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Eingeladener Vortrag
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The Micro Structure of Traditional Brazilian Lime Plasters - The Custom House of Florianopolis
(2005)
Results are reported from a pilot study under the Consultative Committee for Amount of Substance (CCQM) to compare measurements of and resolve any relevant measurement issues in, the amount of thermal SiO2 oxide on (100) and (111) orientation Si wafer substrates in the thickness range 1.5 - 8 nm. As a result of the invitation to participate in this activity, 45 sets of measurements have been made in different laboratories using 10 analytical methods: medium-energy ion scattering spectrometry (MEIS), nuclear reaction analysis (NRA), RBS, elastic backscattering spectrometry (EBS), XPS, SIMS, ellipsometry, grazing-incidence x-ray reflectrometry (GIXRR), neutron reflectometry and transmission electron microscopy (TEM). The measurements are made on separate sets of 10 carefully prepared samples, all of which have been characterised by a combination of ellipsometry and XPS using carefully established reference conditions and reference parameters.
The results have been assessed against the National Physical Laboratory (NPL) data and all show excellent linearity. The remaining data sets correlate with the NPL data with average root-mean-square scatters of 0.15 nm, half being better than 0.1 nm and a few at or better than 0.05 nm. Each set of data allows a relative scaling constant and a zero thickness offset to be determined. Each method has an inherent zero thickness offset between 0 nm and 1 nm and it is these offsets, measured here for the first time, that have caused many problems in the past. There are three basic classes of offset: water and carbonadeous contamination equivalent to ~1 nm as seen by ellipsometry; adsorbed oxygen mainly from water at an equivalent thickness of 0.5 nm as seen by MEIS, NRA, RBS and possibly GIXRR; and no offset as seen by XPS using the Si 2p peaks. Each technique has a different uncertainty for the scaling constant and consistent results have been achieved. X-Ray photoelectron spectroscopy has large uncertainties for the scaling constant but a high precision and, critically, if used correctly, has zero offset. Thus, a combination of XPS and the other methods allows the XPS scaling constant to be determined with low uncertainty, traceable via the other methods. XPS laboratories returning results early were invited to test a new reference procedure. All showed very significant improvements. The reference attenuation lengths thus need scaling by 0.986 ± 0.009 (at an expansion factor of 2) deduced from the data for the other methods. Several other methods have small offsets and, to the extent that these can be shown to be constant or measurable, then these methods will also show low uncertainty. Recommendations are provided for parameters for XPS, MEIS, RBS and NRA to improve their accuracy.
Glass-ceramics containing Ca2KNa(PO4)2 as the main crystalline phase have a solubility which is 8 times higher than that of alpha-tricalcium phosphate ceramics. When using these compositions in drug delivery systems, especially in bone, it is necessary to create a material with a high open porosity. A Ca2KNa(PO4)2-based glass-ceramic was prepared from a borosilicate glass melt. The processed material includes minor amounts of boron which are low enough for medical application. Tissue response was studied using an animal model. Particles were implanted in rabbit femurs. Bone and soft tissue development occurred at the particle interfaces. In general, most particles were enclosed in the network of trabecular bone. The advantages of using a biomaterial with high porosity (pore size of 1-3 micron), together with rapid biodegradation, bioactivity and biocompatibility, despite traces of boron, were shown. 4 refs.
In vivo test of a high porous rapidly resorbable dicalcium potassium sodium phosphate glass-ceramics
(2002)
Fabrication of carbon/silica hybrid materials using cationic polymerization and the sol-gel process
(2002)
Zur Alterung von Smalten - Materialuntersuchungen bei der Restaurierung eines Gründerzeit-Mosaiks
(2001)
Das Mosaik "Muse der Kunst" war in Berlin-Mitte mehrere Jahrzehnte hinter einer Vermauerung verborgen, bevor es nun wiederentdeckt und restauriert wurde. Die Smalten zeigten zum Teil Risse, Verkrustungen und Farbveränderungen in Folge von Alterungsprozessen der historischen Materialien. Einzelne Deckgläser von Goldsmalten waren abgesprengt.
Zur genaueren Kenntnis des Einflusses der Ermüdungsbelastung auf das Versagen von Beton wurde das Ermüdungsverhalten von gekerbten Betonbalken in kraft- und verformungsgeregelten Dreipunktbiegezugversuchen untersucht. Für die verformungsgeregelten Versuche wurde eine neuentwickelte Versuchstechnik angewendet, mit der auch unter hochzyklischer Beanspruchung mit Lastspielzahlen von bis zu einer Million Zyklen sowohl der ansteigende als auch der abfallende Ast in einem Kraft-Verformungsdiagramm aufgezeichnet werden kann.