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- Englisch (12)
Schlagworte
- Hydrogen desorption (4)
- Titanium alloys (4)
- Corrosion behavior (3)
- AZ31B (2)
- Beta-21S (2)
- Hydrogen absorption (2)
- Microstructure (2)
- Thermal Desorption Spectroscopy (TDS) (2)
- Thermal desorption spectroscopy (TDS) (2)
- AZ31 Magnesium Alloy (1)
Different characteristics of hydrogen's absorption/desorption behavior and trapping in ß-21S titanium alloy are studied by means of thermal desorption spectroscopy (TDS). Spectra analysis is supported by data from variety of other experimental techniques, such as LECO hydrogen determinator, XRD and microstructure investigations by means of optic and electronic microscopy. In contrast to many past considerations, the complex process of hydrogen evolution has been found to be significantly affected by the way hydrogen introduction into the alloy. The different trapping sites, as well as phase transformations, have to be considered as the reasons for the different hydrogen evolution behavior.
Gas tungsten arc welds made on wrought magnesium AZ31 plate have
been characterized for corrosion in saline solution (3.5% NaCl). Microstructural
changes induced by the welding process resulted in different
environmental behaviour of each zone (BM-base metal, HAZ-heat affected
zone and FZ-fusion zone). The faster kinetics of corrosion in FZ and especially
HAZ are attributed to (a) the coarse microstructure, consisting of
large grains, and (b) very small amounts of ß-phase in the grain boundaries.
Also, hardness traverses have shown that these zones are weaker
than the base metal. Based on the significant effect of grain size on strength
in magnesium alloys, the weld metal grains have been systematically refined
using controlled oscillation during welding, and by adding a grain
refiner to the weld pool. Detailed microstructure analyses have been carried
out and the relationships between corrosion behaviour, mechanical
properties and microstructure (grain refinement and second-phases formation)
are highlighted.
Based on its excellent combination of a high strength/weight ratio and good corrosion behavior, Ti6Al4V alloy is ranked among the most important advanced materials for a variety of industrial applications. However, in many of these technological applications, this alloy is exposed to environments which can act as sources of hydrogen, and severe problems may arise based on its susceptibility to hydrogen embrittlement. Even small hydrogen concentrations might lead to failure. Consequently, a comprehensive knowledge of hydrogen's absorption/desorption behavior and interactions between hydrogen and different microstructural features is necessary to better understand the desorption and trapping mechanisms, the types of the trap sites, and the trapped hydrogen content, in order to determine the safe service conditions of this alloy in the industry. In this paper, different characteristics of hydrogen's absorption/desorption behavior and trapping in a duplex-annealed Ti6Al4V alloy are studied by means of thermal desorption spectroscopy (TDS). Spectra analysis is supported by data from a variety of other experimental techniques, such as LECO hydrogen determinator, XRD and microstructure investigations by means of optical and electron microscopy. Hydrogen evolution is found to be a very complex process, being affected by the way hydrogen was initially introduced to the alloy, the phase transformations that may occur during the thermal analysis and the presence of potential trapping sites.