The solubility of carbon dioxide in three ionic liquids (ILs) under supercritical fluid condition was measured at pressures up to 32 MPa and at temperatures of 313.15, 323.15, and 333.15 K in a high-pressure view cell. The imidazolium-derivative ionic liquids 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6]), 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]), and 1-octyl-3-methylimidazolium tetrafluoroborate ([omim][BF4]) were employed in this research. The effects of pressure, temperature, nature of anion and cation as well as the water content on the solubility of CO2 in the ILs were investigated experimentally. The solubility of CO2 in the IL was higher for the ILs with longer cationic alkyl group and for the ILs with lower anion polarity. The lower the water content or the lower the temperature as well as the higher the pressure, the higher was the solubility of CO2.
A simple and efficient method of preparing composites of carbon nanotubes and titania (CNT-TiO2) is reported via a microwave-assisted synthesis in an ionic liquid, [bmim][BF4]. CNT-TiO2 nanocomposites were formed by the thermal decomposition of titanium (IV) isopropoxide (Ti(OPri)4) in the presence of CNTs under microwave irradiation. The obtained product was characterized by BET surface area, XRD, SEM, and TEM. TiO2 particles with average size of 9 nm were as anatase. The surface area of the Composites increased with an increase of CNT content. Moreover, the catalytic efficiency of the composite was investigated through the photoelectrodegradation of methylene blue.