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Quantitative determination of sulfur content in concrete with laser-induced breakdown spectroscopy
(2005)
Laser-induced breakdown spectroscopy has been employed for the investigation of the sulfur content of concrete. Sulfur compounds are a natural but minor component in building materials. The ingress of sulfates or sulfuric acid constitutes a major risk of chemical aggression for concrete. There is a need for a fast method, which can be used on-site and is able to investigate a wide range of different measuring points, so that damages can be characterized.
For quantitative determination the sulfur spectral line at 921.3 nm is used. The optimum ambient atmosphere has been determined by comparison of measurements accomplished under air, argon and helium atmosphere.
Reference samples have been produced and calibration curves have been determined, the results of LIBS measurements are compared with results from chemical analysis. Defining a limit for the intensity ratio of a calcium and a oxygen spectral line can reduce the influence of the heterogeneity of the material, so that only spectra with a high amount of cementitious material are evaluated. Depth profiles and spatial resolved sulfur distributions are presented measured on concrete cores originating from a highly sulfate contaminated clarifier.
Abstract
In the recent years the application of infrared thermography and especially its active approaches lock-in thermography, impulse themography and pulse phase thermography (PPT) has gained more importance for non-destructive testing (NDT). In this paper it is demonstrated that PPT is very well suited for NDT in civil engineering. The method is based on pulse heating of the investigated specimen and on the observation of the cooling down process on its surface with an infrared camera. The transient behaviour is afterwards analysed with Fast Fourier Transformation, enabling the creation of phase and amplitude images with enhanced visualisation of the defects. Results of European and National (i.e. DFG) funded projects are presented, for example the detection of voids and inhomogeneities close to the surface and the localisation of delaminations on plastered concrete and masonry specimen.
ZUSAMMENFASSUNG
Im Rahmen eines von der Deutschen Forschungsgemeinschaft geförderten Vorhabens zur zerstörungsfreien Prüfung im Bauwesen wird in der Bundesanstalt für Materialforschung und -prüfung (BAM) in Zusammenarbeit mit der Technischen Universität Berlin (TUB) die Puls-Phasen-Thermografie (PPT) weiterentwickelt, bewertet und eingesetzt. Die durch die Impuls-Thermografie (IT) aufgenommenen Daten werden mittels Fast Fourier Transformation (FFT) bearbeitet. Die durch die FFT gewonnenen Phasenbilder reduzieren die Störeinflüsse von Oberflächeninhomogenitäten und ungleichmäßiger Erwärmung.
Die dargestellten Ergebnisse zeigen deutlich, dass sich die PPT sehr gut zur zerstörungsfreien Prüfung im Bauwesen eignet. Insbesondere Inhomogenitäten im oberflächennahen Bereich, wie Ablösungen und Hohlstellen hinter Beschichtungen (Putz, CFK-Laminate etc.), aber auch Defekte in größeren Tiefen können zuverlässig geortet und bildgebend dargestellt werden.