt daher im Moment eine Entlassung aus der Nachsorge von Deponien faktisch aus, wenn in den Böschungen Geokunststoffprodukte eingesetzt wurden. Auch der Fachbeirat der BAM zur Zulassung von Geokunststoffen, Polymeren und Dichtungskontrollsystemen hat sich daher mit der Thematik beschäftigt. Die aktuelle Situation soll daher auf dieser Grundlage diskutiert werden.
Zu den unerwünschten Gästen im Museum oder im Haushalt gehört zweifelsohne die Kleidermotte Tineola bisselliella. Es sind die Larven dieses Kleinschmetterlings, die die Schäden verursachen. Neben der konventionellen Schadensabwehr besteht die Möglichkeit, Schlupfwespen zur Bekämpfung der Larven einzusetzen. Der Vortrag rekonstruiert die Natur- und Kulturgeschichte der Kleidermotte anhand ökologischer Studien und historischen Indizien.
Second occurrence of aberrant antenna in house longhorn beetle Hylotrupes bajulus (Coleoptera: Cerambycidae) in the F3 generation. In 2016, the house longhorn beetle (Hylotrupes bajulus) breeding culture of the Federal Institute for Materials Research and Testing (BAM) in Berlin produced a second female beetle with a unique malformed right antenna similar to the one previously reported. As in the first case the flagellum following the pedical was bifurcated. This time, however, both branches were of similar length with 7 and 8 flagellomeres, respectively. The left antenna was normally developed with 11 antennal segments (scape, pedicel and 9 flagellomeres). This second female stands as F3-generation in direct maternal line to the previous one. A heritable cause for the malformation is likely.
Rare occurrences of termites in Germany. Termites are typical elements of the tropical and subtropical insect fauna. In Europe, their most northern natural range is southern France, Italy and the South-Balkan region. Only occasionally are termites found in Germany. Their occurrence is always very closely associated with the synanthropic environment. Drywood termites like Cryptotermes brevis or Kalotermis flavicollis were accidentally imported with furniture, wooden artefacts or plant material into homes or indoor arboretums. Similar pathways of termite introduction are described for Coptotermes gestroi and Reticulitermes sp. into tropical botanical gardens and tropical theme parks. Although termites were introduced to Germany several times, successful spreading or long term establishment never occurred due to climatic barriers, namely cold winter temperatures. Only Reticulitermes flavipes formed sustainable colonies in the city of Hamburg for several decades. Originating from the eastern United States of America, this species was introduced in the 1930s with infested wood through the sea port. Small subterranean colonies could survive the winter in areas where pipes of the central heating system kept the ground from freezing. Control efforts of this potentially invasive species of economic importance started early on but failed until modern bait techniques were applied in the year 2000. Currently, termites have not been detected in Hamburg for the last five years.
Ausgewählte Ergebnisse des UBA-Vorhabens "Beregnete Bauteile und Bauprodukte: Entwicklungen für Vergabegrundlagen für den Blauen Engel mit Hilfe von Auslaugtest" werden für organische und anorganische Analyten präsentiert. Ein Schwerpunkt ist den Einfluss der verschiedenen Schichten von WDVS-Systemen aufzuzeigen.
Sintered bioactive glass scaffolds of defined shape and porosity, e.g. made via additive manufacturing, must provide sufficient bioactivity and sinterability. As higher bioactivity is often linked to high corrosion and crystallization tendency, a certain compromise between sintering ability and bioactivity is therefore required. Groh et al. developed a fluoride-containing bioactive glass (F3), which allows fiber drawing and shows a bioactivity well comparable to that of Bioglass®45S5.
To study whether and to what extent the sinterability of F3 glass powder is controlled by particle size, coarse and fine F3 glass powders (300-310µm and 0-32µm) were prepared by crushing, sieving and milling. Sintering, degassing and phase transformation during heating were studied with heating microscopy, vacuum hot extraction (VHE), DTA, XRD, and SEM.
For the coarse glass powder, sintering proceeds slowly and is limited by surface crystallization of primary Na2CaSi2O6 crystals. Although the crystallization onset of Na2CaSi2O6 is shifted to lower temperature, full densification is attained for the fine powder. This finding indicate that certain porosity might be tuned via particle size variation. Above 900°C, intensive foaming is evident for the fine powder. VHE studies revealed that carbon species are the main foaming source.
Two new approaches towards an emission reference material for use in quality assurance measures for materials emissions testing were developed and intensively tested. The overall goal was to obtain solid materials with homogenous and reproducible (S)VOC release. Since the application in inter-laboratory comparisons is aimed at, it should furthermore be long-term stable to ensure safe shipment to the customer without sustaining compound losses. In the first approach, thermoplastic polyurethane (TPU) was impregnated with the VOC texanol under high-pressure with liquid CO2 as solvent. In the second, styrene (VOC) and the SVOC 2,6-diisopropylnaphthalene (DIPN) were spiked into vacuum grease (VG) and a mixture of paraf-fin/squalane (P/S). For the prediction of the emission rates a finite element model (FEM) was developed for the VG and P/S type materials. All requirements for reference materials were fulfilled, whereas the TPU samples need to be aged for about 10 days until repeatable and reproducible emission rates were obtained.
Die Präsentation erläutert die Hintergründe der nationalen Anforderungen für die Verwendung von Kunststoffdichtungbahnen in Deponieabdichtungen. Die Beständigkeit wird diskutiert. Anforderungen an das Qualitatsmanagement während der Produktion der Produkte und der Bauphase werden aufgezeigt und die Auswirkungen auf die langzeitige Funktionserfüllung werden beschrieben.
The properties of nanomaterials are influenced not only by their chemical composition but also by physical properties (such as size, geometry and crystal structure). For the reliable determination and assessment of behaviour and effects of nanomaterials as well as for the determination of the exposure of humans and environment a comprehensive physical-chemical characterization of nanomaterials is essential. This is an important prerequisite to identify them as nanomaterials and to interpret and compare test results and - in future – to forecast interaction and effects of nanomaterials.
In 2006, the OECD launched a sponsorship program for the testing of nanomaterials in which 11 nanomaterials were thoroughly investigated using a variety of methods. The aim of the project was, among other things, to find out where problems occur and where there are gaps in the measurement and test procedures and where are changes required. An important outcome of the sponsorship program was the finding that the OECD Test Guidelines should in several cases be extended to the specific needs in testing of nanomaterials. The existing standardized test methods of the OECD for physical-chemical characterization have not been developed for nanomaterials in particular. A high demand for an extension of the test guidelines was identified. Germany complied with the OECD's request in 2017 and has agreed to extend the “Test Guideline on Particle Size Distribution / Fiber Length and Diameter Distributions Test Guideline” for Manufactured Nanomaterials (MN). UBA commissioned BAM and BAuA with the preparation of the Test Guideline. The aim of the project is the development of a harmonized test protocol for a valid and reproducible determination of particle size and size distribution which is one of the most relevant physical-chemical properties for MNs.
Different measuring methods provide different results for the size distribution of the particles. This is caused by the different measuring principles of the methods. Each method measures a specific parameter that ultimately determines particle size. First, the measured quantity differs for each method (Scattered light intensity, 2D image / projection, electric mobility, etc.). Second, the calculated diameters of the MN may differ (Feret Diameter, Area Projection, Mobility Diameter, Aerodynamic Diameter, Hydrodynamic Diameter). Third, a measuring method provides a size distribution which is measured either mass-based, surface-based or number-based. A conversion between the results requires additional parameters and thus possibly increases the measurement error.
In addition to the technical differences, the individual parameters are strongly influenced by the structure and material of the nanoparticles. For example, a surface functionalization can lead to very different results in the size distribution. The suitability of measurement methods differs with the material of the MN. As a result, two very different results can be measured for the particle size distribution using two different methods, which are nevertheless both correct. Several large projects in recent years therefore concluded that nanomaterials should be characterized by at least two complementary method. Imaging techniques are regarded as one of these methods for the characterization, the complementary methods are supposed to be statistical methods.
The different results for the size distribution of nanomaterials become problematic for the registration of new MN. A comparable and reproducible size distribution is a prerequisite for a standardized registration. In the future, the particle size distribution in the EU will also decide on the classification of a substance as a nanomaterial or as a non-nanomaterial. Especially in borderline cases, a standardized and comparable measurement methodology is therefore essential.
The new OECD test guideline will address the following four main steps in the determination of the length and width distributions of fibers: sample preparation, image acquisition, data evaluation and uncertainty analysis. As the sample preparation has to be optimized for each material, general quality criteria will be given in the protocol. For full visibility of a fiber the appropriate resolution has to be chosen. In the data evaluation the length and diameter of each fiber will be determined concurrently to allow for application of different regulatory definitions. The quality of the results critically depends on the sample preparation as well as the data evaluation. In this step the classification rules have to be formulated and followed accurately in order to optimize reproducibility of the method. The SOP will be validated in an international round robin test, which is planned for 2018/2019.
The OECD test guidelines (TGs) for testing chemicals have been widely used for regulatory purposes all over the world since the establishment of the Mutual Acceptance of Data (MAD) principle in 1984. This MAD principle ensures that, if a chemical is tested under the Good Laboratory Practice (GLP) conditions accordingly to an OECD TG, the data should be accepted in all OECD countries. The TGs have been developed, harmonized, internationally validated (round robin tests) and adopted by OECD countries to be used for the physical-chemical characterisation, fate estimation, and hazard identification for risk assessment of various chemicals. In addition to the TGs, OECD Guidance Documents (GDs) usually provide guidance on how to use TGs and how to interpret the results. These GDs do not have to be fully experimentally validated, and hence they are not under MAD, but they are based on relevant published scientific research.
But are the existing TGs and the related GDs applicable and adequate for the regulatory testing of nanomaterials? In general, it is accepted that most of the "endpoints" or more precisely measurement variables are applicable also for nanomaterials. However, for some endpoints new or amended TGs are needed. In addition, several GDs are needed to give more precise advice on the test performance in order to gain regulatory relevant data on nanomaterials.
The poster will present the status quo on recent TGs and GDs development for nanomaterials at OECD level with relevance for physical-chemical characterisation. Emphasis will be given to the proposed OECD TG on particle size and size distribution for manufactured nanomaterials. The development of such a TG is of special importance as particle size and size distribution is considered as major information for nanomaterial identification and characterization. A reliable and reproducible characterisation of particle size and size distribution is also needed for chemicals risk assessment of nanomaterials, for instance to interpret and compare test results and - in future – to forecast interaction and effects of nanomaterials. The presented poster will illustrate the way from the idea for a new TG and new GD to an accepted OECD TG/GD.
Wastewater contains a diverse array of organic and inorganic compounds and its complex composition strongly depends on the location and the connected dischargers. However, municipal wastewater as a carrier of feces and urine generally contains considerable amounts of the main nutrients nitrogen and phosphorus. The latter is in the focus of the discussions about the recovery potential of wastewater due to the relatively high mass flows of phosphorus in wastewater and the finite nature and decreasing quality of phosphate rock reserves. But due to the presence of the whole periodic table of elements, wastewater might contain further valuable components of interest for recovery including those defined as critical raw materials by the European Commission. Phosphorus and most of the other critical raw materials are fixed in the sewage sludge and after incineration in the sewage sludge ash (SSA). This is accompanied by high concentration factors from wastewater via sludge to ash. However, the mass fractions of the majority of elements in sewage sludge are comparable to those of the earth crust, indicating no relative enrichment. Nevertheless, enrichment factors of 100 or higher are given for phosphorus, copper, zinc, cadmium, silver, tin, lead and the platinum group elements indicating an anthropogenic input. An economic value of sewage sludge was estimated to $460,-/t calculated on the basis of the respective market prices for high purity elements – a theoretical value. A German survey of sewage sludge ashes showed that the mass fractions and the mass flows of most of the elements present in SSA are probably too low for an economic recovery. In most cases the mass flows are rather small compared to the imports and the chemical forms are not suitable for recovery. An exception is phosphorus that is present in high mass fractions up to 13% and that bears a high substitution potential. If the application of P-recovery technologies lead to a further concentration of valuable elements e.g. as by-products in side streams of the process, it would probably make also the recovery of other elements of economic interest.
This paper reports the outcome of an interdisciplinary team’s application of multispectral imaging techniques and material analysis to a music fragment from the first decades of the fifteenth century: Atri, Archivio Capitolare, Museo della Basilica Cattedrale, Biblioteca del Capitolo della Cattedrale, Frammento 17. This important parchment leaf has rarely been investigated since its discovery 45 years ago. Thanks to the applied techniques and methods (such as the evaluation of the data using the fingerprint model), it is now possible to discuss new evidence supporting conclusions regarding the fragment’s origin and afterlife.
Microbially influenced corrosion (MIC) of iron is usually attributed to sulfate-reducing microorganisms (SRM) which act upon the metal by the reactiveness of hydrogen sulfide, and by withdrawal of the available electrons (Fe → Fe²⁺ + 2e⁻ ; E° = 0.47 V) in electrical contact through surface attachment. Also methanogenic archaea are supposed to cause MIC. Because they do not produce hydrogen sulfide, withdrawal of electrons may be their main corrosive mechanism; however, mechanistic details and kinetics of the overall process are poorly understood. Precipitation of siderite (4Fe + 5HCO₃⁻ + 5H⁺ → 4FeCO₃ + CH₄ + 3H₂O) can lead to an insulating layer on the metal surface and lower the corrosion rate. Still, the extent of FeCO₃ precipitation may be significantly influenced by environmental conditions such as pH and advective processes.
To investigate the corrosive potential of methanogens, we studied strains isolated from marine sediments (Methanococcus maripaludis 14266, 2067, Methanobacterium-affiliated strain IM1), crude oil tanks (Methanococcus maripaludis Mic1c10, KA1) and the oral cavity (Methanobrevibacter oralis) in a closed (batch) culture, and in a sand-packed flow-through cell with pH control and simulation of a fluctuating environment. Results indicate that the rates of iron corrosion due to coupled methanogenesis (up to 0.3 mm/yr) are comparable to that caused by SRM. Surface analyses of the metal showed severe pitting. Such knowledge and deeper understanding also from an electrokinetic point of view may not only provide further models in microbial electrophysiology, but also contribute to mitigation strategies in MIC.
Anoxische Objektbehandlungen gegen Schädlingsbefall stellen eine besonders materialverträgliche und umweltschonende Alternative zu chemischen Bekämpfungsverfahren dar. Die Wirksamkeit hängt jedoch von der Dauer, dem Restsauerstoffgehalt sowie der Temperatur und Feuchtigkeit ab. Unterschiedliche Arten von Schadinsekten sind verschieden tolerant gegenüber sauerstoffarmen Bedingungen. Insbesondere bei Behandlungsbedingungen von unter 24° C und mehr als 0,5 % Restsauerstoffgehalt stößt das Verfahren an die Grenze der Zuverlässigkeit. In Versuchsreihen unter standardisierten Bedingungen erwiesen sich insgesamt 12 von 34 im Projekt untersuchte Insektenarten hierbei als widerstandsfähig. Davon als besonders tolerante Arten sind Hylotrupes bajulus, Lasioderma serricorne, Trogoderma parabile und Mezium affine zu nennen.
Mit dem entwickelten UWB-Sensoriksystem können durch elektromagnetische Wellen Bewegungen von Schädlingen innerhalb geschlossener Holzobjekte berührungslos erfasst werden. Voraussetzung für die eindeutige Detektion der Schädlingsaktivität ist neben der digitalen Signalverarbeitung zur Filterung und Extraktion des Nutzsignals, die genügend hohe Eindringtiefe, die ausreichend ist, wenn Schädlingsvorkommen häufig dicht unter der Holzoberfläche gelegen sind. Die Versuchsergebnisse haben gezeigt, dass bereits eine einzelne Trockenholztermite der Art Incisitermes marginipennis hinter einer 5 cm dicken Holzplatte aufgespürt werden kann. Somit erscheint das Messsystem potentiell für die Erfolgskontrolle einer Anoxia-Behandlung an Museumsgütern geeignet.
Today glass is broadly used in modern architecture. For applications indoor it is possible to produce decor glass by using enamel colors and glass painting techniques without any problems. However, this is more limited for applications outdoor. Humidity and environmental pollution attack the surface of the coating and damage it strongly. There are only few colors on the market which are resistant towards acids and bases until now. Additionally, most of those colors are opaque. In order to extend the color palette, chemically resistant colored glasses are being developed which are transparent, relatively low melting and intensively toned even in thin coat thickness. To achieve such ambitious aim, many parameters have to match which act in complex manner. Metal oxides were used to color the glasses. A lead-free glass composition was developed to avoid an exposition of heavy metals to the environment. The glasses were characterized, in particular in terms of their thermal properties, their crystallization and corrosion behavior as well as their chemical and environmental durability. Different practical applications will be shown.
Fluorometric sensing is a versatile approach for trace analysis outside of the laboratory, requiring suitable sensor materials and their integration into sensing devices. The versatility of fluorophores as probes, especially in terms of the possibility to tailor their optical as well as their recognition properties by synthetic modifications in a wide range, renders them as superior active component for the preparation of optical sensing devices. Recent works at BAM in this field include, for example, the detection of nerve gas agents, illustrating impressively the aforementioned benefits of fluorophores in optical sensing applications.
In the interdisciplinary project presented here, we target hazardous gases such as ammonia, benzene, and hydrogen sulfide, next to others, which pose a major threat to human health and environmental safety and for which the availability of a sensitive and reliable detection method is highly desirable. The dyes presented follow a “turn-on” fluorescence schematic, which allows for the selective and sensitive detection of the respective gaseous analyte. The immobilization of the probe in polymeric matrices is then the next step toward the fabrication of a prototype device for molecular sensing. Further steps in the project include the assembly of instruments for test-atmosphere generation, the referencing of the sensor system, development and implementation of an optical setup, and the testing of the prototype device under laboratory conditions and in the field.
In this presentation, we give an overview over the recent developments on this topic in our groups. Highlights are hydrogen sulfide sensitive, BODIPY based transition metal complexes, which allow for a sensitive as well as selective detection of the toxic gas. In addition, we present a novel class of highly substituted BODIPY derivatives – pocket-BODIPYs – which are of a synthetically high versatility and can readily be modified to create pockets in the periphery of the molecule of defined geometries. This is illustrated on the successful encapsulation of benzene by a pocket-BODIPY derivative, confirmed by X-ray crystallographic analysis as well as by further spectroscopic and analytical methods.
There is a need for an assessment of the emission properties of volatile organic compounds (VOCs) from consumer products. A method comparison was carried out to evaluate adapted and cost-effective procedures for such items. Smaller and automated emission chambers depicted similar kinetics compared to a 203 L standard chamber. Toy samples made of PVC (Polyvinyl chloride) emitted more VOCs compared to other tested polymeric products. The emissions from 2 selected samples were studied to allow an evaluation of the resulting room concentration and external exposure of a child. Obtained concentrations were not of concern.
Eine entscheidende Problematik nach Inkrafttreten der neuen
Klärschlammverordnung ist, wie Phosphor nicht nur rückgewonnen,
sondern in den Markt eingeschleust und letztlich auch
in den Kreislauf zurückgeführt werden kann. Die Wege hierzu
sind noch weitgehend ungeklärt. Die DWA-Arbeitsgruppe KEK-
1.1 hat aus diesem Grund einen Workshop durchgeführt, um
rechtliche Anforderungen an Rezyklate, Aspekte der Rezyklatqualität
und -beschaffenheit sowie den aktuellen Markt für Rezyklate
zu diskutieren. Auf Basis dieses Workshops wurde ein
Arbeitsbericht erstellt, der sich schwerpunktmäßig mit dem Einsatz
von Rezyklaten zu Düngezwecken beschäftigt. Hierzu liegen
bereits Erkenntnisse vor, und es sind bereits Praxisbeispiele in
der Umsetzung.
The manuscript Codex germanicus 1 (Cod. germ. 1) of the Staats- und Universitätsbibliothek Hamburg is a fifteenth-century German-language manuscript. It comprises two codicological units and has an especially complex developmental history. To trace this developmental history, neglected until now in the research literature, the manuscript was investigated, for the first time not solely with classical codicological and palaeographical methods, but also with the aid of X-ray fluorescence spectroscopy, in order to determine the composition of the writing materials. These methods made it possible, first, to support and check palaeographic findings and, second, to gain information about the stratigraphy of the manuscript where palaeographic methods find their limits – in regard to short entries, rubrications, and non-alphabetical signs.
Advanced codicological studies of Cod. germ. 6 (Hamburg, Staats- und Universitätsbibliothek): Part 2
(2018)
The work presented here follows the article Combining Codicology and X-Ray Spectrometry to Unveil the History of Production of Codex germanicus 6 (Staats- und Universitätsbibliothek Hamburg), published in 2014.1 It confirms the main result of the previous article: the Artusnotiz, the fourth text in the bound manuscript, must have been introduced as the last one. This paper offers further details of the codex production, based on the composition of the black and red inks collected in four measurement campaigns. Furthermore, using imaging μ-XRF, we succeeded in understanding the strong variation of the composition of the red inks in the initials of all the texts except for Parzival and Jeanne d’Arc.
It is well documented that throughout Antiquity, ancient Egyptians used mostly carbon inks as a writing material. In Late Antiquity, some metals started to be added to carbon based inks. We have records of five manuscripts from the Dead Sea Scrolls collection whose carbon inks were found to contain copper Also, lead was recently found as an additive in carbon inks on a charred fragment from Herculaneum. Furthermore, the earliest evidence of iron-gall ink was found in the Book of Proverbs (Codex Ms. Berol. orient. oct. 987) dating to the third fourth centuries ce. It has been suggested that along with carbon and iron-gall inks, there is no reason to think that purely tannin inks were not also in use in Egypt. However, so far, we just have evidence of a copper-tannin ink identified in a number of documents from Egypt in the first third centuries bce. In an attempt to fill this gap in this extremely fragmented scenario during our studies of the socio-geographic history of inks, we arrived at the conclusion that the continuous production of Coptic manuscripts from Late Antiquity to the Middle Ages offers a unique opportunity for the historical study of inks across a large geographic area.
Comparison of Formaldehyde Concentrations in Emission Test Chambers Using EN 717-1 and EN 16516
(2018)
For many years EN 717-1 (Wood-based panels - Determination of formaldehyde release - Part 1: Formaldehyde emission by the chamber method) is the standard for formaldehyde emission testing of wooden boards. In 2017 EN 16516 (Construction products - Assessment of release of dangerous substances - Determination of emissions into indoor air) was published as a new harmonised standard for the emission testing of construction products. Because test chamber conditions are different, both standards give different concentrations for formaldehyde. For the determination of a conversion factor four test series were set up with different wooden boards.
We demonstrate a 2D platform based on high contrast wetting patterns suitable for miniaturized microbiological assays.
In principal, superhydrophilic spots are surrounded by a superhydrophobic surface area. The special structure of the superhydrophilic functional surface ensures that liquids, e.g. bacterial suspensions or biocide solutions, spread immediately and evenly on this surface without passing the wetting boundary. This feature allows a homogenous distribution of bacteria or chemical substances on well defined lateral dimensions. The superhydrophilic spots may also serve as substrate for bacterial biofilms. Due to the high wetting contrast and the fabrication process, it is possible to minimize the test areas as well as their distance to each other.
We demonstrate the fabrication process of the high wetting contrast platform and also present a microbiological assay as an application example. Advantages of this platform are the use of low volumes and its potential of automated analysis.
Microbiologically influence corrosion (MIC) has become a big concern due the increased usage of different metals by our society. Microorganisms can use metal as an electron donor, causing unpredictable but serious damages. Nowadays it is known that besides sulfate reducing bacteria (SRB), other microorganisms including acetogens, iron oxidizers and methanogens can also induce MIC. Current studies related to methanogen-induced MIC (MI-MIC) mainly focused on environmental isolates from the oil and gas industry (e.g. Methanococcus maripaludis) with industrial materials e.g. iron. However, MI-MIC can occur in many other environments as well, including the oral cavity. Methanobrevibacter oralis is a methanogen isolated from the human oral cavity and was found more frequently in patients suffering from peri-implantitis/periodontitis. Titanium-implants removed from those patients have also showed clear signs of corrosion. The aim of our study is to establish and analyze corrosion potentials of dental metals (e.g. titanium) by oral methanogens. Periodontal pockets samples from patients suffering from periodontitis/peri-implantitis were taken for methanogenic and SRB enrichments. Stainless steel, pure titanium or Ti-6Al-4V alloy was used for corrosion studies. Corrosion rates and methane production were measured using weight-loss method and gas chromatography, respectively. Metal surfaces were visualized with scanning electron microscopy. Microbial communities in the dental pockets of healthy people and patients will be compared using 16S rRNA amplicon sequencing. Overall, this is the first study investigating the susceptibility of different dental implant materials to corrosion using human-related Archaea. The outcomes of this study can be further explored for a variety of clinical applications.
The first documentation of fuel biodeterioration dates back to the late 19th century. However, extensive studies concerning the microbial fuel contamination started in 1980’s. Polymeric fuel storage tanks containing diesel and biodiesel provide environmental conditions for microbial growth. Several studies demonstrated that bacteria, which were found in contaminated fuel systems, can use fuels as macronutrient; but such bacteria can also cause microbiologically influenced corrosion and fouling.
The aim of this study is to investigate the initial attachment behavior of bacteria, isolated from a diesel contamination, on neat and photooxidized high-density polyethylene (PE-HD). Two common PE-HD’s, less- and biodiesel-stabilized, were radiated to UV light representing a tank exposed to sunlight. The effect of photooxidiation on PE-HD’s surface were characterized chemically by Fourier-transform infrared spectroscopy (FTIR). The attached bacteria Pseudomonas aeruginosa and Bacillus subtilis on the polymer surface were evaluated by fluorescence microscopy and colony-forming unit tests (CFU).
In Vorbereitung einer Restaurierung erfolgten naturwissenschaftliche Untersuchungen zu Schadensphänomenen und Glaszusammensetzungen an mittelalterlichen Gläsern aus der Dorfkirche in Koszewko (Polen)im Environmental Scanning Electron Microscope (ESEM) mit EDX. Die Ergebnisse zeigen, dass die Glasverwitterung schon sehr stark vorangeschritten ist und ein zukünftiger Schutz der mittelalterlichen Glasmalereifelder vor Umwelteinflüssen unbedingt notwendig ist. Es wurde ein Schutzverglasungsystem entwickelt, das speziell auf den langfristigen Erhalt der einzelnen mittelalterlichen Glasmalereifelder ausgelegt ist.
The SCALE Project is a Horizon2020 Project (GA°730105) that aims to develope a secure supply chain for Scandium in Europe. To achieve that, the whole value chain is investigated and new methodologies and techniques are being developed. In BAM we are characterizing potential Scandium-bearing industrial by-products.
Im Zusammenhang mit dem Horizon2020 geförderten Projekt SCALE (GA°730105) untersuchen wir an der BAM die Scandium Spezies in industriellen Restsoffen wie zum Beispiel Rotschlamm. Dabei kommen Methoden wie Elektronenmikroskopie, LA-ICP-MS und auch X-ray Adsorption near edge structure an Synchrotron-Lichtquellen zum Einsatz. Das Verständnis der Bindungsformen des Scandiums soll im Weiteren helfen, metallurgische Gewinnungsmethoden zu verbessern und anzupassen.
The characteristics of different molecules chosen as representatives for specific functionalities in conditioning layers play an important role on attachment behavior and later biofilm formation of bacteria. The chemical composition is a major component influencing the attachment but there is a conglomerate of influences.
The technique of painting on the reverse side of a glass panel was rediscovered by German artists at the beginning of the 20th century. In contrast to other paint techniques (e.g. panel and mural painting), the paint layers are applied in reverse succession starting with the foremost paint layer and ending with the primer (backmost layer). The paintings are viewed in reflected light, thus revealing an impressive gloss, luminosity and depth of colour. The artist group “Der Blaue Reiter” (the Blue Rider) around W. Kandinsky and F. Marc got in touch with this technique in the summers of 1908 and 1909 and spread their knowledge in different regions. Our pioneering project is tracing this transfer of knowledge by a multidisciplinary approach in terms of art history, painting technology and material science. More than 100 artists and >1000 reverse paintings on glass (1905-1955) were identified during the project. This numbers clearly point out that this technique was by far more important for modern art than previously assumed. In-situ, non-invasive measurements (XRF, Raman, VIS, DRIFTS) on a well-considered selection of 67 paintings reveal the broad palette of colorants ranging from traditional to experimental materials. Special attention is paid on artists who are strongly connected to Berlin. Demonstrative examples by W. Dexel, G. Muche and L. Hildebrandt are used to discuss analytical challenges and highlights.
Carbonfaser verstärkte Kunststoffe (CFK) sind aus dem Leichtbau nicht mehr wegzudenken. Da die Produktion der Fasern viel Energie benötigt ist deren Recycling anzustreben. Durch Bearbeitung und Handling während des Recyclings verkürzen sich die Carbonfasern (CF) analog zur Papierfaser. Zu kurze Fasern können nicht mehr in eine Flächenstruktur eingebracht werden und müssen daher aus dem Kreislauf ausgeschleust und einer Verwertung zugeführt werden. Untersuchungen des Lehr- und Forschungsgebiets Technologie der Energierohstoffe (TEER) der RWTH Aachen University haben gezeigt, dass die Bedingungen für eine energetische Nutzung von CF-Abfällen in Abfallverbrennungsanlagen nicht geeignet sind. Zudem können CF Betriebsprobleme verursachen. Des Weiteren können bei einer unzureichenden thermischen Behandlung sogenannte WHO-Fasern entstehen, die als gesundheitsschädlich einzustufen sind. Eine Alternative können Hochtemperaturverfahren mit höheren Verweilzeiten sein. Es kommt die Herstellung von Calciumcarbid in Frage, bei der CF als Kohlenstoffträger und der Kunststoff als Energieträger genutzt werden. Eine weitere Verwertungsoption stellt die Stahlproduktionsroute dar. Erste Untersuchungen der Bundesanstalt für Materialforschung und -prüfung (BAM) und TEER am kleintechnischen Lichtbogen der BAM zeigen, dass CF-Abfälle potentiell als Reduktionsmittel und Energieträger eingesetzt werden können.
The Cairo Geniza is an “archive” discovered in the 19th century in Ben Ezra Synagogue in Fustat, a district in Old Cairo (Egypt), located south of the center of modern Cairo. The giant collection of mostly Jewish documents that vary in genres, languages and writing supports contains a large number of early medieval Hebrew manuscripts, mostly in fragmentary form. The larger part of the Cairo Geniza is stored today in the Cambridge University Library (CUL).
The Geniza provides sources for the literary, linguistic, historical studies of the various aspects Jewish life. As the documents attest, at least two Jewish communities co-existed in Fustat up to 11th century: a so-called Babylonian and Palestinian. These communities had different leaders, different traditions and lived independently. The differences seem to manifest themselves also in the paleographical, codicological and some material properties of the manuscripts produced by each community.
The aim of this project is to compare the inks used in the Jewish documents depending on different variables: support (paper, parchment), purpose of the manuscript (legal, private, religious), provenance of the scribe. For the determination of the inks type and composition we had to choose non-invasive, non-destructive and portable techniques to analyse the corpus directly in the CUL.
The analyses were carried out with a mobile energy dispersive micro-X-ray spectrometer ArtTAX® (Bruker GmbH, Berlin, Germany), which consists of an air-cooled, low-power molybdenum tube, polycapillary X-ray optics (measuring spot size 70 µm in diameter), an electrothermally cooled Xflash detector, and a CCD camera for sample positioning (Bronk et al 2001, Hahn et al. 2010). All measurements are executed using a 30 W low-power Mo tube, 50 kV, 600 µA Mo tube, and with an acquisition time of 15 s (live time) to minimize the risk of damage (Fig. 1, 2).
Fig. 1: XRF spectrometer probe above a manuscript fragment
Fig. 2: Typical element profile of a XRF linescan
The Dino Lite digital stereomicroscope (Fig. 3) features built-in LED illumination at 395 nm and 940 nm and a customized external white light source. During use, the microscope is fastened to a small tripod or mounted on a Plexiglas ring holder that incorporates a white light source.
Fig. 3: Dino Lite digital stereomicroscope
Fig. 4: Details of one fragment (T-S 16.124) observed with the Dino microscope (x20). On the left, when illuminated with NIR (Near-Infrared, 940 nm) light, the ink fades, indicating iron-gall ink. On the right, the image under NIR light does not change. It is carbon ink.
On example of these studies is the manuscript T-S 16.124 (Cambridge University Library, Fig. 5) whom belongs to the third corpus. It is a deed, written in Hebrew, dated from 1328 (= 1017 CE) and witnessed by a very high number of people (6) comparing to the standard of similar documents (between 2 and 3), from at least two different Jewish communities in Fustat (trans congregational). The verso is written in Arabic (Bareket 1999).
Fig. 5: Manuscript T-S 16.124 (Cambridge University Library)
To compare the inks, we used the fingerprint model. This method relies on the determination of characteristic elemental compositions and represents the amount of a minor constituent relative to the main component, iron in iron gall ink (Malzer et al. 2004, Hahn et al. 2004, Rabin et al 2014). However, a calculation of a fingerprint based on XRF measurements is not possible in the case of carbon ink since carbon, its main component, cannot be detected with this technique.
Fig. 6: Ink fingerprint T-S 16-124 (recto) normalized to iron (Fe)
Conclusion
We show that using reflectography and XRF analysis it is possible to sort the inks according to their type. In the case of the iron-gall inks, use of the ink fingerprint, i.e. amount of the vitriol components normalized to iron we can make direct comparisons of the ink composition.
We would like also to stress that though the methods of material analysis listed above have been successfully employed in the field of cultural heritage and conservation including ancient and medieval manuscripts they have not yet been used to study fragments from the Cairo Genizah. Therefore, we believe that this research project is a pioneering study that will provide new insights into the history of Hebrew writing materials, their production techniques and materials and, thus, contribute new data to the field of Hebrew paleography.
This study focuses on the analysis of a corpus of manuscripts found in Fustat (medieval Cairo, Egypt) in the biggest medieval “archive” found until now: the Cairo Geniza. The giant collection of mostly Jewish documents has been attracting scholars’ attention a lot but so far, the material aspects of these documents seem to have been mainly neglected.
Application of scientific methods of analysis, especially X-Ray fluorescence characterization, contributes to our understanding of the materials used for production of manuscripts during the Middle ages.
Our corpus of the 11th century manuscripts comprises manuscripts written by scribes belonging to three Jewish communities that co-existed in Cairo during this period: the Karaites, the so-called Jerusalemites (or Palestinian) and the so-called Babylonians (or Iraqi), three different communities with different traditions and different leaders. The differences manifest themselves also in the paleographical properties of the manuscripts produced within each community. Can we extend the differences detected by the paleographical analysis to differences in composition of the writing materials and especially the composition of the inks? Or can we relate the differences in the composition to the manuscript type (legal, private...), or to another criterion. In this presentation, we offer answers to some of the questions using statistical analysis of the measurements results.
This study focuses on the analysis of a corpus of manuscripts found in Fustat (medieval Cairo, Egypt) in the biggest medieval “archive” found until now: the Cairo Geniza. The giant collection of mostly Jewish documents has been attracting scholars’ attention a lot but so far, the material aspects of these documents seem to have been mainly neglected.
Application of scientific methods of analysis, especially X-Ray fluorescence characterization, contributes to our understanding of the materials used for production of manuscripts during the Middle ages.
Our corpus of the 11th century manuscripts comprises manuscripts written by scribes belonging to three Jewish communities that co-existed in Cairo during this period: the Karaites, the so-called Jerusalemites (or Palestinian) and the so-called Babylonians (or Iraqi), three different communities with different traditions and different leaders. The differences manifest themselves also in the paleographical properties of the manuscripts produced within each community. Can we extend the differences detected by the paleographical analysis to differences in composition of the writing materials and especially the composition of the inks? Or can we relate the differences in the composition to the manuscript type (legal, private...), or to another criterion. In this presentation, we offer answers to some of the questions using statistical analysis of the measurements results.
The halophilic bacterium Halomonas elongata can tolerate salt concentrations above 10% NaCl and uses the accumulation of the compatible solute ectoine as a major osmoregulatory mechanism. Ectoine can be accumalted inside the cell through import from the medium or de novo synthesis and establishes an osmotic equilibrium with the surrounding1. Ectoine also protects proteins from the effects of freezing, drying and high temperatures4 and DNA from ionizing radiation2. These features make ectoine a valuable compound for cosmetics and medical devices.
H. elongata was originally isolated from a solar salt facility, where it thrives under high salt concentrations. It was found that marine prokaryotes, which are exposed to high oxidative stress in their environment, vary glycolytic strategies5. A variation in the use of the glucose metabolic pathways is also assumed for H. elongata.
The halophilic bacterium Halomonas elongata can tolerate salt concentrations above 10% NaCl and uses the accumulation of the compatible solute ectoine as a major osmoregulatory mechanism. Ectoine can be accumalted inside the cell through import from the medium or de novo synthesis and establishes an osmotic equilibrium with the surrounding1. Ectoine also protects proteins from the effects of freezing, drying and high temperatures4 and DNA from ionizing radiation2. These features make ectoine a valuable compound for cosmetics and medical devices.
H. elongata was originally isolated from a solar salt facility, where it thrives under high salt concentrations. It was found that marine prokaryotes, which are exposed to high oxidative stress in their environment, vary glycolytic strategies5. A variation in the use of the glucose metabolic pathways is also assumed for H. elongata.
While studying the socio-geographic history of inks, division 4.5 of the BAM (Bundesanstalt für Materialforschung und Prüfung) together with the Centre for the Study of Manuscript Cultures in Hamburg has developed a protocol for ink analysis. It consists of a primary screening to determine the type of the ink and a subsequent in-depth analysis using several spectroscopic techniques: XRF, FTIR, and Raman. In most cases, we can obtain satisfactory results using a non-invasive protocol. However, mixed inks that contain no metals evade such a protocol. These inks constitute a heterogeneous group of media used especially in the Middle East and the Islamicate world since at least the 10th century; they are characterized by blending carbon ink and tannins, with or without the addition of vitriol.
Our own research aims primarily at recreating a socio-geographic history of inks, parchment, and papyrus and includes the comparative analysis of the writing materials of the Dead Sea Scrolls, ink and papyrus in Ancient and Hellenistic Egypt, and inks in documents from various contemporary medieval communities in Fustat (first nucleus of Cairo). During many years of study, we concluded that the continuous production of Coptic manuscripts from late Antiquity to the Middle Ages offers a unique opportunity for historical study of the ink in a large geographic area. Thanks to the collaboration with the ERC project “PAThs” (www.paths.uniroma1.it), based at the University of Rome La Sapienza, and within the activities of a PhD research dedicated to this topic, we therefore created a new branch of our project focused entirely on the analysis of Coptic inks, pigments, and dyes. This pioneering systematic study of writing materials coming from a specific area and time frame (5th-10th century) aims not only at a better understanding of the complex Coptic multicultural and plurilingual society, but also and mainly at clarifying the links among the Coptic and other societies between the ancient and medieval eras. Finally, it will cast light on the history of the technological development of inks in the eastern world, from Antiquity to the middle ages.
While studying the socio-geographic history of inks, division 4.5 of the BAM (Bundesanstalt für Materialforschung und Prüfung) together with the Centre for the Study of Manuscript Cultures in Hamburg has developed a protocol for ink analysis. It consists of a primary screening to determine the type of the ink, and a subsequent in-depth analysis using several spectroscopic techniques. The XRF elemental analysis aims primarily at understanding the fingerprints of inks containing metals, making it possible to distinguish among different inks.
Our own research aims primarily at recreating a socio-geographic history of inks, parchment, and papyrus and includes the comparative analysis of the writing materials of the Dead Sea Scrolls, ink and papyrus in Ancient and Hellenistic Egypt, and inks in documents from various contemporary medieval communities in Fustat (first nucleus of Cairo). During many years of study, we concluded that the continuous production of Coptic manuscripts from late Antiquity to the Middle Ages offers a unique opportunity for historical study of the ink in a large geographic area. Thanks to the collaboration with the ERC project “PAThs” (www.paths.uniroma1.it), based at the University of Rome La Sapienza, and within the activities of a PhD research dedicated to this topic, we therefore created a new branch of our project focused entirely on the analysis of Coptic inks, pigments, and dyes. This pioneering systematic study of writing materials coming from a specific area and time frame (5th-10th century) aims not only at a better understanding of the complex Coptic multicultural and plurilingual society, but also and mainly at clarifying the links among the Coptic and other societies between the ancient and medieval eras. Finally, it will cast light on the history of the technological development of inks in the eastern world, from Antiquity to the middle ages.
An approach to achieve “zero leakage” is discussed with respect to the experience in Germany, where strict regulations for landfill lining and capping systems have been developed and issued because of large environmental problems related to landfills that accumulated in the 1970’s and 1980’s. These regulations for landfills and geosynthetics which are used in landfill liner and capping systems are shortly described. The main certification requirements for the products as well as conclusions for their use are presented. Using a thick, high quality HDPE geomembrane (GMB), which is installed free of residual waves and wrinkles in intimate contact with a compacted clay liner (CCL) or geosynthetic clay liner (GCL) of very low permeability, by a qualified, experienced, well equipped and properly third‐party controlled installer and which are protected by heavy protection layers designed with respect to long‐term performance of the GMB, may result in a liner or capping system of practically no leakage. This is demonstrated by analyzing results of measurements obtained from permanently installed leak detection systems in combination with HDPE GMBs.
An approach to achieve “zero leakage” is discussed with respect to the experience in Germany, where strict regulations for landfill lining and capping systems have been developed and issued because of large environmental problems related to landfills that accumulated in the 1970’s and 1980’s. These regulations for landfills and geosynthetics which are used in landfill liner and capping systems are shortly described. The main certification requirements for the products as well as conclusions for their use are presented. Using a thick, high quality HDPE geomembrane (GMB), which is installed free of residual waves and wrinkles in intimate contact with a compacted clay liner (CCL) or geosynthetic clay liner (GCL) of very low permeability, by a qualified, experienced, well equipped and properly third‐party controlled installer and which are protected by heavy protection layers designed with respect to long‐term performance of the GMB, may result in a liner or capping system of practically no leakage. This is demonstrated by analyzing results of measurements obtained from permanently installed leak detection systems in combination with HDPE GMBs.
The Cairo Genizah is a well-known “archive” discovered in the 19th century in Ben Ezra Synagogue in Fustat, a district in Old Cairo (Egypt), located south of the center of modern Cairo. The giant collection of mostly Jewish documents that vary in genres, languages and writing supports contains a large number of early medieval Hebrew manuscripts, mostly in fragmentary form. The larger part of the Cairo Genizah is stored today in the Cambridge University Library, containing about 200,000 fragments.
The Genizah provides sources for the literary, linguistic, historical studies of the various aspects Jewish and non-Jewish life. As the documents attest, at least two Jewish communities co-existed in Fustat up to 11th century: a so-called Babylonian and Palestinian. These communities had different leaders, different traditions and lived independently. The differences manifest themselves also in the paleographical properties of the manuscripts produced by each community.
Although Genizah manuscripts have attracted a great deal of scholarly attention, the material aspects of these documents seem to have been largely neglected. The current study aims to obtain information on the composition of the writing supports and the inks used, in order to obtain insights on trade, local production techniques and social structures.
Can we extend the differences detected by the paleographical analysis to differences in composition of the writing materials ? Can we relate the differences in the composition to a community, to the manuscript type (legal, private...), or to another criterion?
Biofilm formation on materials leads to high costs in industrial processes, as well as in medical applications. This fact has stimulated interest in the development of new materials with improved surfaces to reduce bacterial adhesion.
We present a flow chamber system to test and quantify bacterial adhesion on materials that are part of antifouling concepts. The adhesion process is standardized and can be adapted to different bacteria in subaquatic of subaerial environments. It is combined with a standardized evaluation procedure based on statistical evidence.
Microbially influenced corrosion (MIC) of iron is usually attributed to sulfate-reducing microorganisms (SRM) which act upon the metal by the reactiveness of hydrogen sulfide, and by withdrawal of the available electrons in electrical contact with the metal. Methanogenic archaea are supposed to cause MIC. Because they do not produce hydrogen sulfide, withdrawal of electrons may be their main corrosive mechanism; however, mechanistic details and kinetics of the overall process are poorly understood. Precipitation of siderite (4Fe + 5HCO3 + 5H+ 4FeCO3 + CH4 + 3H2O) can lead to an insulating layer on the metal surface and lower the corrosion rate. Still, the extent of FeCO3 precipitation may be significantly influenced by environmental conditions such as pH and advective processes.
Microbially influenced corrosion (MIC) of iron is usually attributed to sulfate-reducing microorganisms (SRM) which act upon the metal by the reactiveness of hydrogen sulfide, and by withdrawal of the available electrons in electrical contact with the metal. Methanogenic archaea are supposed to cause MIC. Because they do not produce hydrogen sulfide, withdrawal of electrons may be their main corrosive mechanism; however, mechanistic details and kinetics of the overall process are poorly understood. Precipitation of siderite (4Fe + 5HCO3 + 5H+ 4FeCO3 + CH4 + 3H2O) can lead to an insulating layer on the metal surface and lower the corrosion rate. Still, the extent of FeCO3 precipitation may be significantly influenced by environmental conditions such as pH and advective processes.
The quest for the mixed inks
(2018)
In this article, we would like to share our observations concerning the inks produced by intentionally mixing soot or charcoal with tannin extracts or iron-gall ink. Aside from Zerdoun’s mention in her outstanding review of written sources, “Les encres noires au Moyen-Âge”, this ink category has received little if any attention from scholars and scientists. And yet, if analytically attested, the use of such inks could serve as an additional category to classify and distinguish the writing inks on the historical socio-geographic map of the writing inks we are trying to build.
Auslaugversuche wurden mit verschiedenen Bauprodukten durchgeführt, die unter Anwendungsbe-dingungen mit Niederschlägen in Kontakt kommen können. In das Testprogramm wurden Lacke für Außenanwendungen, Wärmedämmverbundsysteme, Dachziegel und polymere Dachfolien einbezogen.
Mit diesen Produkten wurden der von CEN TC 351 entwickelte dynamische Oberflächenauslaugtest (DSLT) und Immersionstests nach EN 16105 durchgeführt. Emissionsverläufe wurden sowohl für an-organische Komponenten als auch für organische Substanzen in den Eluaten ermittelt. Auslaugbare organische Substanzen wurden zuvor in Screeningtests identifiziert.
Um die mögliche Freisetzung von Stoffen aus Bauprodukten beurteilen zu können, ist es erforderlich, Emissionsverläufe zu beschreiben. Dazu sind die verwendeten Testverfahren geeignet. Um Baupro-dukte mit einem Blauen Engel als „Produkte mit geringer Auslaugung“ auszuloben, müssen die aus-laugbaren Substanzen komplett bekannt sein. Für organische Verbindungen ist das noch eine Heraus-forderung. Außerdem erfordert die Bewertung der Testergebnisse sowohl Übertragungsmodelle, die Vorhersagen über freisetzbare Stoffmengen unter Anwendungsbedingungen ermöglichen, als auch Vorgaben zu tolerierbaren Umweltkonzentrationen. Hier besteht noch Handlungsbedarf.
The mayor part of the Berlin collection `Manuscripta Americana´ consists of documents compiled by Alexander von Humboldt. The diversity of the written fragments and their shape presume few accordance concerning purpose, place or time of production. Even before the papers came to Berlin, manuscripts were copied, divided and collected by famous scholars also in Mexico. Back in Europe, Humboldt visited further collections and published the detected hieroglyphic writings altogether with cultural objects and landscapes in the book `Vues des Cordillères et Monuments des Peuples Indigènes de l`Amerique, voyage de Humboldt et Bonpland´, labelled corresponding to the cultural background.
By scientific and culture historical analyses, the Humboldt codices are revised and related to each other and others. In especial, the compilation of fragments shown on plate 36 in the book is looked at more closely. Whereas most of the plates represent only one sheet of painted amate paper, here segments with details of seven fragments are put together. It is tried to comprehend why these pieces are on one plate.
To find out a common feature of the documents, their content and represented form are compared. A correlation between some pieces is obvious and thus is also expected in the manufacture of the codices, in the kind of material used. For this the inks and colors are determined by scientific analysis including XRF-, Raman-, FTIR- and VIS- spectroscopy. Special material is detected and related to results of former analysis of codices written during the colonial period of America. Herewith a clear cultural assignment of the manuscripts is performed.
A relation of the fragments represented on plate 36 among each other and to other codices of the collection Manuscripta Americana in Berlin is discussed. Also, if the manuscripts are unique `originals´ or represent fragments of documents, whose corresponding pieces maybe found- in the best case- incorporated in other collections. We detected, that at least two of them can be put into relation to similar manuscripts deposited in Mexico. Further material analysis should clarify, if the corresponding pieces are identical- from one document, or if one of them is a copy. Herewith an approximation to authenticity features and history is issued.
Los Códices Humboldt, que proceden de la época colonial de Mexico, muestran:
1. colores indígenas típicos y sus mezclas:
cochinilla (rojo), índigo/ Azul Maya (azul y verde), carbón (negro),
zacatlaxcalli, mangle, colores orgánicos (amarillo)
2. influencia colonial:
tinta hierro- gálico para escribir
3. fragmentos distribuidos y cortados:
partes singulares forman parte de otros fragmentos dentro de la colección
(y en otras colecciones?)
Los códices de Mizquiahualla
MsAmer1 frag VII, XIII (XIV, XV) muestran:
- colores indigenes: cochinilla (rojo), indigo (verde, azul), carbón (negro), zacatlaxcalli (amarillo)
- papel indigen (amate)
- pintura con líneas perfil en negro, pintado antes y después de la coloración
- influencía colonial: escritura en tinta hierro- gálica (1571, 1569)
Techialoyan/ Central Mexico
MsAmer7 shows limited colors:
ochre (yellow, brown red, rose)
indigo (blue, green, greyblue+?)
cerussite + chalk (white)
organic ink for writing (brown)
Recycling-Düngemittel auf Basis von sekundären Ressourcen (Gülle, Gärreste, Klärschlamm, Tiermehl etc.) gewinnen in den letzten Jahren zunehmend an Bedeutung in der Landwirtschaft. Die in den Recycling-Düngemitteln enthaltenen P-Spezies weichen oft stark von denen in konventionell hergestellten Düngemitteln aus Rohphosphat ab, zudem enthalten Recyclingdünger oft mehrere verschiedene P-Formen. Die Pflanzenverfügbarkeit des P in ist ganz wesentlich von der enthaltenen P-Form abhängig. Derzeit gibt es außer zeitaufwendigen und kostspieligen Gefäß- und Feldversuchen keine zufriedenstellende Testmethode zur Analyse der P-Pflanzenverfügbarkeit von unterschiedlichen Recycling P-Düngemitteln. Die im europäischen Düngemittelrecht normierten chemischen Extraktionsmethoden (Wasser, Zitronensäure, Ameisensäure, neutral Ammoniumcitrat etc.) zeigen oftmals keine oder nur sehr geringe Korrelation zu der P-Aufnahme von Pflanzen in Gefäßversuchen mit Recycling-Düngemitteln (Kratz et al. 2010, Steckenmesser et al. 2017, Vogel et al. 2017). Eine grundlegende Schwäche chemischer Extraktionsmethoden liegt darin, dass es sich dabei um statische Methoden handelt, die nicht in der Lage sind, die im System Boden/Düngemittel-Bodenlösung-Pflanze stattfindenden dynamischen Prozesse wie P-Freisetzung und Entzug durch die Pflanzenwurzeln abzubilden.
Einen Lösungsansatz bieten hier sog. P-Senken-Methoden. Bereits in den 1950er Jahren wurden erstmals P-Senken zur Analyse des Boden-P angewendet (Chardon et al. 1996). In den darauffolgenden Jahrzehnten wurden verschiedene P-Senken auf der Basis von Eisenoxid-Papier entwickelt (Chardon et al. 1996). Jedoch konnten diese Ansätze auch nur begrenzt zur Bestimmung der P-Pflanzenverfügbarkeit des Boden-P eingesetzt werden. Mitte der 1990er Jahre wurde die DGT (engl. diffusive gradients in thin films) Methode entwickelt (Zhang et al. 1998). Bei der DGT Methode diffundiert P aus der Bodenlösung des angefeuchteten Bodens durch einen Membranfilter und die Diffusionsschicht und wird anschließend an einer Bindungsschicht absorbiert. Durch den Diffusionsgradienten wird das Gleichgewicht in der Bodenlösung permanent gestört, wodurch auch labiles P im Boden gelöst wird. Die stetige Entnahme von P aus der Bodenlösung über die Diffusions-/Bindungsschicht simuliert dabei den Entzug von P durch die Pflanzenwurzel. Die an die Bindungsschicht adsorbierte Menge an P korreliert stark mit der P-Aufnahme von Pflanzen (u.a. Mason et al. 2005, 2013; Menzies et al. 2005, Six et al. 2012). Im Gegensatz zu chemischen Extraktionsmethoden werden bei der DGT Methode Mischungen an Düngemittel und Boden für mehrere Tage inkubiert (Vogel et al. 2017; Duboc et al. 2017), da ansonsten wasserlösliche P-Dünger den DGT Adsorber sättigen und wasserunlösliche P-Dünger unterschätzt werden. Ein bis zwei Wochen Inkubation sind ausreichend, damit sich pflanzenverfügbares P in die Mischungen bildet.
In letzter Zeit haben verschiedene Forschungsgruppen gezeigt, dass die DGT Methode auch eine sehr gute Korrelation mit der Pflanzenverfügbarkeit verschiedener Typen von (Recycling-)P-Düngemitteln aufweist (Vogel et al. 2017; Duboc et al. 2017; Foereid 2017; Haarstad and Bavor 2017; Lemming et al. 2017). Bei Gefäßversuchen mit verschiedenen Recycling P-Düngemitteln konnte die DGT Methode den Ertrag bzw. die P-Aufnahme von Mais deutlich besser vorhersagen als herkömmliche chemische Extraktionsmethoden (Vogel et al. 2017; Duboc et al. 2017).
Daher kann die DGT Methode im Vorfeld der Zulassung von neuen Düngermitteltypen als zuverlässige und robuste Methode zum Screening von Produktvarianten eines Düngemittelherstellers verwendet werden. Um dieses Messverfahren im Rahmen des Düngemittelrechts als Bewertungsinstrument für die Abschätzung der Pflanzenverfügbarkeit unterschiedlicher Düngemittel zu verwenden, muss es allerdings zunächst standardisiert werden. Zu diesem Zweck bietet sich der Einsatz eines „standardisierten“ Bodens bzw. Bodenrezepts an. Zur Kalibrierung der Methode im jeweiligen Labor könnten auch chemisch definierte P-Verbindungen mit bekannter Löslichkeit/Pflanzenverfügbarkeit als Referenz-substanzen verwendet werden.
Die agronomische Effizienz von Düngemitteln wird üblicherweise im Vegetationsversuch geprüft. Vegetationsversuche erlauben die Betrachtung unterschiedlicher Kulturpflanzen und deren Strategien der Nährstoffmobilisierung und -aneignung ebenso wie die Berücksichtigung verschiedener Substrattypen und deren Eigenschaften hinsichtlich Nährstofffixierung und –freisetzung. Solche Versuche, selbst wenn sie nicht im Feld, sondern nur im Gefäß durchgeführt werden, sind jedoch sowohl zeit- als auch kostenintensiv. In erster Näherung wird die Pflanzenverfügbarkeit insbesondere von Phosphor (P)-Düngemitteln daher herkömmlicherweise mit Hilfe standardisierter chemischer Extraktionsmethoden abgeschätzt, deren Durchführung in der deutschen ebenso wie in der europäischen Düngemittelverordnung normiert ist. Diese Methoden werden auch im Rahmen der staatlichen Düngemittelverkehrskontrolle genutzt, um die Einhaltung düngemittelrechtlicher Vorgaben zu überprüfen. Wie jüngere Arbeiten gezeigt haben, ist jedoch die Übertragung herkömmlicher Standardextraktionsmethoden auf neue Dünger aus Recyclingmaterialien wie Klärschlamm mit einigen Schwierigkeiten verbunden, Korrelationen zwischen P-Aufnahme im Vegetationsversuch und chemischer Löslichkeit im Standardextrakt sind oft nur mäßig bis schwach oder überhaupt nicht signifikant. Die vorliegende Literaturübersicht gibt einen Überblick zum aktuellen Stand des Wissens über die chemische Löslichkeit von klärschlammbasierten P-Recyclingdüngern, deren Effizienz im Vegetationsversuch und statistische Relationen zwischen beiden Parametern. Anschließend werden alternative Methoden zur Abschätzung der P-Verfügbarkeit von Recyclingdüngern vorgestellt, die derzeit Gegenstand der wissenschaftlichen Diskussion sind.
The challenge of the project ASHES is focused on the recycling of nutrients from residues of thermochemical processing of by-products of sugar cane industry (bagasse/straw) in Brazil to increase the energy efficiency of thermal conversion and to enable the recycling of process ashes as fertilisers. Dry lignocellulosic biomass (straw, bagasse) are combusted, gasified and subsequently combined with post-thermochemical treatment in the AshDec process to increase the plant availability of phosphorus. Different fertilizer formulations are granulated/pelletized and tested regarding their storage/handling characteristics.
A wide range of methods are used to estimate the plant-availability of soil phosphorus (P). Published research has shown that the diffusive gradients in thin films (DGT) technique has a superior correlation to plant-available P in soils compared to standard chemical extraction tests. In order to identify the plant-available soil P species, we combined DGT with infrared and P K- and L-edge X-ray adsorption near-edge structure (XANES) spectroscopy. This was achieved by spectroscopically investigating the dried binding layer of DGT devices after soil deployment. All three spectroscopic methods were able to distinguish between different kinds of phosphates (poly-, trimeta-, pyro- and orthophosphate) on the DGT binding layer. However, infrared spectroscopy was most sensitive to distinguish between different types of adsorbed inorganic and organic phosphates. Additionally, also intermediates of the time-resolved hydrolysis of trimetaphosphate in soil could be analyzed. Furthermore, infrared and XANES microspectroscopy make it also possible to analyze P compounds on the binding layer with a lateral resolution down to 1 µm2. Therefore, P species of a spatial soil segment (e.g. rhizosphere) can be mapped and analyzed.
Jährlich entstehen in Brasilien ca. 2 bis 10 Millionen Tonnen Aschen aus der Verbrennung von Zuckerrohrbagasse. Die Aschen enthalten schwankende Zusammensetzungen an mineralischen Nährelementen und könnten daher zu Düngezwecken verwendet werden.
Allerdings ist (i) die Nährstoffverfügbarkeit gering, (ii), die entsprechende Nährstoffzusammensetzung nicht optimal für die Nutzung der Aschen als Düngemittel für die Hauptanbaukulturen in Brasilien und (iii) weisen die Aschen aufgrund häufig schlechter Verbrennungsqualitäten hohe organische Kohlenstoffgehalte auf. Im Rahmen des Forschungsprojekts ASHES („Rückführung von Nährstoffen aus Aschen von thermochemischen Prozessen mit Bagasse bzw. Zuckerrohrstroh“), arbeiten 7 deutsche und 4 brasilianische Partner an der Optimierung der thermochemischen Verwertung von Rückständen aus der Zuckerproduktion in Brasilien, inklusive der Formulierung von optimierten Düngemischungen auf Basis der generierten Aschen. In dieser Veröffentlichung wird die Verarbeitung dieser optimierten Mischungen zu Pellets und Granulaten unter Verwendung verfügbarer regionaler Reststoffe wie Filterkuchen (Vinasse-Presskuchen) sowie Hühnertrockenkot beschrieben. Zur Untersuchung der Handlingeigenschaften wurden die produzierten Pellets und Granulate hinsichtlich ihrer mechanischen Stabilität und des Wasseraufnahmevermögens untersucht. Dafür wurden geeignete Prüfverfahren angepasst und entsprechende Versuche durchgeführt.
Background Bacterial biofilms are regarded as the most common cause of chronic infections and are often associated with medical devices, such as implants and catheters. Bacteria growing in biofilms produce a protective, extracellular matrix, which enables them to tolerate much higher antimicrobial concentrations than free-living bacteria and survive long enough to acquire antimicrobial resistance. Preventive and therapeutic strategies against biofilm infections in clinical settings commonly involve the application of multiple antimicrobials: biocidal coatings on the biomaterials and systemically administered antibiotics. This frequent practice harbors the risk of the development of cross-resistance via shared resistance mechanisms between antimicrobials used in material coatings and administered antibiotics.
Aim Our goal is to determine how bacteria adapt to antimicrobials during biofilm formation on surfaces coated with antimicrobials, how antimicrobial resistance mutations are acquired and evolve within mature biofilms, and how population dynamics within biofilms affect the transmission of resistance mutations. Specifically, we want to identify antimicrobial-antibiotic-combinations that select for and against antibiotic resistance in biofilms by following the population dynamics of resistant and susceptible strains in competition assays.
Methodology We will grow biofilms of Pseudomonas aeruginosa on glass surfaces with and without antimicrobial coatings and expose them to antibiotics. Then we will track their physiological properties, evolutionary adaptations, and population dynamics. First, we will screen in vitro for combinations of antibiotics and antimicrobials that select for and against antibiotic resistance. Second, effective combinations will be chosen for in-depth investigations during bacterial adhesion and of mature biofilms of resistant and susceptible genotypes. Third, based on the outcome of the screen and the obtained mechanistic understanding we will choose a clinical example in which we study the relevance of our findings in biofilms grown in vivo.
Relevance Studying the biointerfacial interactions between bacterial biofilms and medical devices in terms of population dynamics as well as on single cell level during multidrug selection will help us understand how drug resistance develops and spreads in persistent biofilm infections. Based on our findings we aim to provide clinical recommendations for improved administration of antibiotics/antimicrobials in combination with medical device materials in order to mitigate against biofilm associated antimicrobial resistance.
Selection of resistance in bacteria grown on antimicrobial surfaces in a multidrug environment
(2018)
Bacterial biofilms are regarded as the most common cause of chronic infections and are often associated with medical devices, such as implants and catheters. Bacteria growing in biofilms produce a protective, extracellular matrix, which enables them to tolerate much higher antimicrobial concentrations than free-living bacteria and survive long enough to acquire antimicrobial resistance. Preventive and therapeutic strategies against biofilm infections in clinical settings commonly involve the application of multiple antimicrobials: antimicrobial coatings on the biomaterials and systemically administered antibiotics. This frequent practice harbors the risk of the development of cross-resistance via shared resistance mechanisms between antimicrobials used in material coatings and administered antibiotics.
Our goal is to determine how population dynamics within biofilms affect the transmission of resistance mutations. Specifically, we want to identify antimicrobial-antibiotic-combinations that select for and against antibiotic resistance in biofilms by following the population dynamics of resistant and susceptible strains in competition assays. Gaining a better understanding about resistance development and spread in persistent biofilm infections will enable us to provide clinical recommendations for improved administration of antibiotics/antimicrobials in combination with medical device materials to mitigate against biofilm associated antimicrobial resistance.
Here, we will discuss our first findings on the effects of combinations of the carbapenem drug meropenem and various antimicrobials.
Background Bacterial biofilms are regarded as the most common cause of chronic infections and are often associated with medical devices, such as implants and catheters. Bacteria growing in biofilms produce a protective, extracellular matrix, which enables them to tolerate much higher antimicrobial concentrations than free-living bacteria and survive long enough to acquire antimicrobial resistance. Preventive and therapeutic strategies against biofilm infections in clinical settings commonly involve the application of multiple antimicrobials: biocidal coatings on the biomaterials and systemically administered antibiotics. This frequent practice harbors the risk of the development of cross-resistance via shared resistance mechanisms between antimicrobials used in material coatings and administered antibiotics.
Aim Our goal is to determine how bacteria adapt to antimicrobials during biofilm formation on surfaces coated with antimicrobials and how population dynamics within biofilms affect the transmission of resistance mutations. Specifically, we want to identify antimicrobial-antibiotic-combinations that select for and against antibiotic resistance in biofilms by following the population dynamics of resistant and susceptible strains in competition assays on a single cell level.
Methodology To study the effect of antimicrobial-antibiotic exposure on resistance development and population dynamics on bacterial biofilms in a multidrug environment, we will grow Pseudomonas aeruginosa on glass surfaces with and without antimicrobial coatings and expose them to antibiotics. First, we will screen in vitro for combinations of antibiotics and antimicrobials that select for and against antibiotic resistance. Second, effective combinations will be chosen for in-depth investigations during bacterial adhesion and of mature biofilms of resistant and susceptible genotypes. Third, based on the outcome of the screen and the obtained mechanistic understanding we will choose a clinical example in which we study the relevance of our findings in biofilms grown in vivo.
Relevance Studying the biointerfacial interactions between bacterial biofilms and medical devices in terms of population dynamics as well as on single cell level during multidrug selection will help us understand how drug resistance develops and spreads in persistent biofilm infections. Based on our findings we aim to provide clinical recommendations for improved administration of antibiotics/antimicrobials in combination with medical device materials in order to mitigate against biofilm associated antimicrobial resistance.
Microbiologically influenced corrosion (MIC) is an expensive but unpredictable problem for the industries. The most well-known culprit for MIC is the sulfate-reducing microorganisms (SRM), such as members from the genus Desulfovibrio. It has been widely accepted that SRM can contribute significantly to MIC through the production of hydrogen sulfide (HS-) or in some cases a direct electron uptake from the metal surface. However, in a real environmental system, SRM is not exclusive and often involved with other microorganisms that may also contribute to MIC, such as methanogens.
Methanogenic archaea can produce methane (CH4) using H2+CO2, formate, methylated amines or acetate. Methanogens are highly abundant in the environment and many are found in very extreme conditions, such as high temperature and high salinity. Previous researches have demonstrated that methanogens are capable of MIC, though the specific mechanisms are still under investigation. In the oil and gas industry, methanogens are not considered as the main contributor for MIC since the corrosion rates are often too low. However, the tests for methanogen-induced MIC are usually performed at static conditions, which cannot represent the system accurately. Here, we developed a novel anaerobic system to evaluate the corrosion potential of methanogens under flow conditions. We will use the Methanococcus maripaludis KA1 strain, which was isolated from a crude oil tank, as the organism of interest. A separate system for Desulfovibrio alaskensis will be established for corrosion rate comparisons. Furthermore, we will study the synergistic effects of M. maripaludis and D. alaskensis on MIC under flow.
Microbiologically influenced corrosion (MIC) is the deterioration of metals due to the metabolic activities of microorganisms. Microorganisms can take electrons directly from the metal surface (EMIC) thereby causing corrosion. Well known culprits of EMIC are: sulfate-reducing bacteria (SRB), acetogens and methanogens.
Our aims
- Develop a novel flow system to study MIC by methanogens to mimic industrial Environments
- Investigate the inhibitory concentrations of biocides targeting SRB on corrosive methanogenic strains
- Investigate the inhibitory effects of corrosion inhibitors on methanogens
- Compare the inhibitory concentrations to SRB
Microbiologically influenced corrosion (MIC) is the deterioration of metals due to the metabolic activities of microorganisms. Microorganisms can take electrons directly from the metal surface (EMIC) thereby causing corrosion. Well known culprits of EMIC are: sulfate-reducing bacteria (SRB), acetogens and methanogens.
Potential use of incineration bottom ash in construction – Evaluation of environmental impact
(2018)
Around 5 million tonnes of MSWI bottom ash (BA) are generated per year in Germany. The incineration itself serves for metals as a concentrating and cleaning process. However, due to the almost exclusive wet extraction out of the furnace chamber the various metals are integrated in a heterogeneous and instable matrix. The metal recovery is therefore still a challenge relating the recovery rate and the purity, respectively. With state of the art treatment trains in Germany around 7.7% of ferrous metals and 1.3% of non-ferrous metals can be recovered out of MSWI BA. Large quantities of the mineral fraction are reused for sub-base material in road construction. A three month ageing period has been established as the common practice of further treatment of bottom ash before reuse applications. In the course of this aging the pH value of bottom ash decreases and contaminants are immobilized by processes like carbonation, hydration and oxidation. In particular leaching of heavy metals may be reduced to environmentally acceptable levels. However, the aging results in fixing of other valuable resources such as metals. Two laboratory scale lysimeters (30 cm in diameter) are being operated for more than three years aiming at the investigation of the long-term leaching behavior of a 0.25/45 mm mineral material obtained by treatment of MSWI bottom ash directly after incineration by a wet processing technology. Artificial rainwater is used as leachant (pH ≈ 6, ingredients NO32-, Cl-, SO42-, Na+, K+, Ca2+, Mg2+). The lysimeters are irrigated related to an average annual precipitation rate of 600 mm/a leading to a liquid to solid ratio (L/S) of about 0.7 per year of operation. Lysimeter tests are more adequate to simulate field scenarios and long-term leaching behavior in contrast to laboratory column tests particularly due to the unsaturated conditions and realistic contact time with the leachant.
In comparison to the leaching of bottom ash (aged for 3 month and non-treated) in column tests the chloride and sulfate leaching in the lysimeters was reduced as a consequence of the previous wet processing. The sulfate release kept almost constant limited by CaSO4 solubility up to an L/S of about 0.7 l/kg. The chloride concentrations dropped quickly, starting from 7300 mg/l, and are now at an almost constant level of 50 mg/l which is significantly above the chloride concentration in the leachant. After an initial decrease of the pH from about 10.4 to 8 at L/S of 0.2 l/kg, the pH increased again and leveled out around 9.8 up to L/S 2.2 l/kg. At an L/S of about 2.5 l/kg now, Cr, Cu are still released. The Cu and Cr concentrations in the leachates were about 760 µg/l and 90 µg/l respectively at the beginning. For both metals the concentration decreased to about 35 µg/l now. The Mo concentrations dropped steadily from 1300 to 250 µg/l, whereas V and Sb concentrations increased in the course of the tests. Fe and Mn are not detectable anymore. More results of this experimental study will be presented and discussed with a special focus on elements forming oxyanions.