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- UHPC (14) (entfernen)
Organisationseinheit der BAM
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- 7.1 Baustoffe (8)
- 7.4 Baustofftechnologie (1)
Bauteile bzw. Tragwerke aus Hochleistungsbetonen müssen in der Regel gegen brandinduzierte Abplatzungen mit geeigneten Maßnahmen geschützt werden, um einen ausreichenden Feuerwiderstand im Brandfall zu gewährleisten. Die bisher wirtschaftlich und technologisch sinnvollste Methode zur Verhinderung von explosionsartigen Betonabplatzungen im Brandfall ist die Zugabe von Polypropylen-Fasern. Die Wirksamkeit der Fasern konnte zwar empirisch gezeigt werden, es stellt sich allerdings die Frage, welche Mechanismen zur Verhinderung der Abplatzungen führen. Der vorliegende Beitrag fasst bisherige Theorien zur Wirkungsweise von Polypropylen-Fasern in brandbeanspruchten Hochleistungsbetonen zusammen und stellt eine innovative Methodologie zur Erforschung der mikrostrukturellen Prozesse vor. Die Ergebnisse zeigen, dass die nach dem Schmelzen und Zersetzen der Polypropylen-Fasern frei werdenden Mikrokanäle durch eine gleichzeitig einsetzende Mikrorissbildung netzartig verbunden werden. Die Mikrorissbildung ermöglicht somit den Abbau von Eigen- und Zwangsspannungen im Beton (mechanischer Effekt) und die Entstehung eines Transportwegesystems für den ausströmenden Wasserdampf (Permeationseffekt).--------------------------------------------------------------------------- Structural members and bearing structures of high performance concrete generally have to be protected against explosive spalling due to fire exposure to guarantee a sufficient fire resistance. Up to now, the economically and technologically most worthwhile method to prevent explosive spalling is the addition of polypropylene fibres. Though the effectiveness of the fibres could be shown empirically, the mechanisms preventing explosive spalling are still debatable. The present article summarizes the existing theories concerning the mode of action of polypropylene fibres in fire exposed high performance concretes and presents an innovative methodology for analysing the micro structural processes. The results show that due to the thermal decomposition of the polypropylene fibres micro channels are created and simultaneously connected due to a netlike micro crack formation. This enables the relief of internal stresses (mechanical effect) and the formation of a permeable transport system for the escaping water vapour (permeation effect).
Nanotechnologie im Bauwesen
(2008)
Zu den Zielen der Nanotechnologie gehört die Entwicklung, Produktion und Anwendung von Materialien und Werkstoffen mit völlig neuartigen Leistungsspektren. Für die Baupraxis und die Materialforschung lassen sich über den Einsatz der Nanotechnologie Ziele wie die Optimierung von Baustoffeigenschaften, Vermeidung von Schäden und neue Funktionalitäten definieren. Der vorliegende Beitrag gibt einen Überblick über mögliche Anwendungsbereiche der Nanotechnologie im Bausektor, wie z. B. zementgebundene Baustoffe, Außen- und Dachfassaden, Fenster und Verglasungen, Brandschutz, Inneneinrichtung und Infrastrukturbau. Zudem werden aktuelle Forschungsarbeiten mit nanowissenschaftlichem und nanotechnologischem Schwerpunkt im Bereich baustoffbezogener Materialien der Bundesanstalt für Materialforschung und -prüfung (BAM) in Berlin vorgestellt. Die Forschungstätigkeiten beziehen sich zum einen auf die Modifikation der Hydratphasen in Ultra-Hochleistungsbeton (UHPC) und zum anderen auf die Weiterentwicklung von Anti-Graffiti-Systemen.
Concrete is by far the most common building material in the world. Due to its good durability it is widely used in building envelopes. One major part of the embodied energy in concrete comes from the production of Portland cement that consumes around 3,500 MJ energy per each ton of cement. Globally 2.6 billion tons of Portland cement is produced and the consumption is increasing. Since concrete will be used as main building material also in future construction, it is reasonable to develop concrete building components with lower embodied energy.Using the example of an ultra-high performance concrete (UHPC) façade element, it is demonstrated how the embodied energy can be reduced by application of hydrothermal curing.
Ultra high performance concrete (UHPC) is characterised by its high compressive strength of more than 120 MPa and its high durability. With thermal treatment at 90°C, hydration is accelerated and a strength comparable to the 28-day strength can be achieved immediately after the treatment. In applying Optimum process conditions, the strength can be even further increased by up to 30%. Previous Research showed that thermal treatment can lead to inhomogeneities in form of a visible zonation within the cross-section, if the UHPC is not protected sufficiently from desiccation. This led to the question, to what extent the related changes in mechanical properties, microstructure and phase composition are of relevance for the performance of the UHPC. First investigations of small specimens thermally treated without protection exhibited a decrease of compressive strength, indicating that the zonation aspect requires further research.
In this study the zonation of UHPC treated thermally at 90°C is investigated after applying four different procedures of treatment and curing in comparison. The samples are characterized with respect to their chemistry, mineral composition and microstructure to allow an assessment on durability and strength development, with focus on potential depth dependent changes associated with the zonation.
The measurements reveal the formation of a visible zonation in case of unprotected treatment, if followed by immersion in water. The compressive strength is not significantly impaired, but a decrease in bending strength gives reason for concern. Further results allow clear correlation with changes in pore structure, whereas the interpretation of relationships with phase distribution, degree of hydration, microchemistry is more complex and therefore, provides only partial clarification.
Ultra high performance concrete (UHPC) is characterised by its high compressive strength of more than 150 MPa and its high durability. Due to thermal treatment at 90°C a strength comparable to the 28-days-strength can be achieved immediately after the treatment and in some cases can be even further increased up to 30 %. The explanations for the increase in strength are the accelerated hydration of the clinker minerals and the intensified pozzolanic reaction contributing to a denser microstructure and hence, a high performance in compressive strength.
Former research shows that thermal treatment can lead to inhomogeneities in form of a visible zonation within the cross-section. The width of the margin increases with shorter pre-storage time before the thermal treatment and with omitting protective measures against desiccation during the treatment. Specimens exhibiting a zonation typically show a lower compressive strength compared to the undisturbed reference whereas changes in chemistry, mineral content and microstructure were not reported in detail.
In this study the zonation of thermally treated UHPC is investigated with respect to its chemistry, mineral composition and microstructure to allow predictions on durability and strength development. Measurements show a change in pore sizes, minerals phase composition and element distribution leading to the visible zonation and weaker bending tensile strength compared to the reference.
The advantages of treating prefabricated components made of Ultra-High-Performance Concrete (UCPC) at 90 °C are largely recognized, while hydrothermal treatment at 185 °C and the corresponding saturation pressure of 1.1 MPa, in contrast, is not applied in building practice so far and was studied only by a few researchers.
In the research presented, the parameters pre-storage-time before treatment and dwell time in the autoclave were systematically varied. The results illustrate in which way compressive strength increases with the duration of treatment. Already samples which were only heated up and immediately cooled down show an increase in strength compared to the 28-day reference of about 10 %. After 20 h the maximum increase of about 25 % is reached. Interestingly the compressive strength of samples treated very long hardly decreases. It can be therefore concluded that for the composition investigated the achievable mechanical strength is not severely sensitive regarding the duration of the treatment.
Also, pre-storage times before autoclaving longer than 0.5 days showed no significant impact on strength development.
The phase composition measured by XRD exhibits significant changes compared to the reference. The amount of ettringite and portlandite have vanished, the cement clinker phases are substantially decreased and hydroxylellestadite and hydrogarnet are formed as new phases. The increase in strength can be assigned to an improved pozzolanic and hydraulic reaction. Contradictory to literature, there was found no tobermorite, a mineral which is known to be susceptible for disintegration at Long autoclaving duration. This explains why no significant strength loss appeared.
Composition and microstructure stability of cement compound under cyclic hydrothermal condition
(2020)
There have been many researches focused on the performance improvement of ultra-high performance concrete (UHPC) by autoclaving treatment. The goal of autoclaving is to increase the pozzolanic reaction, and to densify the cement stone and the transition zone which originates from the incorporation of supplementary cementitious materials (SCMs), such as silica fume, fly ash and blast furnace slag. Due to the superior properties, UHPC can also be utilized under high mechanical load and aggressive condition, for example, the fabrication of water tanks for thermal storage which is of great significance for saving energy and reducing CO2 emission. It is known that mineral stability of the hydration products of an inorganic binder is highly related to the temperature and pressure of the environment. A certain stable composition at room temperature, however, may undergo a phase transformation at high temperature and the performance decrease under this severe condition will generally be more severe. In this way, the rationale behind this deterioration under long-term hydrothermal condition involving many cycles and long duration has to be clarified, and then appropriate optimizing methods will be performed in order to obtain a kind of construction with high durability under aggressive environment. For this purpose, different types and amounts of SCMs are introduced into the standard mixture of UHPC and the phase compositions after autoclaving at 200 °C and 15.5 bar are determined by combined X-ray diffraction and scanning electron microscope. Mercury intrusion porosimeter is used to characterise the microstructure of the samples. In order to establish the relationship between microstructure and macroscopic properties, compressive and flexural strength are also investigated.