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Zerstörungsfreie Ortung von Fehlstellen und Inhomogenitäten in Bauteilen mit der Impuls-Thermografie
(2004)
Impulse-thermography is an active method for quantitative investigations of the near surface region of various structures. It has recently been applied and optimised to applications in civil engineering. By using either an internal or external heat source, parts of the structure under investigation are heated up and the transient heat flux is observed by recording the temperature change at the surface as a function of time. This method is very well suited for the detection of voids and honeycombing in concrete, up to concrete covers of 10 cm as well as for the location of delaminations in multi-layered systems (e.g. plaster on concrete, CFRP-laminates on concrete, asphalt on concrete). Also safety relevant defects like voids in tendon ducts and cracks in concrete could be recognised.
The development of earth-abundant catalysts for selective electrochemical CO2 conversion is a central challenge. Cu-Sn bimetallic catalysts can yield selective CO2 reduction toward either CO or formate. This study presents oxide-derived Cu-Sn catalysts tunable for either product and seeks to understand the synergetic effects between Cu and Sn causing these selectivity trends. The materials undergo significant transformations under CO2 reduction conditions, and their dynamic bulk and surface structures are revealed by correlating observations from multiple methods—X-ray absorption spectroscopy for in situ study, and quasi in situ X-ray photoelectron spectroscopy for surface sensitivity. For both types of catalysts, Cu transforms to metallic Cu0 under reaction conditions. However, the Sn speciation and content differ significantly between the catalyst types: the CO-selective catalysts exhibit a surface Sn content of 13 at. % predominantly present as oxidized Sn, while the formate-selective catalysts display an Sn content of ≈70 at. % consisting of both metallic Sn0 and Sn oxide species. Density functional theory simulations suggest that Snδ+ sites weaken CO adsorption, thereby enhancing CO selectivity, while Sn0 sites hinder H adsorption and promote formate production. This study reveals the complex dependence of catalyst structure, composition, and speciation with electrochemical bias in bimetallic Cu catalysts.