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Organisationseinheit der BAM
Eingeladener Vortrag
- nein (1)
To properly understand and assess the long-term behaviour of geosynthetic materials it is necessary to investigate the various types of possible degradation mechanims. This includes both chemical and mechanical behaviour, and sometimes even their interactions with one another. Clearly, chemical degradation of geosynthetics depends on the polymer type. For example, polyolefins are vulnerable to oxidation; polyesters are susceptible to hydrolysis; and plasticizers can leach from polyvinyl chloride. This paper describes the concept of these three types of degradation, but focuses on the oxidation of polyolefins since the majority of the geosynthetics is made from this type of polymer. The methods used to predict the lifetime of antioxidants and service life of the geosynthetic material will be illustrated. Furthermore, the influence of temperature, pressure, and ultraviolet light on the service life are also demonstrated. Finally, the current specifications targeting the longevity of different geosynthetics are presented.
Regarding mechanical degradation, the paper mainly focuses upon the creep deformation of geogrids and stress crack resistance (SCR) of polyethylene geomembranes and geopipe. The method to assess stress crack resistance is described, and the microscopic mechanisms that lead to such failure are explained. For creep evaluation, different acceleration tests are presented and their applicability with respect to the different types of polymers is illustrated. In addition, the long-term shear behaviour of geocomposites and geosynthetic clay liners is presented.
A new type of test sample for the determination of lateral resolution in surface analysis is presented. The certified reference material BAM-L002 Nanoscale strip pattern for length calibration and testing of lateral resolution is an embedded cross-section of epitaxially grown layers of AlxGa1-xAs and InxGa1-xAs on GaAs substrate. The surface of the sample provides a flat pattern with strip widths of 0.4-500 nm. The combination of gratings, isolated narrow strips and sharp edges of wide strips offers improved possibilities for the calibration of a length scale, the determination of lateral resolution and the optimization of instrument settings. The feasibility of the reference material for an analysis of lateral resolution is demonstrated for SIMS.
Different, partly complementary and partly redundant characterization methods were applied to study the transition of magnetite, graphite and MoS2 powders to mechanically alloyed nanostructures. The applied methods were: Transmission electron microscopy (TEM), Mössbauer spectroscopy (MS), Raman spectroscopy (RS), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The main objective was to prepare a model material providing the essential features of a typical tribofilm forming during automotive braking, and to assess the impact of different constituents on sliding behaviour and friction level. Irrespective of the initial grain size, the raw materials were transferred to a nanocrystalline structure and mixed on a nanoscopic scale during high energy ball milling. Whereas magnetite remained almost unchanged, graphite and molybdenum disulphide were transformed to a nanocrystalline and highly disordered structure. The observed increase of the coefficient of friction was attributed to a loss of lubricity of the latter ingredient due to this transformation and subsequent oxidation.
Se presenta una guía completa del procedimiento experimental para la determinación del valor umbral ΔKth intrínseco y caracterización de curvas FCGR sobre el acero de alta resistencia S960QL empleando probetas de pequeña escala. El análisis se realiza comparando probetas SENB de diferentes geometrías, distinguiendo entre “convencionales” y “miniatura”. Las primeras con espesor (B) de 6 mm y anchura (W) de 19, y las segundas con B = 3 y dos valores distintos de W, 4 y 6 mm. A fin de identificar el valor umbral ΔKth intrínseco, la relación de cargas (R) aplicada en todos los ensayos fue 0,8. La técnica de caída de potencial (DCPD) se utilizó para la monitorización del tamaño de grieta a lo largo de los ensayos.
La evaluación de los resultados experimentales confirma la equiparación de resultados entre las distintas geometrías y configuraciones de ensayo practicadas, así como la viabilidad de emplear probetas de pequeña escala en la determinación del valor umbral ΔKth intrínseco. Esto abre nuevas perspectivas en lo relativo al empleo de probetas de reducidas dimensiones en la caracterización de materiales a fatiga. A su vez, permite ofrecer una serie de recomendaciones para reproducir con éxito ensayos semejantes utilizando probetas de pequeñas dimensiones de acero y otros materiales metálicos.
Ausgehend von den verstärkt auftretenden AKR-Schäden an den vor 2005 hergestellten BAB-Abschnitten verfolgte das Forschungsvorhaben zwei Ziele. So sollte einerseits die Ursache für die mit der AKR-Schadensentwicklung einhergehende Dunkelfärbung der Oberfläche der Betonfahrbahndecke im Fugenbereich ermittelt werden. Andererseits galt es, ausgehend von der Zustands- und Schadenserfassung das AKR-Restschädigungspotenzial der Prüfkörper aus je drei ein- und zweischichtig ausgeführten, unterschiedlich stark AKR-geschädigten BAB-Abschnitten vergleichend zu bewerten. Folgende Ergebnisse wurden u. a. erzielt:
1. Dunkelfärbung Experimenteller Nachweis mit kombinierter insitu-
Feuchtemessung mit Radar (integral) und NMR (tiefenaufgelöst), dass Dunkelfärbung der Oberfläche der Betonfahrbahndecke im Fugenbereich auf eine erhöhte Durchfeuchtung der Betonrandzone zurückzuführen ist; erfolgreiche Validierung der ZfP-Ergebnisse mit Darr-Wäge-Versuch.
2. Zustand beprobter BAB-Abschnitte und schadenskategoriespezifische
Bewertung der AKR-Prüfverfahren:
• Auffinden von Horizontalrissen im Bereich der Querscheinfuge bei allen AKR-geschädigten BAB-Abschnitten,
• Ermittlung mittlerer Eindringtiefen bei Natrium von maximal 20 bis 45 mm und bei Chlorid von maximal 15 bis 60 mm im Entnahmezustand;
keine Korrelation mit der AKR-Schadenskategorie des jeweiligen BAB-Abschnitts,
• Nachweis gleichzeitig auftretender SEB bei allen AKR-geschädigten BAB-Abschnitten im Entnahmezustand,
• keine signifikante Verminderung der Spaltzugfestigkeit durch die verstärkte AKR am Plattenrand,
• Ermittlung eines erhöhten AKR-Restschädigungspotenzials bei vier der sechs beprobten BAB-Abschnitte primär mittels AKR-erformanceprüfungen,
• Ermittlung höherer Dehnungen bei Performanceprüfungen aus Ober- und Unterbeton bestehenden Halbschalen, als an separat aus Ober- und Unterbeton gewonnenen Prismen,
• Unauffälliges Verhalten nahezu aller bei der Performanceprüfung auffälligen Bestandsbetone im 40°C- und 60°C-Betonversuch; vermutete Ursache: mit LIBS nachgewiesene hohe und tiefreichende Auslaugung der Alkalien.
Directing nanoparticles to the nucleus by attachment of nuclear localization sequences (NLS) is an aim in many applications. Gold nanoparticles modified with two different NLS were studied while crossing barriers of intact cells, including uptake, endosomal escape, and nuclear translocation. By imaging of the nanoparticles and by characterization of their molecular interactions with surface-enhanced Raman scattering (SERS), it is shown that nuclear translocation strongly depends on the particular incubation conditions. After an 1 h of incubation followed by a 24 h chase time, 14 nm gold particles carrying an adenoviral NLS are localized in endosomes, in the cytoplasm, and in the nucleus of fibroblast cells. In contrast, the cells display no nanoparticles in the cytoplasm or nucleus when continuously incubated with the nanoparticles for 24 h. The ultrastructural and spectroscopic data indicate different processing of NLS-functionalized particles in endosomes compared to unmodified particles. NLS functionalized nanoparticles form larger intraendosomal aggregates than unmodified gold nanoparticles. SERS spectra of cells with NLS-functionalized gold nanoparticles contain bands assigned to DNA and were clearly different from those with unmodified gold nanoparticles. The different processing in the presence of an NLS is influenced by a continuous exposure of the cells to nanoparticles and an ongoing nanoparticle uptake. This is supported by mass-spectrometry-based quantification that indicates enhanced uptake of NLS-functionalized nanoparticles compared to unmodified particles under the same conditions. The results contribute to the optimization of nanoparticle analysis in cells in a variety of applications, e.g., in theranostics, biotechnology, and bioanalytics.
Multifunctional composite nanoprobes consisting of iron oxide nanoparticles linked to silver and gold nanoparticles, Ag–Magnetite and Au–Magnetite, respectively, were introduced by endocytic uptake into cultured fibroblast cells. The cells containing the non-toxic nanoprobes were shown to be displaceable in an external magnetic field and can be manipulated in microfluidic channels. The distribution of the composite nanostructures that are contained in the endosomal system is discussed on the basis of surfaceenhanced Raman scattering (SERS) mapping, quantitative laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) micromapping, and cryo soft X-ray tomography (cryo soft-XRT). Cryo soft-XRT of intact, vitrified cells reveals that the composite nanoprobes form intra-endosomal aggregates. The nanoprobes provide SERS signals from the biomolecular composition of their surface in the endosomal environment. The SERS data indicate the high stability of the nanoprobes and of their plasmonic properties in the harsh environment of endosomes and lysosomes. The spectra point at the molecular composition at the surface of the Ag–Magnetite and Au–Magnetite nanostructures that is very similar to that of other Composite structures, but different from the composition of pure silver and gold SERS nanoprobes used for intracellular investigations. As shown by the LA-ICP-MS data, the uptake efficiency of the magnetite composites is approximately two to three times higher than that of the pure gold and silver nanoparticles.
Linear sensor for areal subsurface gas monitoring - calibration routine and validation experiments
(2014)
Membrane based linear gas sensors and fiber optical sensors feature similar geometries and complement each other in quantities to be measured. To the author's best knowledge, it is the first time that these sensors are combined to a multifunctional sensor for distributed measuring of gas concentrations, temperature, and strain. Objective is a comprehensive monitoring of underground gas storage areas. In the presented project a 400 m² test site and a corresponding laboratory system were just built up to characterize, validate, and optimize the combined sensor. Application of the sensor lines in a grid structure should enable spatial resolution of the measurement data and early detection of relevant events, as gas leakage, temperature change, or mechanical impact. A Calibration routine was developed which can be applied subsequent to underground installation. First measurement results indicate the potential of the method, with regard to highly topical energy transport and storage issues.
One of the main unsolved issues of under-ground storages for, e.g., CO2, H2, and natural gas is the comprehensive surveillance of these areas with reasonable effort and costs. Conventional sensors (e.g., soil air probes or borehole probes), however, can only be used for punctual or locally limited measurements; further their application can cause structural influences (invasive application).
In this paper, we describe in detail the setup of a CO2 injection soil test field. This test field will be used to enhance and validate an innovative ap-proach for distributed subsurface monitoring of gas storage areas. To the author’s knowledge, this is the first time that, for this purpose, a test field is built in an application relevant scale.