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Positioning accuracy of an automatic scanning system for GPR measurements on concrete structures
(2012)
During carbon dioxide storage technology (carbon capture and storage, CCS) components are exposed to a corrosive environment and mechanical stress, which results in corrosion fatigue and inevitably followed by the a lifetime reduction of these components. In order to gain knowledge upon the corrosion fatigue strength of materials, Samples of high alloyed stainless injection-pipe steels AISI 420 X46Cr13, and X5CrNiCuNb16-4 AISI 630 were tested in a at T=60 °C and ambient pressure in a CO2-saturated synthetic aquifer environment similar to possible geological on-shore CCS-sites in the northern German Basin. Therefore a corrosion chamber applied to a resonant testing machine allowing for “in situ” test conditions was designed and successfully tested. In-situ tension compression experiments were established using a resonant testing machine at a frequency as low as 30 – 40 Hz. In addition technical CO2 was introduced into the closed system at a rate close to 9 L/h to keep stable environmental conditions. Simultaneously electrochemical testing was performed to get information on failure causes and the mechanism of failure during the injection of CO2 into deep geological layers. S-N plots, micrographic analysis, and surface analysis of the fracture surface were applied to obtain sustainable information on the corrosion fatigue behavior of injection pipe steels. Samples used have a surface roughness of Rz = 4, to simulate technically machined surfaces. X46Cr13 reached the maximum number of cycles (12.5 x 106) at a stress amplitude of 173 MPa. X5CrNiCuNb16-4 reached the maximum number of cycles (10 x 106) at a stress amplitude at 150 MPa. The scatter range of X5CrNiCuNb16-4 is very high (1:34); by comparison the scatter range of X46Cr13 is only 1:3.5.
Time slices of very dense GPR measurements carried out at concrete with a real point distance of less than 10 mm in x and y direction show weak reflection patterns besides the strong reflections of reinforcements. A repetition of these measurements with the same local geometrical precision at the same specimen shows the same reflection pattem. We suppose that the heterogeneity of concrete given by aggregates (e.g. gravel, broken granite) causes local weak Scattering of the GPR waves and leads to reflection patterns in the GPR data. These reflection patterns can be explained by a Superposition of multiple scatterings of single aggregates. So far these reflection patterns have been not recognized in Standard time slices due to the large spacing (> 5 cm) between single profiles and because of the interpolation between the profiles.
We investigate the characteristics of the volume scattering effects, caused by aggregates, at concrete blocks with two different grading curves. In a more general investigation we study the volume scattering of aggregates by using wooden boxes filled with only typical aggregates and an included defined reflector (metal plate). The thickness of the aggregate layer above the metal plate was varied between 20 cm and 40 cm. With a very dense measuring grid at the surface we are able to calculate the effective volume scattering and to analyze the distribution of the reflection amplitude of the included metal plate for different aggregate set-ups. Results of this study confirm that the weak reflection patterns in concrete can be explained by aggregate scattering and have a direct correlation to the penetration depth of GPR in concrete.
Corrosion fatigue (CF) of duplex stainless steel (DSS) X2CrNiMoN22-5-3 was investigated in in-situ geothermal conditions of the Northern German Basin (NGB). The influence of the load type on CF behavior of the alloy was examined by applying push/pull and rotating bending cyclic load to failure. The hour-glass shaped specimens with both polished and precisely turned surface finish were tested in corrosion chambers allowing for the permanent circulation of Northern German Basin electrolyte heated to 369 K. Additionally, the influence of a protective cathodic potential on the CF life expectancy was investigated by employing a potentiostat. The rotating bending cyclic load led to a higher CF life expectancy, which decreased with increasing duration of the experiment due to a higher deterioration rate of the material. The application of a cathodic potential caused a significant increase of the CF lifespan from 4.7 x 105 (open-circuit potential (OCP)) to 107 cycles (preset threshold cycle number) for the potential range from USHE = – 450 to – 900 mV. Microstructural analysis of the CF damage revealed horizontal grain attack within corrosion pit cavities, multiple fatigue cracks and preferable deterioration of the austenitic phase.
Over decades, the German Federal Institute for Materials Research and Testing (BAM) has established a sophisticated calibration laboratory for force, temperature and electrical quantities. Since more than 15 years it is accredited, currently by the national accreditation body (DAkkS), and offers its service also to external entities on a global scale. As a public provider, we are furthermore committed to research and development activities that demand measurements with highest quality and low level of uncertainties. Two R&D examples are highlighted within this contribution.
Air voids in concrete like honeycombs are one of the major concerns regarding quality assurance for the construction of infrastructure buildings like bridges or tunnels. This paper shows that voids in reinforced concrete walls or slabs can be detected by two standard ground coupled GPR antennas in transmission mode using a two-side zero-offset profiling configuration like in borehole radar applications. For the detection of voids only the amplitudes of the direct wave in transmission mode are evaluated. Even when the depth of the void can not be detected in this configuration, the major advantage of the zero-offset profiling in transmission mode is a lower interference with the surrounding reinforcement compared to a regular one-side reflection profiling. The capability of the two-side zero-offset profiling is demonstrated on a test specimen with a set of polystyrene balls of two different sizes representing voids like honeycombs in concrete. GPR measurements are realized by an automated scanning system in order to allow for a synchronous movement of the antennas. In transmission mode voids can be detected at greater depths compared to reflection mode, since the travel path of the direct wave is half as long. Another characteristic of the transmission mode is that the direct wave through the air voids is faster and arrives earlier than the direct wave in the surrounding concrete. Hence it can be separated from the strong reflection of the reinforcement. Finally the measurements in transmission mode are less sensitive to the antenna frequency and polarization than in reflection mode.
X5CrNiCuNb16-4 has been proven to be sufficient resistant in corrosive environments, but shows rather unusual corrosion behaviour in CCS environment. Therefore a series of 30 specimens was tested at stress amplitudes between 150 MPa and 500 MPa (sinusoidal dynamic test loads, R=-1; resonant frequency ∼ 30 Hz). Due to the rather heterogeneous fine machined surfaces (Rz=4) the specimens are comparable with prefabricated parts. X5CrNiCuNb16-4 reached the maximum number of cycles (10 x 106) at a stress amplitude of 150 MPa and lies 60% below the stress amplitude measured in air. The scatter range TN = 1:34 is disproportionately large. Although the fracture surface exhibited the typical striations and corroded surface areas no significant differences were found. The hardness was found to be homogeneous in all specimens tested at 335 HV10. Non-metallic inclusions were found within the microstructure, but no correlation could be found between the inclusions and early rupture. Still specimens that showed inclusions at the fracture surface and its cross section endured lower number of cycles. Additionally Aluminium was analysed in specimens with low number of cycles and may be cause for early rupture during corrosion fatigue tests. These findings reveal a very high sensitivity on a homogeneous microstructure upon the corrosion and corrosion fatigue behaviour of X5CrNiCuNb16-4 and needs to be taken into account when regarding this steel as pipe steel during injection of CO2 into saline aquifers.
Impact resistance of reinforced concrete (RC) structures can be significantly improved by strengthening RC members with thin composite layers featuring high damage tolerance. Indeed, to limit the well-known vulnerability of cement-based materials against impact loading, the synergistic effects of short fibres and continuous textile meshes as hybrid reinforcement has been proved to be highly beneficial. This paper addresses the characterisation of novel cement-based hybrid composites through accelerated drop-weight impact tests conducted on rectangular plates at different impact energies. Two distinct matrices are assessed, with particular interest in a newly developed limestone calcined clay cement (LC3)-based formulation. Important parameters quantifying energy dissipation capability, load bearing capacity and damage are cross-checked to compute the ballistic limit and estimate the safety-relevant characteristics of the different composites at hand. Although textiles alone can improve the damage tolerance of fine concrete to some extent, the crack-bridging attitude of short, well-dispersed fibres in hybrid composites imparts a certain ductility to the cement-based matrices, allowing a greater portion of the textile to be activated and significantly reducing the amount of matrix spalling under impact.