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- 2019 (4) (entfernen)
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- Englisch (4)
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- Mueller-Matrix imaging ellipsometry (2)
- Spectroskopic Imaging (2)
- Biofuel (1)
- Fatigue (1)
- Hydroliquefaction (1)
- Inspection planning (1)
- Lignin (1)
- Metrology (1)
- Offshore steel structures (1)
- Polarization spectroscopy (1)
Organisationseinheit der BAM
For the vast majority of ellipsometric measurements, the application of planar substrates is mandatory and requires a proper sample alignment prior to the measurement. Here, the authors present a generalized approach of how to extract the isotropic ellipsometric sample parameters from an imaging Mueller-matrix measurement even if the sample is significantly misaligned. They validate the method by layer-thickness calculations based on imaging Mueller-matrix measurements of flat crystalline silicon samples that were misaligned on purpose. Furthermore, they also exploit this method’s capabilities to perform spatially resolved layer-thickness measurements of a single-layer indium-tin-oxide coating on a fused-silica microlens without the need of realignment or repositioning of the sample during the measurement.
Hydroliquefaction is a possible pathway to produce liquid transportation fuels from solid feedstocks like coal or biomass. Though much effort has been put into the investigation of maximizing the oil yield using expensive catalysts and pasting oils in batch setups, little is known about how to commercialize the process. This work aims at the demonstration of lignin hydroliquefaction under conditions interesting for commercial operation. The results from hydroliquefaction experiments of two different lignin types using a cheap iron-based catalyst and anthracene oil as the pasting oil in a semibatch system are presented here. Oil yields of above 50% are reached without observing coke formation. Extensive analyses of the feedstocks and product oils were performed. The process supplies high-quality oil, while differences in the decomposition path of both lignin types are observed. An high heating value of 39 400 J/g and H/C and O/C ratios of up to 1.6 and 0.1, respectively, are detected for the produced bio-oils.
The authors describe and interpret curvature-related changes to the ellipsometric readout. As model system for a concave curvature, a set of three spherical microscopic indents in silicon (100) of different sizes was prepared by instrumented indentation testing using a spherical indenter. For reference, these samples were characterized by AFM to reveal the topography of each structure. The concavelike indents were analyzed by Mueller-Matrix imaging ellipsometry to extract lateral intensity images of 12 elements of the Mueller-Matrix. As a result of the detailed analysis of the image elements m22, m23, and m14, it was possible to correlate intensity changes and symmetry properties to depolarization and cross polarization induced by the edge threshold and the curved surface of the indent.
Identifying optimal inspection and repair strategies for offshore jacket structures is a challenging task. We pre-sent an approach, which is based on recent developments in the field of risk-based operation and maintenance planning at the structural system level. The approach utilizes heuristics to define inspection and repair strate-gies at the system level and to reduce the search space of possible strategies. For each defined strategy, the expected service life cost of inspection, repair and failure is evaluated based on simulated inspection and re-pair histories. Subset simulation is applied to compute the conditional repair and failure probabilities required for this analysis. It also forms the basis for simulating inspection and repair histories. The strategy that mini-mizes the expected service life cost is the optimal one in the set of pre-selected strategies. The underlying condition and performance model accounts for the stochastic dependence among the deterioration states of the different structural elements and the structural redundancy. The approach is demonstrated in a case study considering a jacket-type frame. In this study, we essentially vary the inspection interval, the minimum num-ber of inspected components and the target reliability, and identify the combination that minimizes the ex-pected total service life cost.