Filtern
Erscheinungsjahr
- 2003 (3) (entfernen)
Dokumenttyp
- Zeitschriftenartikel (2)
- Sonstiges (1)
Sprache
- Englisch (3)
Schlagworte
- Alpha-oxoethanals (1)
- Aza-enamines (1)
- DRIFTS (1)
- Formylation (1)
- Heterocycles (1)
- Hydrazones (1)
- La2CrO6 (1)
- LaCrO4 (1)
- Lanthanum-chromium mixed oxides (1)
- Raman spectroscopy (1)
Aza-enamines X - Formylation of Pyrazole-4-carbaldehyde Hydrazones at the Hydrazonoazomethine C-Atom
(2003)
1,3-Disubstituted 1H-pyrazole-4-carbaldehyde-N,N-dimethylhydrazones 1 reacted with the Vilsmeier-Haackreagent, corresponding to the aza-enamine concept, in an electrophilicsubstitution reaction at the azomethine C-atom yielding the 1,4,5-triaza-pentadieniumsalts 2. These were hydrolysed to give2-hydrazono-2-(1H-pyrazole-4-yl)ethanals 3. The electrophilic attack did not takeplace at the vinylogous position 5' of the pyrazoles.
CrOx/La2O3 mixed oxides, prepared by impregnating La2O3 with appropriate aqueous solutions of (NH4)2CrO4 and calcining at 600 °C for 4 h, have been investigated by means of XRD, TPR, XPS, DRIFTS, and Raman spectroscopy (RS). The formation of the compounds La2CrO6, La(OH)CrO4 and LaCrO4 under these conditions was evidenced. Strong peaks at 864, 884, 913, and 921 cm-1, as well as weak peaks at 136, 180, 354, 370, and 388 cm-1 in the RS spectrum of CrOx/La2O3 have been assigned to La2CrO6.