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Autor

  • Brosnan, S. (1)
  • Doriti, A. (1)
  • Schlaad, H. (1)
  • Weidner, Steffen (1)

Schlagworte

  • Polysarcosine (1) (entfernen)

Organisationseinheit der BAM

  • 1 Analytische Chemie; Referenzmaterialien (1)
  • 1.3 Strukturanalytik (1)

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Synthesis of polysarcosine from air and moisture stable N-phenoxycarbonyl-N-methylglycine assisted by tertiary amine base (2016)
Doriti, A. ; Brosnan, S. ; Weidner, Steffen ; Schlaad, H.
Polysarcosine (M-n = 3650-20 000 g mol(-1), D similar to 1.1) was synthesized from the air and moisture stable N-phenoxycarbonyl-N-methylglycine. Polymerization was achieved by in situ transformation of the urethane precursor into the corresponding N-methylglycine-N-carboxyanhydride, when in the presence of a non-nucleophilic tertiary amine base and a primary amine initiator.
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