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Eingeladener Vortrag
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Konventionelle elektrische Verfahren zur Erfassung von Teilentladungen (TE) in hochspannungstechnischen Bauteilen und Betriebsmitteln erfordern elektromagnetisch ungestörte Messbedingungen und sind für die Überprüfung von Anla-gen während des laufenden Betriebs nicht unproblematisch. Daher werden für Prüfung und Überwachung im Feld zu-nehmend unkonventionelle elektromagnetische (HF, VHF, UHF) und akustische Detektionsverfahren eingesetzt. Wegen ihrer prinzipiellen Immunität gegen elektromagnetische Störungen sind darüber hinaus faseroptische Verfahren der TE-Detektion in Erprobung. Im vorliegenden Beitrag werden zwei Typen akustisch-faseroptischer Sensoren (a-FOS) vorgestellt und auf ihre Eignung untersucht, Teilentladungen in elastomeren Isolierkörpern, wie etwa Silikon-Feldsteuerelementen von Kabelgarnituren, zu detektieren. Die hier präsentierten Laborergebnisse zeigen, dass die zur Detektion von TE mit kritischer Intensität (z.B. in Kabelgarnituren) notwendige Empfindlichkeit erreicht werden kann. Darauf basierend wird das Potential der faseroptisch-akustischen Detektion von TE in der hochspannungstechnischen Zustandsüberwachung allein und in Kombination mit fasergekoppelten fluoreszenzoptischen Sensoren diskutiert.
New sensors for the detection of partial discharges (PDs) in high-voltage (HV) cable accessories are being de-veloped consisting of a fluorescent polymer optical fiber (F-POF) as sensing element. Depending on the fiber material F-POFs can be attached to and even integrated into the translucent silicone rubber insulation of HV cable terminations. As the embedment into the insulation material plays an important role, the sensor should not weaken the dielectric strength of the insulation material and should not be the origin of PD incidents. A sensor consisting of a commercial F-POF has been tested in the high-voltage lab regarding its PD detection ability un-der AC in comparison to a conventional electrical sensor. New silicone rubber F-POF (Si-F-POF) fiber models functionalized with coumarin dyes have been produced. The optical properties of these dye functionalized silox-anes are presented. These potential sensor fibers are highly flexible and might be embeddable at medium to high-voltage level. An additional way to further improve the level of PD light detection is to modify the translucent type of silicone rubber used in HV cable accessories in terms of optical transparency. In this context we present our first results of the optical and mechanical properties of new elastomeric transparent silicone materials specif-ically designed for the application as HV insulation materials in stress cones.
Organometallic oligoamides built from three to four ferrocene amino acid units (H-Fca-OH,1-amino-1'-ferrocene carboxylic acid) fold into hydrogen bonded secondary structures featuring eight-membered rings by cooperative hydrogen bonds. NMR studies and DFT calculations (CAM-B3LYP, LANL2DZ, IEFPCM (THF) reveal that the organometallic zigzag foldamer structures are highly resistant toward denaturation by hydrogen bond acceptors such as dimethyl sulfoxide and 2,4-lutidine. Replacing one ferrocene amino acid unit by the organic alpha-amino acid glycine at the C-terminal end (Fca goes to Gly) significantly destabilizes the secondary zigzag structure facilitating denaturation by DMSO. Highly stabilized ordered poly(Fca) architectures are very attractive for future applications of switchable hydrogen-bonded redox-active materials.
We present recent progress in our development of fibre-optic sensors for the detection of partial discharge (PD) in silicone cable accessories, based on detecting related low-level optical emission. We experimentally show that the sensitive optical detection of PD can dramatically enhance the performance of conventional electrical PD measurement in electromagnetically noisy environments, and that it can yield high sensitivity and specificity even when no synchronous electrical PD measurement is conducted. This is demonstrated using a real-scale model of a high voltage cable accessory with a surface-attached conventional thermoplastic fluorescent polymer optical fibre (F-POF) sensor. In order to increase light collection efficiency, as a prerequisite for a commercially competitive implementation using cost-efficient detectors, sensing fibres will have to be integrated into the silicone rubber insulation, close to the potential origin of PD-induced damage. This is the rationale for our efforts to develop elastomeric fluorescent sensing fibres, tailored to the requirements of the application. We discuss specific challenges to be tackled and report on the successful implementation of all-silicone rubber fluorescent POF, to our best knowledge for the first time. © (2015) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
We present the production process and characterization of a fluorescent functionalized elastomeric polymer optical fiber (E-POF) consisting of a covalently linked interface between fiber core and fiber cladding. This all silicone rubber E-POF shows increased temperature stability and can be used for sensing applications. Due to the sophisticated production process surface roughness of the interface of fiber core - fiber cladding are even lower than of the thermoplastic tubing template. Total fiber lengths can be extended by a "chemical splicing" technique, allowing individual tailoring of fibers while maintaining sufficient elasticity under applied mechanical stress.
We present fundamentals for the selection of fluorescent dyes and show the challenges of the implementation of fluorescent dyes in silicone rubber materials for the production of fluorescent all-silicone rubber POF.