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The focus of this study is to evaluate of hydrogen on the friction and wear behavior of a wide range of polymer materials. Thereby, the tribological performance of filled and unfilled polymers from different suppliers were compared at room temperature in air and hydrogen gas (H2) as well as in liquid hydrogen at -253°C (LH2).
The focus of this study is to evaluate the influence of hydrogen on the friction and wear behavior of a wide range of polymer materials. Thereby, the tribological performance of filled und unfilled polymers from different suppliers were compared at room temperature in air and hydrogen gas (H2) as well as in liquid hydrogen at -235°C (LH2).
The development of hydrogen technologies entails high safety requirements in distribution and dispensing infrastructure. Therefore, it is necessary to pursue research on material compatibility in hydrogen, especially for critical parts with tribological issues.
The focus of this study is to evaluate the influence of hydrogen on a wider range of commercially available polymer materials. Thereby, the friction and wear behavior of different grades of TPE, POM, PA66, PA12, PPA, PEEK, PPS, PTFE, PAI, PI and PBI were investigated against a rotating steel disk (AISI 304). Filled and unfilled polymers from different suppliers were evaluated at room temperature in air, vacuum and hydrogen gas (H2) as well as in liquid hydrogen at - 253°C (LH2).
The sliding behavior of the polymer materials is discussed by means of surface analyses, whereby special attention is paid to the formation of a transfer film.
According to the results at ambient temperature, the effect of hydrogen environment on the tribological behavior of neat polymers may be related to lack of moisture, but also to saturated hydrocarbons in gaseous hydrogen. In liquid hydrogen, the best tribological performances were achieved with neat PA polymers as well as PPS and PI composites.
Effect of high-pressure hydrogen environment on the physical and mechanical properties of elastomers
(2024)
This study presents the influence of high-pressure hydrogen environment on the physical and mechanical properties of two types of cross-linked hydrogenated acrylonitrile butadiene rubbers. Based on the CSA/ANSI standard, static exposures in hydrogen experiments were performed up to 100 MPa at 120 °C. Characterization before and after exposure was conducted by means of density and hardness measurements, dynamic mechanical analysis (DMA), tensile tests, compression set, FT-IR and AFM analyses to assess effects after decompression. While the effect of high-pressure exposure is significant immediately after exposure, most of the physical and mechanical properties recover after 48 hours. FT-IR, AFM, SEM and compression set results indicate, however, permanent effects.
Die tribologischen Eigenschaften von graphitgefüllten Polyimiden gegen Stahl 100Cr6 wurden an Luft, im Hochvakuum (l0⁻ ³ Pa) und in Wasserstoffumgebung bei verschiedenen Drücken (10³ Pa, 10⁴ Pa und 10⁵ Pa) untersucht. Zwei unterschiedliche Polyimid-Typen wurden eingesetzt, wobei Typ und Menge des Graphits variiert wurden.
Die Experimente wurden bei 3,1 MPa Kontaktdruck und einer Gleitgeschwindigkeit von 0,2 m/s bzw. 1 m/s durchgeführt. Die verschlissenen Oberflächen und die Morphologie des Materialübertrags auf die Stahl-Gegenfläche wurden mittels Lichtmikroskopie, REM, TEM und FTIR untersucht. Die Untersuchung zeigt, dass sowohl die Matrix als auch der Graphitanteil einen deutlichen Einfluss auf das Reibverhalten von Verbundwerkstoffen in Wasserstoffumgehungen haben können.
The tribological behaviour of polyetheretherketone (PEEK) and polyimide (PI) composites was investigated in air, vacuum and hydrogen environments. Polymers were filled with graphite, submicron particles or carbon nano-tubes. Experiments reveal that hydrogen environment has a major influence on both polymer structure and fillers during sliding. The sliding behaviour of these polymer composites is much improved in hydrogen compared to air. In particular, graphite and nano-particles have a remarkable effect on friction and wear, respectively.
Safety and reliability are the major challenges to face for the development and acceptance of hydrogen technology. It is therefore crucial to study deeply material compatibility, in particular polymer materials that are directly in contact with hydrogen. This paper presents an experimental study on the fretting wear behavior of two types of cross-linked hydrogenated acrylonitrile butadiene rubbers against 316L steel ball in hydrogen environment. Furthermore, aging experiments were conducted for 7 days under static conditions in 100 MPa hydrogen. the influences of hydrogen pressure as well as the aging exposure on the fretting behavior are discussed by means of surface analyses along with the material properties.