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- Dielectric relaxation (2)
- Microplastic (2)
- Microplastics (2)
- Analysis (1)
- Analytik (1)
- Beispiele industriell angew. automat (1)
- Components and Performance of a Test Equipment (1)
- Composite (1)
- Creep behavior (1)
- Creep fatigue (1)
- Dynamic mechanical analysis (1)
- Environment (1)
- Epoxy (1)
- Evolved gas analysis (1)
- Examples (1)
- Faulted dipoles (1)
- Ferroelectric polymer (1)
- Gas chromatography (1)
- Gas chromatography mass spectroscopy (1)
- Identification and quantification of polymers (1)
- Ionic liquid (1)
- Irradiation (1)
- Kenngrößen automatischer Prüfsysteme (1)
- Kunststoff (1)
- Lattice parameters (1)
- Mikroplastik (1)
- Nitroaniline chromophore (1)
- P(VDF-HFP) (1)
- POD (1)
- Performance of Tests (1)
- Plastics (1)
- Poly(vinylidene(fluoride - hexafluoropropylene) (1)
- Pull-out tests (1)
- Pulsed laser treatment (1)
- Rafting (1)
- SC16 (1)
- Single carbon fibers (1)
- Single crystal (1)
- Stacking faults (1)
- Superalloy (1)
- Supercapacitor (1)
- Test-Related Technical Objectives and Conditons (1)
- Thermal Degradation (1)
- Thermal desorption (1)
- Thermogravimetric analysis (1)
- Thermoplastic polyurethane (1)
- Titanium Aluminides (1)
- Ultraschall-Prüfsysteme (1)
- Umwelt (1)
- Uniaxial stretching (1)
- Wasserwirtschaft (1)
- Water management (1)
- Zerstörungsfreie Prüfung (1)
- Zuverlässigkeit (1)
- ortsbezogener Messdateneinzug (1)
Structural supercapacitor electrolytes based on bicontinuous ionic liquid-epoxy resin systems
(2013)
'Structural electrolytes' retain the desirable mechanical characteristics of structural (epoxy) resins whilst introducing sufficient ionic conductivity to operate as electrolytes in electrochemical devices. Here, a series of ionic liquid–epoxy resin composites were prepared to identify the optimum system microstructure required to achieve a high level of multifunctionality. The ionic conductivity, mechanical properties, thermal stability and morphology of the cured epoxy based structural electrolytes were studied as a function of phase composition for three fully formulated high performance structural epoxy systems. At only 30 wt% of structural resin and 70 wt% of ionic liquid based electrolyte, stiff monolithic plaques with thicknesses of 2–3 mm were obtained with a room temperature ionic conductivity of 0.8 mS cm-1 and a Young's modulus of 0.2 GPa. This promising performance can be attributed to a long characteristic length scale spinodal microstructure, suggesting routes to further optimisation in the future.
Visualization of material defects - modern approaches in acoustical and electrical NDE-methods
(2008)
Increasing demands in materials quality and cost effectiveness have led to advanced
standards in manufacturing technology. Especially when dealing with high quality
standards in conjunction with high throughput quantitative NDE techniques are vital to
provide reliable and fast quality control systems. Fast NDE-systems using a high degree
of automatisation can be used for both determining the degree of integrity of the
components under test and indicating a change of production parameters as well.
However, independently of the applied NDE method and the underlying physical
principle a reliable visualisation of hidden defects within the component under test is
based on a sufficient high signal to noise ratio (SNR) and a high spatial resolution. In this
talk we illuminate two standard NDT methods such as Ultrasonic Testing and Eddy
Current Testing and show their physical principles also discussing the interaction
between sound waves or induced eddy currents with different kinds of material defects.
This introduction substantiates the attainable SNR and spatial resolution of both methods
with respect to defect sizing and defect classification. As a first future prospect we report
on the SAFT-algorithm to improve SNR and spatial resolution paving the way for a flaw
sizing approach in ultrasonic inspection. As a second modern NDE approach we
represent the use of small magnetoresistance sensor arrays for EC testing of Al-laser
welds or for testing superconducting wires. The high sensitivity and small extent of GMR
sensors results in a remarkably SNR and spatial resolution offering new visualisation
techniques for defect localisation, defect characterization and tomography-like mapping
techniques.
The temperature dependences of dielectric permittivity and elastic modulus of poly(vinylidene fluoride - hexafluoropropylene) (P(VDF-HFP)) are compared and explained by use of structural data obtained by differential scanning calorimetry and X-ray analysis. Special emphasis is put on the effect of uniaxial stretching which renders the polymer ferroelectric. It is shown that dielectric and mechanical relaxations at the glass transition (aa relaxation) are closely related and not significantly affected by stretching. It is further confirmed that stretching destroys the non-polar spherulitic crystalline structure and produces relatively small-sized polar crystallites. This manifests in the disappearence of the so-called ac relaxation which is associated to molecular motions within the spherulitic crystalline lamellae. However, there are discrepancies between dielectric and mechanical losses above the glass transition which point towards a still not described structural transition.
Relaxation behaviour of thermoplastic polyurethanes with covalently attached nitroaniline dipoles
(2002)
Thermoplastic polyurethanes with covalently attached nitroaniline chromophores exhibit a strong high-temperature relaxation associated with a glass transition rather than the typical frequency-independent loss due to the aggregation of polymer chains via hydrogen bonds. This relaxation behaviour suggests the formation of an amorphous structure without separation into soft-segment and hard-segment phases. In such a structure, a field-induced orientation of molecular dipoles is stabilised by the high viscosity of the material below its glass transition. The dipole orientation yields a pyroelectric effect caused by dipole-density changes upon thermal expansion and contraction.
The changes in phase separation are investigated by varying the chain length of the soft-phase component and studying its influence on the calorimetric, dynamic-mechanical, and dielectrical properties. Good correlation was found between differential scanning calorimetry, dynamic-mechanical analysis and dielectric spectroscopy as well as measured and calculated pyroelectric coefficients. This leads to a uniform picture of the structural changes caused by the incorporation of nitroaniline chromophores into the polyurethane structure.
In order to determine the relevance of microplastic particles in various environmental media, comprehensive investigations are needed. However, no analytical method exists for fast identification and quantification. At present, optical spectroscopy methods like IR and RAMAN imaging are used. Due to their time consuming procedures and uncertain extrapolation, reliable monitoring is difficult. For analyzing polymers Py-GC-MS is a standard method. However, due to a limited sample amount of about 0.5 mg it is not suited for analysis of complex sample mixtures like environmental samples. Therefore, we developed a new thermoanalytical method as a first step for identifying microplastics in environmental samples. A sample amount of about 20 mg, which assures the homogeneity of the sample, is subjected to complete thermal decomposition. The specific degradation products of the respective polymer are adsorbed on a solid-Phase adsorber and subsequently analyzed by thermal Desorption gas chromatography mass spectrometry. For certain identification, the specific degradation products for the respective polymer were selected first. Afterwards real environmental samples from the aquatic (three different rivers) and the terrestrial (bio gas plant) systems were screened for microplastics. Mainly polypropylene (PP), polyethylene (PE) and polystyrene (PS) were identified for the samples from the bio gas plant and PE and PS from the rivers. However, this was only the first step and quantification measurements will follow.