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- 5 Werkstofftechnik (41)
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- 9.0 Abteilungsleitung und andere (5)
- 9.4 Integrität von Schweißverbindungen (4)
- 9.6 Additive Fertigung metallischer Komponenten (4)
- 8 Zerstörungsfreie Prüfung (2)
- 8.3 Thermografische Verfahren (2)
Eingeladener Vortrag
- nein (27)
Am 9. Juli 2008 entgleiste ein Hochgeschwindigkeits-Triebzug der Baureihe 403, ICE3, bei der Ausfahrt aus dem Kölner Hauptbahnhof. Ursache dafür war der Schwingbruch einer Radsatzwelle. Im Auftrag der Staatsanwaltschaft Köln untersuchte die BAM die Schadensteile, insbesondere die gebrochene Treibradsatz-Hohlwelle.
Zunächst wurden das Drehgestell, der Antriebsstrang, die Räder, die Bremsen und die gebrochene Radsatzwelle visuell untersucht und deren Zustand dokumentiert.
Anschließend erfolgte die zerstörungsfreie Prüfung der beiden Bruchstücke der Hohlwelle mit teilmechanisierter Ultraschall-Handprüfung.
Vor der Zerlegung der Radsatzwelle wurden ausgewählte Maße kontrolliert und die Oberfläche eingehend untersucht. Nach der Probenahme und Präparation wurden die relevanten spezifizierten Eigenschaften des Wellenwerkstoffs überprüft.
Mittels Bruchflächenanalyse konnte die Startstelle des Schwingrisses lokalisiert, aufgrund der starken Sekundärschäden auf der Bruchfläche und an den Bruchkanten jedoch nicht direkt ausgewertet werden. Durch die Kombination von Mikro-Computertomographie und Ultraschall-Tauchtechnik wurden u. a. nahe der Schwingriss-Startstelle Inhomogenitäten erkannt, die durch metallographische Zielpräparation als nichtmetallische Einschlüsse identifiziert wurden. Die Größe dieser Einschlüsse ist gemäß gefordertem Reinheitsgrad unzulässig. Vergleichbare Einschlüsse in diesem hochbeanspruchten Bereich der Radsatzwelle haben vermutlich den Schwingriss initiiert.
A titanium (Ti-6242) matrix composite reinforced with continuous SiC fibers was studied. The mechanical behavior of the matrix and the composite was characterized by tensile, creep and isothermal fatigue tests at room temperature and up to 550°C. The thermo-mechanical fatigue behavior under in-phase and out-of-phase conditions was investigated for the composite between 100 and 550°C. Fracture surfaces were characterized by confocal light microscopy and by scanning electron microscopy to identify the damage mechanisms.
An extended model of the tension-compression asymmetry of single crystal nickel-base superalloys
(1996)
Die Verwendung von höherfesten, vergüteten Stählen für Radsatzwellen wird zurzeit kontrovers diskutiert. Für die zuverlässige Auslegung mit diesen Werkstoffen werden verlässliche mechanische und bruchmechanische Kennwerte benötigt. Zudem müssen die aus Prüfungen an Kleinproben und Bauteilen gewonnenen Werte konsistent sein. Das war bisher nicht immer der Fall.
In einem von der Bundesanstalt für Materialforschung und -prüfung (BAM) Berlin im Auftrag des Verbandes der Bahnindustrie in Deutschland (VDB) durchgeführten Forschungsvor- haben wurden Proben aus dem Werkstoff A5T (42CrMo4+QT), entnommen aus Original-Radsatzwellen und aus 1:1-Proben eines anderen Forschungsvorhabens, untersucht. Alle Proben haben für den Werkstoff A5T und seinem Wärmebehandlungszustand den gültigen Normen entsprechende Kennwerte im Rahmen der geforderten Eigenschaften gezeigt. Gefügefehler konnten an den vorliegenden Prüfstücken nicht nachgewiesen werden. Die vorgenommenen Wärmebehandlungen beeinflussen das Gefüge und die mechanischen Eigenschaften in der erwarteten Weise.
An extended model of the tension-compression asymmetry of single crystal nickel-base superalloys
(1996)
Unexpected wind-induced vibrations of the hangers have caused an early fatigue crack on specific steel components and joints of a railway bridge over the Elbe River at Lutherstadt Wittenberg, Germany. During regular periodic inspection a fatigue crack of approximately 240 mm length was found near a butt weld of the longest hanger. The hanger was immediately secured by welded butt straps across the crack. Based on experimental investigations of hanger vibrations additional bracings were added between the hangers to avoid wind-induced vibrations. The weld heat influence zone which was affected by high cyclic stresses was replaced by new material.
Nevertheless it was impossible to determine sufficient remaining service life for those remaining bridge components that were exposed to extreme high real load cycles. The grinding of the affected steel surfaces was the key element of the remedial actions. Furthermore, additional fracture mechanic calculations were carried out in order to assess the remaining service life of the welded joints. In this respect, the calculation approach used by Deutsche Bahn AG was compared to further procedures from the mechanical engineering field. These investigations showed that the studied, repaired components have both, bearing and fatigue capacities within the validity of standards.
Investigations on the breakdown of a heat recovery steam generator during the initial operation run
(2014)
Several years ago, in 2003, an industrial heat recovery steam generator in charge of generating process steam in a petrochemical refinery was installed and prepared for initial operation. The steam generator enclosed an evaporator section and a superheater section consisting mainly of bundles of tubes with the longest up to several metres in length. During initial operation test runs severe leakages in the evaporator and superheater modules became noticeable. The test runs were stopped and after disassembly, through-wall cracks in several tube bends were found. BAM was commissioned to carry out the investigations in order to find out the reasons for the failure of the tubes. During on-site inspection a number of relevant damaged components and parts were selected and taken away to the laboratories for detailed inspection. Planned analyses were to comprise metallographic as well as fractographic investigations, mechanical fatigue testing and experimental as well as finite element vibration analyses on specimens and components. Soon, the fracture mechanism was found to be mechanical fatigue due to the fact that the examined fracture surfaces showed the very characteristic beachmarks and colouring patterns. To identify the particular loading and time at which crack initiation and crack propagation took place, experimental and numerical vibration analyses of specific tubes as well as mechanical fatigue tests on tube bends were carried out. Thus it was possible to identify the eigenfrequencies of individual tubes, to estimate the dynamic response as well as the nominal stresses and, hence, experimentally characterise the in-service fatigue strength of the components. Mechanical and thermal comparative tests on tube bends were performed simulating the conditions during the initial test run in order to get crack surfaces comparable to that of the originally damaged components. Thereby it became obvious that the fatigue cracks were initiated by vibrations the tube bundles were exposed to during rail transport from the manufacturers site to the place of installation. Based on these results, the damaged components could be repaired or exchanged without modification of the construction, but the rules relating packaging and securing for shipping had to be revised.
On October 24th 1950 the 'Freedom Bell' rung for the first time in the tower of the former West Berlin town hall. One year after the Berlin blockade and at a first climax of the 'Cold War', the 'American National Committee for a Free Europe' donated the bell to the city of West Berlin. The bronze bell has a weight of about 10 tons. Its clapper has a length of 2.40 m and a weight of nearly 1 ton. In 1966 the hanging of the clapper and in 1979 the clapper of the bell broke down. Both failures were found to be caused by fatigue fracture. In 1974, a crack in the bell body was detected. After years of periodic monitoring using non-destructive testing, the crack was closed in 2001.
CO2 streams captured from power stations or industrial plants may contain impurities that impact the consecutive steps of the CO2 capture and storage (CCS) chain. As the basis for an optimization of CO2 purity over the whole CCS chain, impacts of different impurities were investigated at key steps including studies on (i) corrosion of metallic materials in CO2 streams and brine, (ii) fluid and interfacial properties as a function of pressure, temperature and CO2 stream composition and their implications for CO2 transport, injection and geological storage, (iii) costs of different pipeline design options, (iv) geochemical alterations at typical reservoir conditions and their implications for geomechanical rock properties. Major findings are synthesized for two exemplary single source-single sink CCS chain scenarios involving CO2 stream compositions typical for pre-combustion capture and oxyfuel combustion. Recommendations for material selection for compression, transport and injection were derived for various CO2 stream compositions. To reliably control corrosion, a limitation of water contents to 50 ppmv is recommended for pipeline transportation of all CO2 streams. At geological storage conditions, the presence of either O2, NOx or SO2 only weakly affected fluid-mineral/rock interactions that still impacted geomechanical rock properties.
Application of 4Q-BSE detector and dedicated software enables 3D surface measurements of fracture samples in SEM. 3D surface measurement is independent from magnification and material invariant. Quantitative height measurements require careful detector adjustment and system calibration. Live 3D view allows a fast assessment of topographical features. In addition to SE and BSE imaging, 3D surface data help to analyse and interpret fracture samples.
Aufbau einer Wissensbasis zu Bruchflächen und Gefüge in der fraktographischen online-Datenbank
(2016)
Fraktographisches Wissen in Form von Vergleichsbildern von Bruchflächen werden in einer fraktographischen online-Datenbank zusammengetragen und der interessierten Fachöffentlichkeit zur Verfügung gestellt. Zu diesem Zweck werden Vergleichsversuche durchgeführt, insbesondere Schwingversuche. Die erzeigten Bruchflächen werden makroskopisch und mikroskopisch analysiert und dokumentiert. Das dazu gehörige Werkstoffgefüge wird ebenfalls dargestellt. Das Augenmerk der aktuellen Arbeiten liegt daher auch auf Zusammenhängen zwischen Bruchmechanismen und Gefügestrukturen. Zur Einleitung wird eine Schadensanalyse von Adolf Martens aus dem Jahre 1884 vorgestellt.“
Synergistic effects of impurities in the condensate on the corrosion of CO2 transport pipeline
(2017)
For the reliability of transport pipelines the corrosion resistance of the materials used needs to be determined in conditions, which are possible during the transport process. In some situations condensation of components out of the CO2 stream can occur. To study the effect of condensate on transport pipeline steel, a “worst-case scenario” gas mixture, containing 2.5 % H2O, 1.8 % O2, 1000 ppmv NO2, and 220 ppmv SO2, was proposed, fed (1.5 L/min) into a glass reactor containing coupon-shaped specimens for 120 600 h at 278 K (to simulate the underground pipeline transport), and resulted in the condensate containing 0.114 M H2SO4 and 0.0184 M HNO3 (pH 2.13). Basing on this “original” condensate, exposure tests and electrochemical characterization together with pH and conductivity in CO2 saturated condition at the same temperature were carried out. The role of each gas impurity and the combination of them, when the condensate is formed, was studied by investigating the role of individual and varying combination of acidic components in the condensate on the corrosion behaviors of the commercial pipeline-steel (L360NB). It can be concluded that although the condensation of NOx in form of HNO3 causes faster corrosion rate, it is the condensation of SOx or the combination of SOx and NOx that may cause much more severe problems in form of localized and pitting corrosions. Different to the corrosion products formed in CO2 atmosphere without impurities (mainly iron carbonate) the corrosion products resulted from these acidic condensation have no protectability, indicating the need of controlling gas quality during the transportation within the pipeline network.
Carbon Capture Utilization and Storage (CCUS) is a promising technology for the reduction of CO2 emissions, e.g. from fossil-fuel operated power plants or cement mills. Crucial points for a sustainable and future-proof CCUS procedure are reliability and cost efficiency of the pipeline transport network. Due to the absence of certified benchmarks for upper limits, systematic experiments with impurities in the CO2 stream were carried out. For oxidation processes SO2 and NO2 acted as corrosive components, and for reductive atmosphere H2S. Carbon steel L485MB (pipeline), martensitic steel 1.4313 (compression) and austenitic steel 1.4562 (injection) were selected as specimens. Experiments were performed at 0 bar or 100 bar and within a temperature range 278 K ≤ T ≤ 313 K. High-alloyed Cr-Ni steels revealed no corrosion (1.4562, 1.4313), while for carbon steel considerable corrosion was observed. The type and intensity of corrosion was strongly coupled with the applied corrosive species and the level of humidity in the CO2 stream, leading to different compositions of acidic condensates. Applying a reducing atmosphere results in very little corrosion rates, but provokes pitting corrosion. In contrast, oxidizing or mixed settings lead to a clearly increased growth of the corrosion layer, but exhibit shallow uniform corrosion. Exceptional nitric acid results in intergranular corrosion. Investigations on the specimens were carried out by optical microscopy, XRD, SEM/EDX, and AAS/IC.
Carbon Capture Utilization and Storage (CCUS) is a promising technology for the reduction of CO2 emissions from fossil-fuel operated power plants, steel and cement mills or refineries. Crucial points for a sustainable and future-proof CCUS procedure are reliability and cost efficiency of the pipeline transport network especially concerning corrosion risks under impurities and moisture in the CO2 stream. Recent studies have shown that even high alloyed steels might be susceptible to general and/or localized corrosion caused by condensates. It was concluded from our study on carbon steels in normal and high pressure conditions, that the combination of these gas impurities, resulted in the acidic condensate, is not only a simple sum of each corrosive effect, but highly accelerates the corrosion rate of the pipeline steel, indicating the need of dynamic tests before installing the network pipeline system.
Die Grundlagen der Metallographie wurden in der zweiten Hälfte des 19. Jahrhunderts von Henry Clifton Sorby in England und Adolf Martens in Deutschland gelegt. Den verfügbaren Quellen nach erfolgten diese Arbeiten unabhängig voneinander. In diesem Beitrag werden die Beiträge von Adolf Martens und Emil Heyn zur Etablierung der Metallographie als ein eigenständiges Fach im Rahmen der Metallkunde dargestellt. Dabei werden Aspekte der Werkstoffprüfung, der Fraktographie und der Schadensanalyse einbezogen. Abschließend wird die führende Rolle dieser Pioniere der Metallkunde bei der Gründung der Deutschen Gesellschaft für Materialkunde (DGM) sowie des Deutschen Verbands für Materialforschung und -prüfung (DVM) gewürdigt.
CCUS-Technologie (CO2-Abtrennung; Nutzung und Speicherung, engl. Carbon Dioxide Capture, Utilization and Storage) gilt als eine vielversprechende Methode zur Abschwächung des Beitrags von fossilen Emissionen zur globalen Erwärmung. Dabei wird das in den Verbrennungsprozessen entstandene Treibhausgas aufgefangen, zu verschiedenen Lagerstätten transportiert und langzeitig gespeichert bzw. einer chemischen Nutzung zugeführt.
In bisher veröffentlichten Untersuchungen wurde gezeigt, dass die CO2-Transport-Pipelines in hohem Maße gefährdet sind, wenn sie korrosiven Begleitstoffen des CO2-Stroms, wie SOx, NOx bei einem hohen Wasserdampfanteil ausgesetzt sind. Screening-Tests zeigten, dass bei einer Konzentration von 1000 ppmv H2O die Reaktionen und Kondensation von SO2 und NO2 mit O2 und H2O zu Säuretropfen (pH ~ 0,5) auf der Oberfläche von Metall-Prüfkörper und Gefäß führen. Die Werkstoffe 1.0582, 1.8977, 1.4313 und 1.4562 wurden in CO2-gesättigtem Kondensat mit unterschiedlichem Verhältnis der säurebildenden Komponenten untersucht. Diese Studien zeigten grundsätzlich den Mechanismus sowie die Rolle jedes CO2-Strom-Begleitstoffes auf den Korrosionsprozess. Allerdings spiegeln die bei Auslagerung und elektrochemischen Messungen in der künstlichen CO2-gesättigten Kondensat-Lösung auftretenden Bedingungen nicht im Detail die Realität in der Praxis, wo sich nur Tröpfchen bilden, wider.
Diese Arbeit konzentriert sich auf den Korrosionsprozess von Kondensat in Form von Tröpfchen, auf der Oberfläche von Rohrleitungswerkstoffen unter CO2-Atmosphäre bei 5 °C (Simulation des Transportzustandes). Die Experimente wurden nicht nur für Auslagerungsversuche, sondern auch für elektrochemische Tests mit nur einem Tröpfchen (weniger als 20 µL) konzipiert. Die Auslagerungs-versuche wurden sowohl unter Normaldruck als auch bei hohem Druck (> 70 bar) durchgeführt, wobei das CO2 als dichte – den Tropfen umgebende - Phase vorliegt. Die korrodierten Prüfkörper wurden rasterelektronenmikroskopisch (REM) und mittels Energiedispersiver Röntgenspektroskopie (EDX) analysiert, um nicht nur Korrosionsform, sondern auch die Elementverteilung der Korrosionsprodukte zu zeigen.
This work examined the droplet corrosion of CO2 pipeline steels caused by impurities in CO2 supercritical/dense phase at 278 K, simulating the underground transport condition. The wetting properties of carbon steels (X52 and X70) as well as martensitic steel UNS S41500, and superaustenite UNS N08031 were studied by contact angle measurement, revealing reactive wetting behavior of carbon steels. Exposure tests with CO2 saturated water droplet on steel surface showed that the impurities (220 ppmv SO2 and 6700 ppmv O2) diffused into the droplet and then reacted with metal coupons in supercritical/dense phase condition, forming the corrosion product instantly during pumping process. Due to the active wetting behavior, the carbon steels suffered from heavily attack, while negligible corrosion product was observed in cases of martensitic steel UNS S41500 and superaustenite UNS 08031 coupons. Condensation experiments that were carried out on fresh polished coupons in CO2 with 1200 ppmv H2O showed that the formation and aggregation of droplet is dependent on the presence of impurities. Without SO2 and O2, the same concentration of H2O did not cause observable corrosion process after a week of exposure. With 220 ppmv SO2 and 6700 ppmv O2 even low water concentration (5-30 ppmv) still resulted in heterogeneous nucleation and subsequent growth of droplets, leading to corrosive process on carbon steel surface albeit to a lesser extent.
In this work, the focus was set on the corrosion process of condensate as drops on the surface of carbon steels (X52, X70), martensitic steel UNS S41500, and superaustenite UNS N08031 in CO2 atmosphere with impurities at 278 K (to simulate the transportation condition in a buried pipeline). Exposure tests were performed at both normal pressure and high pressure where CO2 is supercritical or in dense phase. The drop, 1 ‑ 10 μL in volume, was prepared by dropping CO2 saturated ultra-pure water onto the surface of steel coupons in a one-liter-autoclave. The CO2 gas stream, simulating the oxyfuel flue gas with varying concentration of impurities (SO2 and O2 ), was then pumped into the autoclave to observe the condensation and corrosion impacts of impurities. Comparable exposure tests were carried out with the same gas mixture and the same volume of water as vapor to observe the drop formation and the corrosion process that follows. The wettability and stability of drops on the surface of steel coupons in CO2 supercritical/dense phase environment was evaluated additionally by contact angle measurement.
In July 2008 an ICE3 high speed train rated for 330 km/h service speed derailed during departure from Cologne, Central Station, Germany, due to fatigue failure of one of the driving axles. The train was emergency stopped immediately and, due to low travel speed at this point, no serious injuries occurred to passengers. Referring to public interest, the public attorneys office solicited the German Federal Institute for Materials Research and Testing (BAM) for the analysis of the root cause.
No deviations from specification were found in the geometries of the basic parts of the bogie or the wheelset assembly. Inspection of the axle fragments using standard acoustic non-destructive testing (NDT) techniques revealed no additional cracks and no indications of oversized discontinuities. Metallographic and chemical inspection of the axle material and its microstructure revealed all parameters to be acceptable except for an elevated impurity level.
The fracture surfaces of the axle fragments were heavily damaged due to some continued travel after final breakage on the high speed line before Cologne Central Station. Extensive visual inspection of the remaining beachmarks was carried out to find the origin of the fatigue crack. The region of the crack origin was located near the axle surface but could not be analysed in detail due to secondary damage. Fatigue was identified as the mechanism of crack growth until final fracture, but the reasons for crack initiation initially remained unclear.
Neither standard NDT techniques nor metallography according to the relevant axle specifications were able to identify inclusions in the material that could have served as crack initiation sites. However, discontinuities were detected near the crack origin in micro computer tomography and ultrasonic immersion testing. Subsequent metallographic sample preparation was targeted to specific areas based on the location coordinates of the flaws identified by these NDT techniques. These revealed non-metallic inclusions that were much larger than admissible for the relevant specifications. It is likely that the fatigue crack in the highly loaded axle volume initiated at those non-metallic inclusions.
Condensates from the gas stream in simulated CO2 transport pipelines have been identified during the experiments in the laboratory. Because of their acidic origin the corrosion resistance of pipeline steels used for CCS (carbon capture and storage) technology might be limited. Over the last years it has become clear that the amount of water and acid building constituents in the CO2 stream has to be controlled very well. In this work, condensates formed in experiments using gaseous CO2 containing high amounts of water, NO2 and SO2 were analyzed, replicated, and used for extensive electrochemical experiments. These highly acidic condensates were enriched with CO2 and then applied to characteristic steels planned to use in the CCS transport chain. Even high alloy steels are susceptible to localized corrosion under these conditions. The results implicate that condensation of aggressive acid droplets has to be avoided or the locations where condensation takes place have to be controlled extensively.