Filtern
Erscheinungsjahr
Dokumenttyp
- Zeitschriftenartikel (72)
- Beitrag zu einem Tagungsband (18)
- Forschungsbericht (6)
- Beitrag zu einem Sammelband (2)
- Buchkapitel (1)
Sprache
- Englisch (82)
- Deutsch (16)
- Mehrsprachig (1)
Schlagworte
- Quantum yield (8)
- Phosphor (7)
- Concrete (6)
- Klärschlamm (5)
- Nanoparticle (5)
- Behälter (4)
- Endlager (4)
- Fluorescence (4)
- Klärschlammasche (4)
- Lanthanide (4)
Organisationseinheit der BAM
- 4 Material und Umwelt (11)
- 1 Analytische Chemie; Referenzmaterialien (8)
- 4.4 Thermochemische Reststoffbehandlung und Wertstoffrückgewinnung (8)
- 1.2 Biophotonik (7)
- 8 Zerstörungsfreie Prüfung (6)
- 6 Materialchemie (5)
- 8.2 Zerstörungsfreie Prüfmethoden für das Bauwesen (5)
- 3 Gefahrgutumschließungen; Energiespeicher (4)
- 3.4 Sicherheit von Lagerbehältern (4)
- 4.3 Schadstofftransfer und Umwelttechnologien (4)
Paper des Monats
- ja (1)
Pseudomonas aeruginosa is an opportunistic pathogen of considerable medical importance, owing to its pronounced antibiotic tolerance and association with cystic fibrosis and other life-threatening diseases. The aim of this study was to highlight the genes responsible for P. aeruginosa biofilm tolerance to antibiotics and thereby identify potential new targets for the development of drugs against biofilm-related infections. By developing a novel screening approach and utilizing a public P. aeruginosa transposon insertion library, several biofilm-relevant genes were identified. The Pf phage gene (PA0720) and flagellin gene (fliC) conferred biofilm-specific tolerance to gentamicin. Compared with the reference biofilms, the biofilms formed by PA0720 and fliC mutants were completely eliminated with a 4-fold-lower gentamicin concentration. Furthermore, the mreC, pprB, coxC, and PA3785 genes were demonstrated to play major roles in enhancing biofilm tolerance to gentamicin. The analysis of biofilm-relevant genes performed in this study provides important novel insights into the understanding of P. aeruginosa antibiotic tolerance, which will facilitate the detection of antibiotic resistance and the development of antibiofilm strategies against P. aeruginosa.
Ananion-dopedaluminiumchlorofluoride AlCl0.1F2.8(OTeF5)0.1(ACF-teflate) was synthesized.The material contains pentafluor-oorthotellurate(teflate)groups, which mimic fluoride ions electronically, but are sterically more demanding. They are embedded into the amorphous structure. The latter was studied by PDF analysis, EXAFS data and MAS NMR spectroscopy. The mesoporous powder is a Lewis superacid, and ATR-IR spectra of adsorbed CD3CN reveal a blue-shift of the adsorption band by73 cm-1, which is larger than the shift for SbF5. Remarkably,ACF-teflate catalyzes dehydrofluorination reactions of mono-fluoroalkanes to yield olefins in C6D6. In these cases,no Friedel-Crafts products were formed.
Luminescent solar concentrators (LSC) allow to obtain renewable energy from building integrated photovoltaic systems. As promising efficient and long-term stable LSC fluorophores semiconductor nanocrystals like Quantum dots (QDs) with size and composition tunable optoelectronic properties have recently emerged. The most popular II/VI or IV/VI semiconductor QDs contain, however, potentially hazardous cadmium or lead ions, which is a bottleneck for commercial applications. A simple aqueous based, microwaveassisted synthesis for environmentally friendly and highly emissive AgInS2/ ZnS QDs is developed using 3-mercaptopropionic acid (MPA) and glutathione (GSH) and their incorporation into polylaurylmethacrylate (PLMA) polymer slabs integrable in LSC devices (10.4 × 10.4 × 0.2 cm3, G = 12.98).
With this simple approach, optical power efficiencies (OPE) of 3.8% and 3.6% and optical quantum efficiencies (OQE) of 24.1% and 27.4% are obtained, which are among the highest values yet reported.
We synthesized and characterized a set of ultrasmall hexagonal-phase NaGdF4: 20% Yb3+, 2% Er3+ upconversion nanoparticles with core diameters of 3.7 ± 0.5 nm. In order to assess passivation effects and the influence of possible core−shell intermixing and to identify optimum particle structures for combined imaging in the visible and near-infrared (vis−NIR: 410−850 nm) and short-wave infrared (SWIR: 1520 nm), NaYF4 shells of varying thicknesses (monolayer to 10 nm) were introduced and the influence of this parameter on the upconversion and downshifting photoluminescence of these particles was studied at different excitation power densities. This included excitation power-dependent emission spectra, slope factors, quantum yields, and excited state decay kinetics. These measurements revealed enhancement factors of the upconversion quantum yield of >10 000 in the low power region and an excitation power density-independent quantum yield of the downshifted emission at 1520 nm between 0.1 and 14%. The optimized shell thickness for combined vis and SWIR imaging was identified as 5 nm. Moreover, lifetimes and quantum yields can be continuously tuned by shell thickness which can be exploited for lifetime multiplexing and encoding. The fact that we did not observe a saturation of the upconversion quantum yield or the excited state decay kinetics with increasing shell thickness is ascribed to a strong intermixing of the active core with the inert shell during the shelling procedure. This indicates the potential of spectroscopic tools to detect cation intermixing.
Im Forschungsvorhaben KoBrA werden Anforderungen an Endlagerbehälter für hochradioaktive Abfälle erstmals systematisch und unter Berücksichtigung des internationalen Standes von Wissenschaft und Technik hergeleitet. Parallel werden die behälterrelevanten Randbedingungen und Beanspruchungsgrößen für Endlagerbehälter in den drei potenziellen Wirtsgesteinen Steinsalz, Tonstein und Kristallingestein ermittelt. Darauf aufbauend werden die zur Erfüllung der Anforderungen unter den gegebenen Einwirkungen und Beanspruchungen notwendigen Behälterfunktionen bestimmt und erste Konzeptideen für zukünftige Endlagerbehälter diskutiert bzw. entwickelt.
Nanocrystalline basaluminite [Al4OH10(SO4)(H2O)3–5] and Aggregation of the e-Keggin polyoxocation [Al12(AlO4)(OH)24(H2O)12]7+, referred to as Al13, have both been described to form in acid mine Drainage environments. Although the chemical composition is quite similar, their crystalline varieties significantly differ, demonstrating that various types of Al-hydroxysulfates can form under similar conditions and that their respective formation is not fully understood yet. Here, we report the occurrence of nanocrystalline precipitates that form naturally in a small alpine catchment in Switzerland where an acidic mountainous stream (pH 4) is neutralized successively after mixing with several neutral tributaries. The stepwise neutralization in conjunction with the large amount of precipitates provide an ideal setting for obtaining new insights into (i) the structure of naturally forming Al-hydroxysulfates, (ii) their formation mechanism, (iii) their role in controlling the solubility of Al, and (iv) their ability to lower the mobility of As. Synchrotron-based high-energy X-ray diffraction and subsequent pair distribution function analyses demonstrate that these precipitates are structurally identical to basaluminite samples obtained from acid mine drainage sites. In contrast, only minor amounts of tetrahedrally coordinated Al, as present in Al13, were identified by nuclear magnetic resonance spectroscopy. The precipitates are further characterized by elevated As concentrations up to 600 lg/g, whereas other heavy metals are at background concentrations only. Given the low As concentrations in the stream from which precipitation occurs (<0.03 mg/L), high As concentrations confirm that basaluminite serves as a highly efficient As sink, which is attributed to its high anion-exchange capacity. Chemical analysis of streamwater samples in combination with geochemical modeling show that precipitation occurs instantaneously upon mixing with neutral streams.
Moreover, our data reveal that the precipitation of basaluminite exerts a strong solubility control on dissolved Al concentrations as manifested by the quasi-constant basaluminite ion activity product observed during neutralization from pH 5 to pH 5.9. We hypothesize that in our field system, high fluoride and sulfate concentrations on the order of 100 and 1–2 mg/L,
This paper presents a probabilistic methodology based on the thermo-mechanical finite elements analysis to investigate the impact of the variability of the thermal properties of the concrete in the fire safety of structures. This is meant to evaluate if characteristic values or safety factors for the conductivity and specific heat are
required during the semi-probabilistic structural fire safety assessment. To illustrate the use of the proposed methodology, this work includes a case-study with a tunnel lining which considers the uncertainties related to the thermal and mechanical properties of the concrete, the soil load, and the temperatures described by the
standard temperature-time curve. Two failure criteria are considered: one was the maximum temperature of 300 °C at the reinforcement and the other based on the temperature-dependent strength as provided in the Eurocode EN 1992-1-2. Several finite element analyses are performed. The design of experiments is executed by a Correlation Latin Hypercube Sampling. The calculated probability of failure has different values depending on the adopted failure criteria. A sensitivity analysis using the Spearman's rank correlation coefficient was carried out and demonstrates that the uncertainty related to the specific heat has the greatest impact on the results.
This paper presents a probabilistic methodology based on the thermo-mechanical finite elements analysis to investigate the impact of the variability of the thermal properties of the concrete in the fire safety of structures. This is meant to evaluate if characteristic values or safety factors for the conductivity and specific heat are required during the semi-probabilistic structural fire safety assessment. To illustrate the use of the proposed methodology, this work includes a case-study with a tunnel lining which considers the uncertainties related to the thermal and mechanical properties of the concrete, the soil load, and the temperatures described by the standard temperature-time curve. Two failure criteria are considered: one was the maximum temperature of 300 °C at the reinforcement and the other based on the temperature-dependent strength as provided in the Eurocode EN 1992-1-2. Several finite element analyses are performed. The design of experiments is executed by a Correlation Latin Hypercube Sampling. The calculated probability of failure has different values depending on the adopted failure criteria. A sensitivity analysis using the Spearman's rank correlation coefficient was carried out and demonstrates that the uncertainty related to the specific heat has the greatest impact on the results.
Structuring over many length scales is a design strategy widely used in Nature to create materials with unique functional properties. We here present a comprehensive analysis of an adult sea urchin spine, and in revealing a complex, hierarchical structure, show how Nature fabricates a material which diffracts as a single crystal of calcite and yet fractures as a glassy material. Each spine comprises a highly oriented array of Mg-calcite nanocrystals in which amorphous regions and macromolecules are embedded. It is postulated that this mesocrystalline structure forms via the crystallization of a dense array of amorphous calcium carbonate (ACC) precursor particles. A residual surface layer of ACC and/or macromolecules remains around the nanoparticle units which creates the mesocrystal structure and contributes to the conchoidal fracture behavior. Natures demonstration of how crystallization of an amorphous precursor phase can create a crystalline material with remarkable properties therefore provides inspiration for a novel approach to the design and synthesis of synthetic composite materials.