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Methods to sequester and store atmospheric CO2 are critical to combat climate change. Alkaline-rich bioashes are potential carbon fixing materials. This work investigates potential co-benefits from mineralizing carbon in biomass ashes and partially replacing high embodied greenhouse gas (GHG) Portland cement (PC) in cement-based materials with these ashes. Specifically, rice hull ash (RHA), wheat straw ash (WSA), and sugarcane bagasse ash (SBA) were treated to mineralize carbon, and their experimental carbon content was compared to modeled potential carbonation. To understand changes in the cement-based storage materials, mortars made with CO2-treated WSA and RHA were experimentally compared to PC-only mortars and mortars made with ashes without prior CO2 treatment. Life cycle assessment methodology was applied to understand potential reductions in GHG emissions. The modeled carbonation was ∼18 g-CO2/kg-RHA and ∼180 g-CO2/kg-WSA. Ashes oxidized at 500 °C had the largest measured carbon content (5.4 g-carbon/kg-RHA and 35.3 g-carbon/kg-WSA). This carbon appeared to be predominantly residual from the biomass. Isothermal calorimetry showed RHA-PC pastes had similar heat of hydration to PC-pastes, while WSA-PC pastes exhibited an early (at ∼1.5 min) endothermic dip. Mortars with 5 % and 15 % RHA replacement had 1–12 % higher compressive strength at 28 days than PC-only mortars, and milled WSA mortars with 5 % replacement had 3 % higher strength. A loss in strength was noted for the milled 15 % WSA, the CO2-treated 5 %, and the 15 % WSA mortars. Modeled reductions in GHG emissions from CO2-treated ashes were, however, marginal (<1 %) relative to the untreated ashes.
Balancing the Mechanical Performance and Environmental Sustainability of Fiber-Reinforced Concrete
(2025)
Fiber-reinforced concrete (FRC) can have improved durability and tensile properties, potentially enabling the more efficient use of concrete and lowering greenhouse gas (GHG) emissions. Yet, systematic quantifications of the environmental impacts of FRC, particularly when paired with changes to mechanical properties and the implications for material longevity, are limited. Herein, an assessment following the life-cycle assessment methodology for four common FRCs was performed, namely, those reinforced with polyvinyl alcohol (PVA), steel (ST), polypropylene (PP), and polyethylene terephthalate (PET). The analysis was bound to a cradle-to-gate scope, and solely virgin fiber material production was considered for the environmental impacts. Coupled changes in compressive and tensile strength, environmental impacts, and the role of material longevity and cost relative to unreinforced concrete were examined. Findings from this work show that, similar to unreinforced concrete, cement remains a key source of GHG emissions in FRC production. However, in FRCs fibers can drive additional emissions by up to 55%. Notably, PVA and ST led to the highest impacts and costs, which were minimal for inclusions of PP and PET. Yet ST contributed to the greatest benefits in flexural and compressive strengths. When the effects of longevity were integrated, FRC with PP reinforcement could offer desired emissions reductions with minimal increase in use period and cost, but the other fiber reinforcements considered may need to offer longer service life extension to reduce emissions compared with conventional concrete. These results indicate that FRC can enhance mechanical performance, but fiber type selections should be informed by the design life to achieve actual GHG emissions reductions.
The use of biochar as a concrete constituent has been proposed to reduce the massive carbon footprint of concrete. Due to the low density and complex porosity of biochar, microstructural analysis of Portland cement-biochar composites is challenging.
This causes challenges to the improvement of the micro-scale understanding of biochar composite behavior. This work advances the microstructural understanding of Portland cement composites with 0, 5, and 25 volume percent (vol%) of cement replaced with wood biochar by applying common characterization techniques of mercury intrusion porosimetry (MIP), gas sorption, scanning electron microscopy, and isothermal heat flow calorimetry (HFC) in conjunction with 1H nuclear magnetic resonance (NMR) and micro-X-ray computed tomography (XCT) analysis techniques. The combination of these techniques allows a multi-scale investigation of the effect of biochar on the microstructure of cement paste. NMR and XCT techniques allow the observation and quantification of the pore space. HFC and MIP confirmed that biochar absorbs moisture and reduces the effective water-cement ratio. Gas sorption, MIP, and NMR shows that 5 vol% replacement does not significantly affect the gel and capillary pore structures. Results from XCT (supported by MIP and NMR) show that biochar can reduce the formation of larger pores.
Importantly, XCT results suggest that biochar can act as a flaw in the microstructure which could explain reductions in the mechanical properties. Overall, the mechanical properties already analyzed in the literature are consistent with the microstructural changes observed, and these results highlight the need to carefully tailor the volume fraction of biochar to control its effect on the paste microstructure.
Admixtures are important constituents to enhance the performance of concrete. They allow for more efficient use of binders which can mitigate negative environmental impacts from producing cement-based materials. Commonly used rheology modifying agents like polycarboxylate ethers or cellulose ethers are synthetic or semi-synthetic, respectively. This requires additional energy consumption for their production and global supply chains particularly for many developing regions, which will be large consumers of concrete in the future. However, many locally available bio-based polysaccharides could be effectively used instead. These polymers are often overlooked by engineers and scientists due to their limited distribution and inherent complexity, yet they represent an underleveraged source of precursors for admixtures. This study investigates the action mechanisms of some bio-based rheology modifying agents, i.e., acacia gum and miscanthus gum, and provides a comparison to a conventionally modified starch. The results show that the mechanism of action of these polymers is closely related to the composition of the mixture, mixing regime, and the composition of the aqueous phase. Depending on the agent, either plasticizing or stabilizing effects on rheology can be revealed.
When the European Union (EU) Carbon Border Adjustment Mechanism (CBAM) comes into force, importers of Portland cement and clinker will be required to purchase carbon allowances for their goods. Herein, the trade flows into the EU are mapped by country and the equivalent carbon dioxide (CO2-eq) emissions from production is modeled. Using average allowance prices, the additional cost passed to the consumer if carbon allowances had been purchased for imports in the modeled years are estimated. Together, this retrospective analysis provides insights into CBAM and the potential implications of carbon allowances on the cost of imported goods.
Industrial sectors, especially those with significant global CO2 emissions like the cement and concrete industries, are striving to achieve net-zero emissions by 2050. It is anticipated that carbon dioxide removal will be required to meet these goals. Hydrated cement in concrete can react with atmospheric CO2 to form carbonate minerals (i.e. carbonation), and in doing so, act as a carbon uptake mechanism. This carbonation process can be accelerated via various engineering interventions, such as crushing concrete after demolition. In this literature review, we examine key parameters, including porosity, exposure conditions, CO2 concentration, curing methods, coatings, and the use of supplementary cementitious materials, that affect CO2 uptake in concrete to inform better quantification of life cycle emissions. These findings can inform the feasibility of implementing carbonation as a method for reducing emissions from cement-based materials and identify data limitations that need further study for future modeling efforts. Presently, it has been estimated that 9%–17% of concrete production emissions could be re-adsorbed during use and end of life. However, such estimates of uptake have only considered limited data sets, without fully addressing the comingled effects of the parameters impacting carbonation. Further, some carbon uptake modeling efforts may require input values that are not readily available, or may be challenging to repeat, and do not accurately account for carbon fluxes over the life cycle. Findings from this review highlight the importance of development of systematic approaches to assess cradle-to-grave life cycle assessments using dynamic carbon accounting when measuring concrete carbonation.
With growing environmental impacts over the construction of and lifetime of built infrastructure, tools are needed to guide emissions reduction strategies. Herein, the EDGE Application by the International Finance Corporation (IFC) is investigated via case studies to understand hidden assumptions in the system and potential gaps in early efforts such as the EDGE tool. This work highlight questions around how baselines are selected, what are appropriate and feasible mitigation strategies, and if the quantified impacts lead to meaningful improvement.
As future populations are projected to boom, cement and concrete consumption in Africa is expected to explode. With increasing interest in the socio-economic development of this region tied to recent investment in production capacity by development banks, we investigate the current state of production, consumption and the related environmental impacts for cement in Africa. Trade and production statistics are used to map the source of production and understand regional material fluxes. A harmonized environmental impact model is assembled that represents the technology and energy sources of each area to model the production emissions from each unit of material. Herein, greenhouse gas (GHG) emissions as well as water demands, water consumption, particulate matter, and other notable air pollutants are modeled to provide information on climate related impacts as well as those directly related to human health. Median 2022 import reliance by country or area was ~37% with 15 areas fully reliant on imports. While GHG-related impacts are similar, there were shifts in particulate matter and water related impacts between imported and domestically produced materials. Together this model enables the exploration of potential impact shifting and raises important question about material sovereignty and the ability for local areas to regulate the embodied environmental impacts of the building material that are critical to future socio-economic development in their regions.
To rapidly reduce the environmental impacts from building materials, carbon-storing biochars have been proposed as a means of capturing and storing CO2 in cement-based materials. Herein we investigate the implications of various replacement rates of biochar and applications of chemical admixtures in cement-based materials. Notably, the complex microstructure of the biochar itself drives dynamic interactions between moisture content and density, thus complicating possible applications.
Chemical admixtures are an integral component of modern concrete and enable the careful tailoring of fresh and hardening properties. Herein we investigate candidate materials from the bioeconomy in idealized system and discuss the methodology as a possible rapid evaluation technique to categories the role of the candidate biopolymers at selected dosages.