Filtern
Erscheinungsjahr
Dokumenttyp
- Beitrag zu einem Tagungsband (79)
- Zeitschriftenartikel (51)
- Posterpräsentation (46)
- Vortrag (33)
- Beitrag zu einem Sammelband (8)
- Forschungsbericht (4)
- Sonstiges (2)
- Dissertation (1)
Sprache
- Englisch (151)
- Deutsch (70)
- Mehrsprachig (2)
- Polnisch (1)
Schlagworte
- Structural health monitoring (16)
- RFID sensors (14)
- Gas storage areas (12)
- Membrane-based gas sensing (12)
- Subsurface monitoring (12)
- Monitoring (11)
- Mobile Robot Olfaction (10)
- Nano aerial robot (10)
- Smart structures (10)
- Drop test (9)
Organisationseinheit der BAM
- 8 Zerstörungsfreie Prüfung (67)
- 8.1 Sensorik, mess- und prüftechnische Verfahren (67)
- 1 Analytische Chemie; Referenzmaterialien (9)
- 8.2 Zerstörungsfreie Prüfmethoden für das Bauwesen (8)
- 1.9 Chemische und optische Sensorik (7)
- 2 Prozess- und Anlagensicherheit (4)
- 2.1 Sicherheit von Energieträgern (4)
- 3 Gefahrgutumschließungen; Energiespeicher (2)
- 6 Materialchemie (2)
- 6.7 Materialsynthese und Design (2)
- 8.0 Abteilungsleitung und andere (2)
- 8.6 Faseroptische Sensorik (2)
- 1.2 Biophotonik (1)
- 1.4 Prozessanalytik (1)
- 2.0 Abteilungsleitung und andere (1)
- 3.0 Abteilungsleitung und andere (1)
- 3.1 Sicherheit von Gefahrgutverpackungen und Batterien (1)
- 3.3 Sicherheit von Transportbehältern (1)
- 5 Werkstofftechnik (1)
- 5.0 Abteilungsleitung und andere (1)
- 9 Komponentensicherheit (1)
- 9.5 Tribologie und Verschleißschutz (1)
- VP Vizepräsident (1)
- VP.2 Informationstechnik (1)
Paper des Monats
- ja (1)
Eingeladener Vortrag
- nein (33)
Thermogravimetry (TG), thermogravimetry coupled with mass spectroscopy (TG-MS) and thermogravimetry coupled with Fourier transform infrared spectroscopy (TG-FTIR) were used to characterise the thermo-oxidative behaviour of two intumescent coating materials. The temperature dependence, the corresponding volatile products and the amount of residue of the different processes were determined. Using both TG-MS and TG-FTIR results in an unambiguous interpretation of the volatile products. Characteristics such as the influence of endothermic reactions, the release of non-flammable gases, the dehydrogenation enhancing the char formation and the stability of the cellular char were discussed in detail. It was demonstrated, that TG, TG-MS and TG-FTIR are powerful methods to investigate mechanisms in intumescent coatings and that they are suitable methods in respect to quality assurance and unambiguous identification of such materials.
The influence of different organobentonites on the decomposition and the combustion behaviour of an epoxy resin were examined. The epoxy resin is a cationically polymerised cycloaliphatic epoxy resin flexibilised with poly(tetrahydrofuran) (PTHF), with hydroxyl endgroups. The bentonite was modified with either an ammonium or a phosphonium salt. The thermal decomposition of the PTHF induced by the initiator, used for the cationic polymerisation, did neither take place for the nanocomposite based on the ammonium bentonite nor for that based on the phosphonium bentonite. This improved decomposition characteristic lead to a larger time to ignition for both kinds of nanocomposites compared to the not modified polymer, which is not the case for other polymer/clay nanocomposites described in the literature. The fire behaviour was investigated using limiting oxygen index (LOI), a horizontal burner test and a cone calorimeter. The forced flaming conditions in the cone calorimeter were varied using different external heat fluxes between 30 and 70 kW · m-2. The fire behaviour of the nanocomposites was improved in comparison to the polymer, and phosphonium bentonite was superior to ammonium bentonite. The main mechanism is a barrier formation resulting in a reduction of the fire growth rate, which was more pronounced in the case of high external heat fluxes.
Polymeric intumescent coatings are fire protective materials that increase their thermal resistance when exposed to high temperatures to prevent building structures from damage. The idea of the investigation was to develop a simple test method to determine the time dependent thermal conductivity of intumescent coatings. Therefore steel plates were coated with two different intumescent systems. During cone calorimeter tests the temperature at the back side of the coated plates was measured. These results were used to calculate the time dependent thermal resistance of the protective layer with the simulation program IOPT2D for different external heat fluxes and different layer thickness.
Polymeric nanocomposites are discussed as one of the most promising advanced materials whose nanoscale effects can be exploited for industry. Layered silicate polypropylene-graft-maleic anhydride nanocomposites are investigated as a model to clarify the potential of such materials in terms of fire retardancy. The nanostructure is characterized using transmission electron microscopy (TEM) and shear viscosity. The fire behavior is characterized using different external heat fluxes in cone calorimeter, limiting oxygen index and UL 94 classification. A comprehensive fire behavior characterization is presented which enables an assessment of the materials’ potential with respect to different fire scenarios and fire tests. The influence of morphology and the active mechanisms are discussed, such as barrier formation and changed melt viscosity. To our knowledge, it is the first attempt to illuminate the concept’s strengths, such as the reduction of flame spread, and weaknesses, such as the lack of influence on ignitability, in a clear, comprehensive and detailed manner.
The cone calorimeter has become one of the most important and widely used instruments for the research and development of fire retarded polymeric materials. The paper addresses three important ways in which the principal setup influences the results factors which sometimes do not receive due consideration when drawing conclusions. The paper discusses in detail the impact on cone calorimeter results of the choice of external heat flux, the influence on the peak of heat release rate of sample thickness and thermal feedback from the back of the sample, and the influence on irradiance of the horizontal and vertical distances from the cone heater.