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Avoiding road crashes has been the purpose behind many specialized software and hardware systems, involving both active and passive safety principles. Global Positioning technologies were incorporated into the transportation systems with the main purpose of acquiring the position of the vehicle under a continuous basis, for security and economy purposes. However, the GPS data can also be used for assessing the level of safety at which the vehicle is driven. On the basis of the essential data available from commercial GPS devices, in this paper we propose a combined performance measurement to assess the road safety level at which the vehicle is being driven. Such performance measure uses GPS data of the vehicle displacement, including the speed and the acceleration, as well as the course (latitude and longitude coordinates), in an integral driving assessment formulation that can run in real time. Results from the experimental use of this formulation suggest that the level of safety in the driving is time dependent, and that there are risky situations when different factors converge.
GPS-data based calculation scheme for assessing, in real-time, the level of safety exerted during driving, has been described and used. The several variables involved considered the main factors that lead to road mishaps, including the speed, the acceleration and the effects that these variables have on the vehicle when it is negotiating a turn. The performance measure combines three individual performance outputs: speed, acceleration and a hybrid performance measure considering the speed, the acceleration and the change in latitude/longitude. The measures are designed in such a way that weighting factors can be calibrated in order to establish certain critical parameters. On the other hand, the terms in the equations preclude any division by zero of the involved ratios. On the other hand, the simplicity of the equations makes it possible to carry out the assessment in real time. The use of the resultant performance measure to a relatively long path, together with its current average value, indicates that the safe performance of the driving changes with time, and that, for the selected values of the calibration constants, the traveling speed dominates the overall safety performance of the driving. Furthermore, the different calibration constants provide the possibility of considering different types of hazmat carrying vehicles. While many other formulation components could be integrated into the performance measure, this three-component performance measure could be used to assess the driving of a hazmat-carrying vehicle, in order to detect and to prevent dangerous conditions, such as driver fatigue.
Finally, the implementation of the different performance measure formulations in a system such as the one described in the introduction of this paper, could be straightforward.
A simplified methodology is proposed to estimate the dynamic pressures developed within partially filled cylindrical vertical tanks when subjected to earthquake-related horizontal accelerations. The total pressure at the bottom of the tank is calculated as the superposition of vertical and horizontal pressures. While the magnitude of the vertical pressure depends on the free surface height of the liquid, the horizontal pressure depends on the magnitude of the horizontal acceleration and on the diameter of the tank. The liquid free surface oscillation angle is simulated based upon the principles of the simple pendulum analogy for sloshing. The length of the pendulum, however, is set on the basis of a methodology to calculate the free sloshing frequency of partially filled containers. Such a methodology is experimentally verified in this work. The outputs of the model for full scale situations, suggest that the lateral perturbation - sloshing phenomenon (earthquake effect) can generate an increase in the total pressure of 56% above the no lateral perturbation situation, further suggesting that such an overpressure should be taken into account when designing tanks that could be potentially subjected to earthquake-related perturbations.
The results are based on data1. Figure 3 displays temperatures of the tank wall and of the gas phase over testing time. It can be seen that a complete coating strongly delayed the heating of tank wall and gas phase, whereas the partly coated tanks only had a minor influence on temperature development. There was no significant difference between a half coated and a thirdly coated tank measurable. Figure 4 shows the internal pressure of tanks over testing time. Only the fully coated tank enabled a low pressure over 90 min testing time. Hence, a complete coating is necessary to guarantee the fire safety of hazmat tanks and a partly coating is not sufficient.
A simplified model, based upon physical principles, is proposed the simulate the effect of sloshing on the pressure developed in the tanker chambers. The model has been validated in good extent, with experimental data from full scale testing. The characteristic that mostly affects the pressure developed with the chambers of the tanker is the length of the chamber. While a reduction in this property could decrease the pressure developed within a given chamber, the analysis should take into account an overall approach, as a shortening of the individual chambers would influence the number of chambers necessary to carry a certain amount of product. Consequently, the resulting model could be used to study different effects of the sloshing cargo on the carrying vehicles, including the length and position of the chambers along the tanker body.
A dynamic simulation model for a tanker ship along the Rhine River has been proposed, based on a simplified computational scheme, involving a two-degree-of-freedom roll plane multibody system, subjected to lateral accelerations estimated on the basis of measured data. The resulting equations of motion are solved through the transition matrix approach. The results suggest that many contributing factors were involved in the capsizing of the ship, including the relatively high speed of the river water and the meandering path of the infrastructure, further affected by dynamic effects derived from the behavior of the payload and from the steering maneuvers performed.
Rear-end crashes involving heavy trucks as the leading vehicle, and cars as the impact vehicle, cause many deaths and permanent injuries to car´s occupants. Measures have been thus taken in the trucks to prevent underride crashes, including the mounting of stiffer underride guards, set at car´s bumper height. In this respect, an active acceleration system(AAS), installed in the truck, could also contribute to mitigate the effects of These crashes, through the decrease of the relative Speed of the vehicles at the instant of the crash. In this paper, an AAS system is proposed, under the principles of ultrasonic sensors and an actuator for the truck´s accelerator mechanism. Simulation results of the operation of this AAS system, suggest that such a system could decrease the relative impact speed around 8% for an initial relative speed of 10 m/s.
The application of lightweight materials for tanks for transportation appears promising. Besides saving weight and therefore transportation costs, new complex geometries that depart from common cylindrical shapes of steel tanks can be manufactured. For transportation of dangerous goods, fire and explosion safety must be maintained to prevent accidents with serious consequences. In this work the fire behavior of lightweight tanks made from glass fiber reinforced plastics (GFRP) with complex geometries is investigated. Pretests on intermediate scale GFRP plates are conducted to identify suitable fire protection systems and surface treatments for composite tanks. The fire resistance is shown to be improved by addition of fire protective coatings and integrated layers. Finally, a complex rectangular GFRP tank with a holding capacity of 1100 liters is fire protected with an intumescent fire coating. The tank is filled up to 80 % with water and burned under an engulfing fully developed fire. It was shown that the intumescent layer could expand before the decomposition of the resin occurred. Furthermore, the adhesion between tank surface and coating was maintained. The structure could withstand a fire for more than 20 min.
Simulation of liquid cargo – vehicle interaction under lateral and longitudinal accelerations
(2018)
Amongst the vehicle parameters influencing road safety, the carried cargo plays a critical role in the case of a liquid cargo, posing rollover risk and affecting the available friction forces for braking. While the lateral sloshing of the cargo within the vehicle´s compartments, can be excited when the vehicle negotiates a turn, the longitudinal motion of the cargo derives from changes of speed. The combination of both types of perturbations occurs when the vehicle brakes while negotiating a turn. In this paper, a two-pendulum formulation is used to simulate the lateral and longitudinal behavior of a vehicle when negotiating a braking in a turn maneuver. The suspension forces are thus calculated as the linear superposition of both models. Results suggest that the vehicle roll stability is affected by the cargo sloshing, with increments on the order of 100% in the lateral load transfer, for a 50% filled tank. On the other hand, the dispersion of the travelling speed also affects the lateral stability of such type of vehicles, as a function of the dispersion of the vehicle´s travelling speed.
The use of railway transportation for satisfying the transport needs of goods in Mexico is less intense than in developed countries, such as Germany. Mexican performance measures based upon the railway length per capita (intensity), or the railway length per square km of the country surface (density), are well behind from corresponding indicators for Germany, in such a way that the length of the railway infrastructure of Mexico should be, at least, doubled in order to reach a comparable intensity rate as that of Germany. In this paper, the benefits from transferring the whole transportation of goods from road to railway, is discussed. The benefits include a remarkable reduction in energy consumption and CO2 emissions. The feasibility for the electrical infrastructure to provide the necessary energy is further shown, while the economic feasibility of such situation is analyzed on the basis of the federal budget of Mexico. According to these estimations, the investment in railway infrastructure is feasible, while the electrical installed capacity is enough to satisfy an all-electric system.
This paper describes a theoretical model to simulate the effects of a sloshing cargo on the safety performance of a vehicle that performs a braking-in-a-turn maneuver when travels at a partial fill level. The fundamental assumption of the model consists of the superposition of the effects of two simplified mechanical-analogy models that represent a liquid cargo on a vehicle, including one for the roll motion and another one for the pitch motion. The distinctive characteristics of the mechanical models, however, is that they are based upon a validated formulation to establish the properties of the pendulum (length).
The results suggest a small effect of the sloshing cargo on the braking efficiency of the cargo, while the load transfer is moderately affected. However, such results should be put into a perspective, according to which such small variations can represent the avoidance of a rear-end crash or a rollover. In this respect, a specialized ABS system could be considered to improve the performance of such kind of vehicles when performing such maneuvers.
Validation of the proposed methodology should be performed as a continuation of this research effort.
To save weight and resources lightweight tanks with complex geometries made of glass-fibre reinforced plastics (GFRP) are a promising innovation for the transportation of dangerous goods. To realise the use of polymer tanks for such applications, their fire safety must be guaranteed. This paper presents solutions to protect fibre-reinforced plastic tanks from fire. The fire resistance of six GFRP tanks with different fire protection systems was tested in an outdoor full-scale fire test facility according to the regulation stipulated in the ADR (European agreement concerning the national carriage of dangerous goods by road). All tanks feature a complex geometry and a holding capacity of 1100 litres. The fire protection systems are composed of specialised resins as well as two intumescent coatings. All systems had a protective impact. The best results were achieved by the epoxy based intumescent coating, which was able to prolong the time needed to reach 150 °C inside the tank by 20 min. The emergence of a temperature holding point inside the tank due to condensation effects was observed at temperatures around 100 °C.
Seit zehn Jahren führt die Bundesanstalt für Materialforschung und -prüfung (kurz: BAM) auf zwei Prüfständen Brandprüfungen z. B. an Transport-und Lagerbehältern für radioaktive Stoffe oder zur Prüfung von Brandschutzbeschichtungen durch. Als Brandmedium wird Flüssiggas (Propan-Butan-Gemisch C) eingesetzt, mit dem die Prüfobjekte simulierten Unfallfeuern ausgesetzt werden. Seit Anfang 2018 verfügt die BAM darüber hinaus auch über einen Jetfire-Prüfstand, der die Anforderungen der ISO 22899-1:2007 1) erfüllt.
Commodities and rail damage
(2018)
The normalized contact-mechanics fourth-power law approach for the
dynamic loads, suggest: worst railway use situation (double deck at 65 km/h) is 350 times that of the less rail damage situation (flat car at 45 km/h).
The normalized dispersion approach for the dynamic loads (Dynamic Load Coefficient), suggest that the worst railway use situation (double deck at 65 km/h) is about 4 times that of the less rail damage Situation (flat car at 45 km/h).
The potential effect of the different types of cars on the railway fatigue life could be significant, as a function of the vehicle speed.
The experimental validation of these outputs will be carried out as a continuation of this research effort. In addition to that, it should be mentioned that the associated simplified model could be used to analyze some other situations, related with the transport safety of different products.
Commidities and rail damage
(2018)
A roll-plane simplified model, representing the suspended body-cargo of a railway car, was developed to simulate thedynamic response of a railway car while subjectedto lateral acceleration derived from its traveling along curved tracks. The model provides the means to calculate the suspension forces, which are supposed to be transmitted to the bogie´s wheelset. For the analysis of the potential effect of such forces on the railway fatigue life, different performance measures were considered, under different concepts. A family of curves were produced to analyze the effect of the height of the center of gravity of the body-cargo system, on the different performance measures. The resultingdiagramswereused to assess the rail damage potentials offour different railway cars. Results suggest that the height of the center of gravity, associated to the different types of railway cars, nonlinearly and strongly affects the fatigue lifeof the rail, with the double stack car being the moreinfrastructure-aggressive. In this respect, experimental evidence should be provided about such remarkable effects, so as to supportsome operational recommendationsthat shouldbe taken to mitigate these effects, including, for example, the regulation of the traveling speed of some vehicles.
The use of glass-fiber reinforced plastic (GRP) can reduce the weight of tanks significantly. By replacing steel with GRP in tanks for gases (propane, etc.) a weight reduction of up to 50 % was reached. In this project not only the material should be optimized, but also the design. Previous tanks consist of a double-walled structure with an insulation layer between the two shells (e.g. vacuum). Goal of this project is to realize a single-walled construction of GRP with an insulation layer on the outside.
To determine the temperature dependent material values, two different experiments are performed: In the first experiment, temperature dependent material properties of liquid nitrogen found in literature research are validated in a simple setup. The level of liquid nitrogen in a small jar is measured over the experiment time. Numerical simulation shows the change of nitrogen level with sufficient precision. In the second experiment, a liquid nitrogen is applied on one side of a GRP plate. Temperature is measured with thermocouples on top and bottom of the GRP plate, as well as in the middle of the plate. By use of numerical simulation, temperature dependent thermal conductivity is determined.
In the third experiment, a test stand is designed to examine different insulation materials. In this test stand, the insulation material can easily be changed. A numerical simulation, in which the determined material data is used, is performed as well for this test stand.
The experiments show, that GRP can be used in cryogenic environments. Multiphase simulations are a suitable tool to describe the energy absorption of thermal energy due to thermal phase change. Results on different insulation materials will follow.
Transport safety depends in great extent of what happens to the cargo once the carrying vehicle derails or rollovers. The exposure of tanks to direct fire is a condition that potentially involves catastrophic consequences. Studying the behavior of the contained fluid under these drastic circumstances, is critical to develop methods and techniques to mitigate the serious consequences of many mishaps. In this paper, the experimental potentials of a Particle Image Velocimetry data acquisition system are described, for providing experimental data that could be used to calibrate mathematical models. As an example of the situations that need to be modelled, an experiment is described concerning the effect of the boundary conditions and protecting devices, on the rate of variation of pressure and temperature of the fluid in a tank exposed to a direct fire. In this regard, the results emphasize the importance of equipping the vessels with both thermal insulation and safety valves.
It was possible to achieve an error as 9% or even 0% at certain time steps, as shown in the graph above, the usage of UDF code has major importance in achieving the pressure Profile required, and it heat transfer between the bottle itself and the surroundings was taken into consideration which of course had a high influence on how the temperature of the air flask changes.
Figure 10 illustrates the theoretical results from the simplified model considered, together with the experimental data. These results and measurements are presented one next to the other, in order to facilitate the validity analysis of the proposed simulation methodology.
These results illustrate that the trends are comparable for both sets of data, that is, a similar range is obtained for all of the variables reported. A lower pressure is generated in chamber 5, which is attributed to the shorter length of this chamber. However, such increase in pressure does not correspond exactly to the difference of lengths, as the ratio of lengths would cause a differential pressure of 2.3/1.23 = 1.86, while the ratio of average pressures is on the order of 2. That is, there is an incremental, which is associated to the maximum height attained by the fluid in the chamber. The major difference between both sets of data, the experimental and theoretical, is that the theoretical do not include much of the noise and random oscillations reported in the experimental data. Such noise, however, is of very low amplitude, in comparison with the maximum values attained. The practical applications of these results could be in the area of chamber design, so that the effects of the length of the chambers be taken into account. That is, such greater lengths for the fluid in the chamber would involve larger pressures and consequently, greater stresses. However, the analysis should include an overall perspective, that is, the shortening of the chambers would imply an increase in the number of chambers, for a certain total payload, and the superposition effect of pressures, should be considered. On the other hand, the analysis could be extended to characterize the effects of the distribution of the lengths of the different chambers along the axis of the tanker, as the different resulting forces could have different effects on the pitch response of the road tanker.
There was a need to validate the longitudinal performance required for the cargo securement, as current standards exhibit differences.
A model has been proposed in this paper, to simulate the effect of a shifting cargo on the braking efficiency of the vehicle. Results suggest that the braking efficiency can be greater in the case of a shifting cargo, as a result of the uncoupling of the cargo-vehicle systems, implying that similar braking forces are exerted on a reduced mass. The shifting of the cargo can occur as a result of the vibration of the vehicle, that leads to having a diminished friction force to prevent the shifting of the cargo.
A filling process of the pressure bottle used for the air storage was investigated by numerical simulations. During the filling process, the temperature was rising up to maximal value and after that started to decline. The good match was found between experimental and numerical results. In order to reproduce the experimental conditions, the process of the filling bottle was controlled by the pressure which varied in time. This filling strategy influenced furthermore the mass flow rate and the air flow velocity. Because of the geometrical symmetry, the simulation was calculated as an axisymmetric problem.
Transport safety depends in great extent of what happens to the cargo once the carrying vehicle derails or rollovers. The exposure of tanks to direct fire is a condition that potentially involves catastrophic consequences. Studying the behavior of the contained fluid under these drastic circumstances, is critical to develop methods and techniques to mitigate the serious consequences of many mishaps. In this paper, the experimental potentials of a Particle Image Velocimetry data acquisition system are described, for providing experimental data that could be used to calibrate mathematical models. As an example of the situations that need to be modelled, an experiment is described concerning the effect of the boundary conditions and protecting devices, on the rate of variation of pressure and temperature of the fluid in a tank exposed to a direct fire. In this regard, the results emphasize the importance of equipping the vessels with both thermal insulation and safety valves.
Small and large-scale tests have been carried out Pressure vessel – to improve numerical modelling Different types of fire must be distinguished Modelling of vessels were discussed Test configuration has been developed to see what happens in the vessel First results encourage us to continue the Research Thermohydraulics needs further work (boundary layers).
There was a need to validate the longitudinal performance required for the cargo securement, as current standards exhibit differences. A model has been proposed in this paper, to simulate the effect of a shifting cargo on the braking efficiency of the vehicle. Results suggest that the braking efficiency can be greater in the case of a shifting cargo, as a result of the uncoupling of the cargo-vehicle systems, implying that similar braking forces are exerted on a reduced mass. The shifting of the cargo can occur as a result of the vibration of the vehicle, that leads to having a diminished friction force to prevent the shifting of the cargo.
A novel deign of test equipment has been commissioned to investigate thermal stratification and boiling during fire exposure of pressure vessels. Extensive temperature measurements and video of the internal conditions during fire exposure are possible, and the equipment has been designed for future compatibility with laser-based velocity measurement techniques. It is expected to generate data large quantities of data that will be of use in validation of two- and three-dimensional CFD models for the prediction of pressure vessel behaviour in fire. Future work will seek to characterize the boundary layer conditions in detail for a range of test fluids, fill levels and fire-induced thermal boundary conditions.
Initial tests undertaken during commissioning may indicate that fire exposure of the vessel wall just above the liquid level can have a notable influence on the pressurization rate, by increasing the degree of superheat. Further experimental and modelling work is required to confirm and quantify this effect, or to rebut this conclusion.
The interaction of the vehicles with the pavements imply damaging effects on both systems, as a function of the operating conditions and design characteristics of both systems. These effects influence the road pricing as well as the maintenance costs of the vehicles. In this paper, a simulation scheme has been proposed to analyze such interaction in massive way, involving a multivehicle models was the uncoupling of the roll and pitch responses. Results suggest that the damaging effects on the pavement and the vehicle, depends on the position along the road profile. However, the vertical design of the road would mainly affect the pavement damage, while the turning maneuvers would strongly influence the damage of the vehicle. Many uses can be identified for the proposed simulation scheme, involving different design and operating conditions for both systems.
A model of the cargo – ship interaction has been presented, for a navigation environment in which there is no waves, in which the ship lateral stability depends only on the manoeuver performed and the characteristics of the ship and cargo. Several simplifications have been introduced in the model, including the circular bottom of the ship, which facilitates the location of the buoyancy force on the ship, and the analogy of the sloshing cargo motion to a simple pendulum. Two forms of damping were introduced (river waters with the ship´s hull and the friction of the liquid inside the tanker walls), while the sliding motion of the ship when turning has been assumed as negligible. The results suggest that the sloshing cargo influences the lateral stability of the river tanker, with increases in the maximum roll angle from 15% to 40%, as a function of the speed and the fill level. The maximum roll angle has been found to occur at a 75% fill level, regardless of the ship speed.
The safety of any transport system depends on a multitude of conditions, parameters and circumstances. In this regard, the interaction of the carried Cargo with the carrying vehicle represents a factor influencing the overall safety of any transport. The effects of cargo on the vehicle have to do with the vibration or shifting of the cargo, affecting the lateral stability of the vehicles and the braking performance.
Such interaction has been associated to road crashes and maritime vehicles capsizing. Simulation of cargo-vehicle interaction thus represents an interesting Topic when a reduction in transport accidents is pursued. In this paper, the fundamentals principles for simulating the interaction of the liquid cargo and the carrying vehicle, is presented. In the case of a road transportation, the proposed simplified Simulation methodologies, show good agreement with a full-scale test.
An experimental testing rig has been proposed to study the dynamic interaction between a liquid cargo and the carrying vehicle during turning maneuvers. The basic operational principle of the testing rig consists in simulating the lateral accelerations associated to turning maneuvers through the use of a tilt table.
While the experimental capabilities of the testing rig include the analysis of the effects of the cars on the whole transport infrastructure, including sleepers and ballast, a first use of the rig considered the effect of sloshing cargo on the level of dynamic forces transmitted to the rails. Such test was used to validate a simplified theoretical approach consisting of a two degree-of-freedom double pendulum mechanical system, where a simple pendulum, representing the sloshing cargo, is articulated to the spring-supported vehicle chassis, which is modelled as an inverted torsional pendulum. While the theoretical results exhibit a high correlation with the experimental data, the main discrepancy between both outputs, relates with the frequency of the residual vibration, once the lateral acceleration input is ceased. Such difference in frequency, would imply an underestimation of the number of loading cycles to which the infrastructure is subjected. On the other hand, the peak values are within acceptable difference levels.
Liquefied Hydrogen (LH2) or Liquefied Natural Gas (LNG) establish themselves as important energy carriers in the transport sector. Its storage requires tanks with Thermal Super Insulations (TSI) to keep the transported fluid cold. TSI has proven itself in various applications over a long time, but not in the land transport sector, where accidents involving collisions, fires, and their combination are to be expected. The focus of this study is to investigate the behavior of different types of TSI when exposed to a heat source that represents a fire. Therefore, a High-Temperature Thermal Vacuum Chamber (HTTVC) was used that allows the thermal loading of thermal insulation material in a vacuum and measuring the heat flow through the TSI in parallel. Within this study, 5 samples were tested regarding 3 different types of MLI, rock wool, and perlites. The thermal exposure caused different effects on the samples. In practice, this can be connected to the rapid release of flammable gases as well as a Boiling Liquid Expanding Vapour Explosion (BLEVE). These results are relevant for the evaluation of accident scenarios, the improvement of TSI, and the development of emergency measures.
Liquefied Hydrogen (LH2) or Liquefied Natural Gas (LNG)
establish themselves as important energy carriers in the transport
sector. Its storage requires tanks with Thermal Super Insulations
(TSI) to keep the transported fluid cold. TSI has proven itself in
various applications over a long time, but not in the land
transport sector, where accidents involving collisions, fires, and
their combination are to be expected. The focus of this study is
to investigate the behavior of different types of TSI when
exposed to a heat source that represents a fire. Therefore, a High-
Temperature Thermal Vacuum Chamber (HTTVC) was used that
allows the thermal loading of thermal insulation material in a
vacuum and measuring the heat flow through the TSI in parallel.
Within this study, 5 samples were tested regarding 3 different
types of MLI, rock wool, and perlites. The thermal exposure
caused different effects on the samples. In practice, this can be
connected to the rapid release of flammable gases as well as a
Boiling Liquid Expanding Vapour Explosion (BLEVE). These
results are relevant for the evaluation of accident scenarios, the
improvement of TSI, and the development of emergency
measures.
The interest in hydrogen-based green energy is increasing worldwide, and the same is true for hydrogen-powered vehicles. Among the possible solutions to store hydrogen in such vehicles, cryogenic tanks equipped with multi-layer insulation (MLI) are the most promising to increase the amount of energy stored per unit volume. However, MLI is affected by severe deterioration when exposed to an external source of heat such as a fire following a car accident, leaving the tank unprotected and leading to failure in a relatively short time. In this work, a one-dimensional model to evaluate MLI thermal degradation when a liquid hydrogen tank is exposed to fire is presented. The relevance of taking MLI degradation into account when simulating the pressure increase due to external fire exposure is here demonstrated through the analysis of several case studies. The results show that MLI systems performance depletes within a few minutes of exposure to hydrocarbon poolfire.
The dynamic response of a vehicle during braking is influenced by the tangential forces developed at the wheel-rail’s contact surface. The friction coefficient affects the load transfer from the wheel’s tread to the vehicle. In this work, the vibrations of a scale-down railway vehicle are monitored during braking and their relationship with the friction coefficient between wheel and rail is found out. The vehicle is instrumented with encoders, accelerometers, and is controlled via Bluetooth.
The tests are carried out with clean and friction-modified rails. The tangential forces transmitted from the wheel to the railcar’s body are visualized in time and frequency using a proposed correlation algorithm based on the outputs of the ContinuousWavelet Transform (CWT). The results demonstrate
that tangential forces have a significant impact on railway vehicles under conditions of high friction coefficients and large creep values.
Biofuels, particularly biodiesel, have gained significant attention as an alternative to traditional fossil fuels in recent years. Unlike diesel, which contains hundreds of compounds, biodiesel only contains a few compounds in the C16-C18 carbon chain. However, the use of biodiesel in automobile and transportation applications can result in problems of degradation or even damage in materials. Among the commonly used polymer materials, fluorocarbon (FKM) shows excellent performance and high stability and compatibility towards oil, diesel, ethanol, and other chemicals. FKM is a family of fluorocarbon-based fluoroelastomer materials, which provide excellent high-temperature and chemical stability compared to other elastomers. As a result, FKM is widely used in chemical processes such as petroleum refining, where it is used for sealings, pumps, and other components.
Mechanical stress often accelerates the failure of polymer materials. The aim of this research is to study the interaction between the sealing material FKM and biofuels B10 (heating oil with 10% biodiesel). The mechanical stress test was carried out in a special apparatus. Both mechanical and non-mechanical stress tests were conducted on specimens at 20, 40, and 70 °C for 28 days to document changes in mass, volume, and tensile properties. Both increasing temperature and mechanical stress have a significant effect on the tensile strength of the FKM polymer when exposed to B10. The combination of increasing temperature and mechanical stress induced rupture within 2 h. It was also established that FKM polymer with pre-exposure in B10 survived longer during mechanical stress compared to specimens exposed only to air. With the support of infrared (IR) spectroscopy, we were able to confirm the penetration of B10 into the FKM polymer.
The importance of tanks for storing cryogenic fluids in the energy industry is increasing because of ongoing political conflicts and the implementation of more environmentally friendly energy sources. Key representatives for the application of cryogenic tanks are natural gas in the form of Liquefied Natural Gas (LNG) and hydrogen, e. g. in the form of Liquefied Hydrogen (LH2), for which significantly higher transport capacities can be achieved with the same transport volume using cryogenic storages than with storages based solely on overpressure.
What applies to all cryogenic transported fluids in common is their condition that must be maintained. Hence heat flows into the preserved fluid must be minimized. Thermal super Insulations (TSI) based on e. g. multilayer insulations (MLI), perlites, and vacuum are utilized for this purpose and have already proven themselves in similar applications. However, for the use of tanks for cryogenic fluids in the transport sector, there is insufficient knowledge regarding the course and consequences of incidents, which is due to the still short period of use and the few documented incidents, hence few investigations carried out in this field. Typical scenarios in the transport sector represent car accidents with collisions, fires, and their combination, which are associated with extraordinary loads on the tank.
The focus of this study is to investigate the behavior of TSI as a result of their thermal exposure to a heat source representing a fire. It is worth mentioning that this could lead to an increase of the heat flux into a tank by several orders of magnitude, and to permanent damage of the TSI, ultimately rapid release of flammable gas as well as a Boiling Liquide Expanding Vapour Explosion (BLEVE). For this purpose, a high temperature thermal vacuum chamber (HTTVC) has been developed that allows thermal loading of MLI or perlites in a vacuum and simultaneous measurement of heat flow through this TSI. The HTTVC is designed to represent realistic insulation conditions and to withstand thermal loads from typical design fires.
The HTTVC was applied to investigate TSI based on MLI and vacuum. It is shown that the thermal stress caused permanent damage to the TSI, with shrinkage, phase change, pyrolysis, and condensation being significant damage mechanisms. The results are relevant for the evaluation of accident scenarios and can thus contribute to the improvement of TSI and the development of emergency measures for the protection of persons and infrastructures.
The importance of tanks for storing cryogenic fluids in the energy industry is increasing because of ongoing political conflicts and the implementation of more environmentally friendly energy sources. Key representatives for the application of cryogenic tanks are natural gas in the form of Liquefied Natural Gas (LNG) and hydrogen, e. g. in the form of Liquefied Hydrogen (LH2), for which significantly higher transport capacities can be achieved with the same transport volume using cryogenic storages than with storages based solely on overpressure.
What applies to all cryogenic transported fluids in common is their condition that must be maintained. Hence heat flows into the preserved fluid must be minimized. Thermal super Insulations (TSI) based on e. g. multilayer insulations (MLI), perlites, and vacuum are utilized for this purpose and have already proven themselves in similar applications. However, for the use of tanks for cryogenic fluids in the transport sector, there is insufficient knowledge regarding the course and consequences of incidents, which is due to the still short period of use and the few documented incidents, hence few investigations carried out in this field. Typical scenarios in the transport sector represent car accidents with collisions, fires, and their combination, which are associated with extraordinary loads on the tank.
The focus of this study is to investigate the behavior of TSI as a result of their thermal exposure to a heat source representing a fire. It is worth mentioning that this could lead to an increase of the heat flux into a tank by several orders of magnitude, and to permanent damage of the TSI, ultimately rapid release of flammable gas as well as a Boiling Liquide Expanding Vapour Explosion (BLEVE). For this purpose, a high temperature thermal vacuum chamber (HTTVC) has been developed that allows thermal loading of MLI or perlites in a vacuum and simultaneous measurement of heat flow through this TSI. The HTTVC is designed to represent realistic insulation conditions and to withstand thermal loads from typical design fires.
The HTTVC was applied to investigate TSI based on MLI and vacuum. It is shown that the thermal stress caused permanent damage to the TSI, with shrinkage, phase change, pyrolysis, and condensation being significant damage mechanisms. The results are relevant for the evaluation of accident scenarios and can thus contribute to the improvement of TSI and the development of emergency measures for the protection of persons and infrastructures.