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- Rheology (11)
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- Nano-silica (4)
- Self-compacting concrete (4)
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Organisationseinheit der BAM
Waste sludge, a solid recovered from wastewater of photovoltaic-industries, composes of agglomerates of nano-particles like SiO2 and CaCO3. This sludge deflocculates in aqueous solutions into nano-particles smaller than 1 µm. Thus, this sludge constitutes a potentially hazardous waste when it is improperly disposed. Due to its high content of amorphous SiO2, this sludge has a potential use as supplementary cementitious material (SCM) in concrete. In this study the main properties of three different samples of photovoltaic's silica-rich waste sludge (nSS) were physically and chemically characterized. The characterization techniques included: scanning electron microscopy (SEM), X-ray energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), nitrogen physical adsorption isotherm (BET method), density by Helium pycnometry, particle size distribution determined by laser light scattering (LLS) and zeta-potential measurements by dynamic light scattering (DLS). In addition, a dispersability study was performed to design stable slurries to be used as liquid additives for the concrete production on site. The effects on the hydration kinetics of cement pastes by the incorporation of nSS in the designed slurries were determined using an isothermal calorimeter. A compressive strength test of standard mortars with 7% of cement replacement was performed to determine the pozzolanic activity of the waste nano-silica sludge. Finally, the hardened system was fully characterized to determine the phase composition. The results demonstrate that the nSS can be utilized as SCM to replace portion of cement in mortars, thereby decreasing the CO2 footprint and the environmental impact of concrete.
Varying ambient temperatures in plants or on construction sites during casting of SCC can cause serious problems affecting the fresh concrete performances, such as rheological properties and setting time, with consequences for the hardened properties in the structure. By sensible choices of the components, the robustness of SCC mixtures against temperature variations can be improved. However, this aspect has not been the focus of intensive research yet. In this study the effects of varied ambient temperatures on the early performance of differently composed SCC mixtures are investigated, with emphasis on changes in rheology, early deformations, heat evolution and setting. Focus is placed on the study of the influence of the polycarboxylate ether molecule type as well as different viscositymodifying agents on the temperature robustness. Effects on the relevance for practical concrete applications are evaluated, which will provide a reliable framework of possible actions on the appropriate use of admixtures for SCC.
Effects of amorphous nano-silica additions on mechanical and durability performance of SCC mixtures
(2012)
In the recent years the application of nanotechnology in building materials has increased
exponentially. One of the most referred and used nano-materials is amorphous silica with
particles size in the nano-range, even though its application and effect in concrete has not been
fully understood yet. It has been reported that nano-silica (nS) addition increases the
compressive strength and reduces the overall permeability of hardened concrete due to the
pozzolanic properties which are resulting in finer hydrated phases (C-S-H gel) and densified
microstructure (nano-filler and anti leaching effects). These effects enhance the durability of
concrete structures such as bridges, quays or off-shore oil facilities in marine environments.
In this study two different types of nano-silica were applied in self-compacting concrete (SCC),
both having similar particle size distributions (PSD) but produced in two different processes
(fumed powder silica and precipitated silica in colloidal suspension). The influence of nanosilica
on SCC was investigated with respect to the properties of concrete in the fresh state
(workability) and hardened state (mechanical properties and durability). Additionally, the
densification of microstructure of the hardened concrete was verified by SEM and EDS analyses.
The obtained results demonstrate that an efficient use of nano-silica in SCC can improve its
mechanical properties and durability. Considering the reactivity of the two nano-silica studied,
colloidal type shown more reactivity at early age, which influenced all the final SCC properties.
Since its invention in the early 1990’s, self-consolidating concrete has never become well established in the ready-mix sectors worldwide. The reason for this can be mainly found in the fact that the sophisticated compositions are sensitive against changing environments. This lack of robustness can be attributed to the interaction between cement hydration reaction and high range water reducing agent (HRWRA). Understanding the relevant mechanisms that control the initial flow performance as well as the flow retention helps optimizing SCC mixtures that perform either steadily in one specific environment or that perform largely similarly at steadily changing environments.
This paper depicts how HRWRAs interact with clinker and hydration phases and discusses the important role of the charge density of a polycarboxylic HRWRA in the way the rheology is affected. Based on rheometric results and observations of the Vicat setting times, it is shown that increasing charge densities of the HRWRA and decreasing water to powder ratios (w/p) reduce the flow retention and have lesser retarding effect on the setting. Based on the discussion, optimization procedures for the mixture composition and the HRWRA modification are suggested to achieve optimized performance for varying environmental situations or highest robustness for specific conditions.
Selbstverdichtender Beton verhält sich unter Temperatureinfluss anders als Normalbeton, da die Rheologie neben der fortschreitenden Hydratation zusätzlich durch die von der Zeit und dem Hydratationsfortschritt abhängige Adsorption von Fließmitteln beeinflusst wird. Anhand rheometrischer Betonversuche an SVB unterschiedlicher Entwurfskonzepte mit variierter anionischer Ladungsdichte im Fließmittel wird verdeutlicht, dass mehlkornreiche SVB bei niedrigen Temperaturen sehr robust sind, während bei hohen Temperaturen mehlkornärmere Entwürfe zu bevorzugen sind. Darüber hinaus wird gezeigt, wie sich unterschiedliche Fließmittelmodifikationen in bestimmten Temperaturbereichen verhalten. Anhand des Wasser-Feststoff-Verhältnisses und des Adsorptionsverhaltens von Fließmitteln werden die maßgeblichen Prozesse erläutert und Möglichkeiten für die Entwicklung robuster Mischungen für individuelle Temperaturbereiche aufgeführt.--------------------------------------------------------------------------------------------------------------------------------------------------------------
Regarding the temperature dependent performance, self-compacting concrete (SCC) distinguishes from normal concrete, since its rheology does not only depend upon the hydration itself but supplementary upon the adsorption of superplasticizers, which is affected by the time and the hydration progress. Based on rheometric concrete investigations with different SCC mixture compositions and varied anionic charge densities of the superplasticizers, it is shown that SCC, which is rich in powder components, shows robust performance at low temperatures, while compositions with lower powder contents are favourable at high temperatures. Furthermore, the performance of different superplasticizer modifications at different temperature ranges is demonstrated. The relevant processes are explained by means of the water to powder ratio as well as the adsorption behaviour of superplasticizers, and options for the development of robust mixture compositions for individual temperature ranges are itemised.
Stabilising admixtures are commonly used additives in repair mortars and grouts. Beyond this, such type of admixture is increasingly used in concrete and other cementitious materials. In particular when fresh mortar or concrete properties have to be adjusted reliably, stabilising agents can be beneficially used to improve workability and robustness of the mixture. The mode of operation of these admixtures varies, rather affecting either the liquid phase or the solid particles in the dispersion, both causing strong interactions with the mortar or concrete system, and significant changes in their rheological behaviour. Furthermore, these are strongly affected by the environmental temperature during the casting process. In the paper the effect of temperature on the performance of stabilising agents in cementitious systems is presented and how performance changes affect fresh and hardening mortar or concrete properties. Particular attention is placed on interactions between stabilising agents and superplasticizers. Results are discussed with special focus on self-compacting concrete.
This paper presents experimental investigations and analyses on the early-age-behavior of zero-slump concrete, such as compaction behavior and green-strength. First, the influence of the granulometric properties of the fines is discussed in detail. For this purpose, the early-age behavior of two different fines (quartz flour and fly ash) is investigated by means of the intensive compaction test (IC-test). The tests on the influence of the fines focus on effects caused by differences in the particle shape and the use of a plasticizing admixture. The conducted tests on the compaction behavior of the fines and their corresponding green-strength are extended to continuously graded granular mixes. Here, the influence of optimized particle packing on the early-age behavior is presented and a comparison on the basis of the aforementioned quartz flour and fly ash is made. In this consideration, experimental investigations on the early-age behavior of a zero-slump concrete mix and possible effects on the hardened concrete properties are included.